Novel Interacting Blends Based on Acryl Terminated Oligoimides Using Bismalamide with Michael Addition Reaction

Authors(1) :-Dr. Rita R. Patel

New amino terminated oligoimides (AOIs) were prepared by the Michael addition reaction of various bismaleimide (1), namely 1-(4-((4-((2,5-dioxocyclopent-3 enylamino)methyl)cyclohexyl)methyl) cyclohexyl)-1,6-dihydropyridine-2,5-dione with excess of various diamines(2a-c). Characterization of these AOIs was carried out by elemental analysis, FT-IR spectral studies and number average molecular weight estimated by non-aqueous conductometric titrations. After the treatment of AOIs with acrylol chloride and resultant acryl terminated oligoimides (AcOIs) samples were also characterized thermogravimetrically. Each of these AcOI was then combined with the N-phenyl maleimide (PM) in THF solvent. The resultant suspensions were then heated in the presence of azobisisobutyronitrile (AIBN) as an initiator. The AcOI and PM polymerized through double bond simultaneously and form interacting blends, which were analyzed thermogravimetrically. The glass fiber reinforced composites were fabricated by using the suspensions of the AcOI and PM. The composites of Interacting blends were analyzed for their mechanical, chemical and electrical properties.

Authors and Affiliations

Dr. Rita R. Patel
P.B. Science College, Kapadwanj Gujarat, India

Amino terminated oligomides (AOIs), Acryl end capped oligoimides (AcOIs), Acryl amide and AIBN and glass fiber reinforced composites, Michael addition reaction.

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Publication Details

Published in : Volume 3 | Issue 7 | September-October 2017
Date of Publication : 2017-10-30
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 1305-1312
Manuscript Number : IJSRST11845312
Publisher : Technoscience Academy

Print ISSN : 2395-6011, Online ISSN : 2395-602X

Cite This Article :

Dr. Rita R. Patel, " Novel Interacting Blends Based on Acryl Terminated Oligoimides Using Bismalamide with Michael Addition Reaction", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 7, pp.1305-1312, September-October-2017.
Journal URL : https://ijsrst.com/IJSRST11845312
Citation Detection and Elimination     |      | |
  • A. A. Berlina; B. I. Liogon'kiia; B. I. Zapadinskiia; E. A. Kazantzevaa; A. O. Stankevich, "J. MACROMOL. XI.-CHEM.", 1977, All(l), pp. 1-28.
  • Liliana Burakowski Noharaa,b,*, Michelle Leali Costaa,b, Mauro Angelo Alvesb,Marta Ferreira Koyama Takahashic, Evandro Luís Noharad, Mirabel Cerqueira Rezendeb, "Materials Research", 2010, 13(2), pp.245-252.
  • D. E. Rajsfus, M.B. Meador and A.A. Frimer, "Macromolecules", 2010, 43, pp.5971–5980.
  • R. Hoogenboom, U. S. Schubert, "Macromol. Rapid Commun." 2007, 28, pp.368–386.
  • A. Oishi, H. Matsuoka, T. Yasuda, M. watanabe, "J.Material Chemistry" , 2009,19, pp 514-521.
  • I.E.Serhatli, A.B. Duz and Y.Yagci, "Polymer Bulletin", 2000, 44(3),pp.261-268.
  • Y. Lu, W. Sun and Z. shen, "European Polymer Journal", 2002, 38(7), pp 1275-1279.
  • G. Liu, X. Li, L. Zhang, X. Qu, P. Liu, L. yang, J. gao, "Journal of Applied Polymer Science" , 2002, 83(2), pp.417-422.
  • D.R.Suwier, P.A.M.Steeman, M.N.Yeerenstra, M.A.J.Schellekens, B.Vanhaecht, M.J.Monterio and C.E. Kohing, "Macromolecules", 2002, 35(16), pp.6210-6216.
  • F.Ylimaz, L.Cidnga, Y.Gunner, L.Toppare, Y.Yagci, "Polymer", 2004, 45, pp.5765-5774.
  • M. C. Patel, R. R. Patel, "Journal of Chemical and Pharmaceutical Research", 2011, 3(1).
  • J. V. Crivello, Chem. Ed., 1976, 14, pp.159.
  • N. E. Searle and H. W. Arnold, US Patent 2467835, Chem. Abast., 1976, 43, pp.4421b .
  • H. S. Patel and V. J. Shah, J. Macromol. Sci., Part A, 1995, A32 (3), pp.405.
  • S. K. Chatterji and V. B. Agrawal, J. Polym. Sci., Part A, 1971, Al (9), pp.3225.
  • R. N. Patel and S. R. Patel, Angew. Makromol. Chem., 1981, 96, pp.85.
  • J. R. Dyer, Application of Absorption Spectroscopy of Organic Compounds, CBS, New Delhi, 1987.
  • " target="_blank"> BibTeX
    |
  • A. A. Berlina; B. I. Liogon'kiia; B. I. Zapadinskiia; E. A. Kazantzevaa; A. O. Stankevich, "J. MACROMOL. XI.-CHEM.", 1977, All(l), pp. 1-28.
  • Liliana Burakowski Noharaa,b,*, Michelle Leali Costaa,b, Mauro Angelo Alvesb,Marta Ferreira Koyama Takahashic, Evandro Luís Noharad, Mirabel Cerqueira Rezendeb, "Materials Research", 2010, 13(2), pp.245-252.
  • D. E. Rajsfus, M.B. Meador and A.A. Frimer, "Macromolecules", 2010, 43, pp.5971–5980.
  • R. Hoogenboom, U. S. Schubert, "Macromol. Rapid Commun." 2007, 28, pp.368–386.
  • A. Oishi, H. Matsuoka, T. Yasuda, M. watanabe, "J.Material Chemistry" , 2009,19, pp 514-521.
  • I.E.Serhatli, A.B. Duz and Y.Yagci, "Polymer Bulletin", 2000, 44(3),pp.261-268.
  • Y. Lu, W. Sun and Z. shen, "European Polymer Journal", 2002, 38(7), pp 1275-1279.
  • G. Liu, X. Li, L. Zhang, X. Qu, P. Liu, L. yang, J. gao, "Journal of Applied Polymer Science" , 2002, 83(2), pp.417-422.
  • D.R.Suwier, P.A.M.Steeman, M.N.Yeerenstra, M.A.J.Schellekens, B.Vanhaecht, M.J.Monterio and C.E. Kohing, "Macromolecules", 2002, 35(16), pp.6210-6216.
  • F.Ylimaz, L.Cidnga, Y.Gunner, L.Toppare, Y.Yagci, "Polymer", 2004, 45, pp.5765-5774.
  • M. C. Patel, R. R. Patel, "Journal of Chemical and Pharmaceutical Research", 2011, 3(1).
  • J. V. Crivello, Chem. Ed., 1976, 14, pp.159.
  • N. E. Searle and H. W. Arnold, US Patent 2467835, Chem. Abast., 1976, 43, pp.4421b .
  • H. S. Patel and V. J. Shah, J. Macromol. Sci., Part A, 1995, A32 (3), pp.405.
  • S. K. Chatterji and V. B. Agrawal, J. Polym. Sci., Part A, 1971, Al (9), pp.3225.
  • R. N. Patel and S. R. Patel, Angew. Makromol. Chem., 1981, 96, pp.85.
  • J. R. Dyer, Application of Absorption Spectroscopy of Organic Compounds, CBS, New Delhi, 1987.
  • " target="_blank">RIS
    |
  • A. A. Berlina; B. I. Liogon'kiia; B. I. Zapadinskiia; E. A. Kazantzevaa; A. O. Stankevich, "J. MACROMOL. XI.-CHEM.", 1977, All(l), pp. 1-28.
  • Liliana Burakowski Noharaa,b,*, Michelle Leali Costaa,b, Mauro Angelo Alvesb,Marta Ferreira Koyama Takahashic, Evandro Luís Noharad, Mirabel Cerqueira Rezendeb, "Materials Research", 2010, 13(2), pp.245-252.
  • D. E. Rajsfus, M.B. Meador and A.A. Frimer, "Macromolecules", 2010, 43, pp.5971–5980.
  • R. Hoogenboom, U. S. Schubert, "Macromol. Rapid Commun." 2007, 28, pp.368–386.
  • A. Oishi, H. Matsuoka, T. Yasuda, M. watanabe, "J.Material Chemistry" , 2009,19, pp 514-521.
  • I.E.Serhatli, A.B. Duz and Y.Yagci, "Polymer Bulletin", 2000, 44(3),pp.261-268.
  • Y. Lu, W. Sun and Z. shen, "European Polymer Journal", 2002, 38(7), pp 1275-1279.
  • G. Liu, X. Li, L. Zhang, X. Qu, P. Liu, L. yang, J. gao, "Journal of Applied Polymer Science" , 2002, 83(2), pp.417-422.
  • D.R.Suwier, P.A.M.Steeman, M.N.Yeerenstra, M.A.J.Schellekens, B.Vanhaecht, M.J.Monterio and C.E. Kohing, "Macromolecules", 2002, 35(16), pp.6210-6216.
  • F.Ylimaz, L.Cidnga, Y.Gunner, L.Toppare, Y.Yagci, "Polymer", 2004, 45, pp.5765-5774.
  • M. C. Patel, R. R. Patel, "Journal of Chemical and Pharmaceutical Research", 2011, 3(1).
  • J. V. Crivello, Chem. Ed., 1976, 14, pp.159.
  • N. E. Searle and H. W. Arnold, US Patent 2467835, Chem. Abast., 1976, 43, pp.4421b .
  • H. S. Patel and V. J. Shah, J. Macromol. Sci., Part A, 1995, A32 (3), pp.405.
  • S. K. Chatterji and V. B. Agrawal, J. Polym. Sci., Part A, 1971, Al (9), pp.3225.
  • R. N. Patel and S. R. Patel, Angew. Makromol. Chem., 1981, 96, pp.85.
  • J. R. Dyer, Application of Absorption Spectroscopy of Organic Compounds, CBS, New Delhi, 1987.
  • " target="_blank">CSV

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