Home > Archives > IJSRST1731020 IJSRST-Library

pH-Metric Study on Determination of Metal-Ligand Stability Constants of some Substituted Isoxazolines

Authors(1) :-P. J. Parmar

The interaction of Cu(II), Co(II), fe(III), Al(III) and Nd(III) with 3-(2''-hydroxy-3''-nitro-5'' methylphenyl)-5-phenyl isoxazoline (Ligand-1), 3-(2''-hydroxy-3''-nitro-5''-methylphenyl)-5-(4'-methoxyphenyl)-isoxazoline(Ligand-II), 3-(2''-hydroxy-3''-nitro-5'' methylphenyl)-5-(3'-nitrophenyl)-isoxazoline(Ligand-III) and 3-(2''-hydroxy-3''-nitro-5'' methylphenyl)-5-(3', 4'-methylene dioxyphenyl)-isoxazoline (Ligand-IV) have been studied by spectrophotometric technique at 0.1 M ionic strenghth and (30±0.1° c) in 70 % dioxane-water mixture. The data obtained were used to estimate the values of metal-ligand stability constant of substitututed isoxazolines. Spectrophotometric investigation of Co(II), Cu(II), Fe(III), Al(III) and Nd(III) complexes with Ligand(I), Ligand (II), Ligand (III) and Ligand(IV) showed l:l and l:2 complex formation simultaneously. The information of complexes has been studied by Calvin-Bjerrum titration technique. The results obtained of stability constants are in good agreement.
P. J. Parmar
Stability Constants, Complex Formation, Ph-Metric Study, Cu(II), Co(II), Fe(III), Al(III), Nd(III) Metal-Ligand Stability Constants, Substituted Isoxazolines.
  1. P. B. Raghuwanshi, A. G. Doshi and M. L. Narwade, J. Indian Chem. Soc., 73, 21 (1996).
  2. P. R Athappan, P. Shanthi and C. Natranjan, Indian J, Chem., 34, 648 (1995).
  3. G. F. Duffin and J. D. Kendall, J. Chem. Soc., 405(1954).
  4. Z. H. Khalil and A. S. Yanni, J. Indian Chem. Soc., 58, 168 (1981).
  5. A. I. Vogel, A Text Book of Practical Organic Chemsitry, Longmans, London (1966).
  6. M. Calving and N. C. Melchior. J. Chem. Soc., 3270 (1948).
  7. H. M. Irving and H. S. Rosotti, J. Chem. Soc., 3397 (1953).
  8. D. Moore and R. Reynolds, X-Ray Diffraction and the Identification and Analysis of Clay Minerals, Oxford University Press, Oxford (1997).
  9. M. M. Mortland, S. Shaobai and S. A. Boyd, Clays Clay Miner., 34, 581 (1986).
  10. J. Lee, M. M. Mortland, C. T. Chiou, D. E. Kilc and S. A. Boyd, Clays Clay Miner., 38, 113 (1990).
  11. C. T. Cowan and D. White, The mechanism reactions occurring between sodium montmorillonite n-primaty apliphatic amine salts (1986) (Translated by D. R. GarKarini and L. L. Lion).
  12. S. A. Boyd, M. M. Mortland and C. T. Chou, Soil. Sci. Soc. Am. J., 52, 652 (1988).
  13. R. M. Barer, Zeolites and Clay Minerals as Sort Molecular Sieves, Academic Press. London pp. 407-409 (1978).
  14. S. A. Boyd, S. S. Kai and M.M. Mortland, in: K. G. Theng (Ed.), The Chemistry of Clay-Organic Reactions, Wiley, New York (1974).
  15. A. R. Khan, R. Atullah and A. Al-hadded, J. Colloid Interface Sci., 194, 154 (1997).
  16. S. Haydar, M. A. F. Garcia, J. R. Ultrilla and J. P. Joly, Carbon, 41, 387 (2003).
  17. H. J. Lee, D. J. Song nad Y. W. Jeon, Sep, Sci. Tech, 32, 1975 (1997).
  18. A. Wolborka, Water Res., 23, 85 (1989).
  19. M. A. M. Lawrence, R. K. Kukkadapa and S. A. Boyd, Appl. Clay Sci., 13, 13 (1998).
  20. A. Weiss, Appl. Clay Sci., 4, 193 (1989).
  21. K. Krause, Process for Immobilizing Organic and Inorganic Pollutants in a Contaminated Soil Material on a Remediation Site, US 5651831 (1997).
  22. B. C. Pan, Y, Xion, Q. Su, A. M. Li, J. L. Chen and Q. X. Zhang, Chemosphere, 51, 953 (2003).
  23. M. Akcay and G. Akcay, J. Hazard, Mater., 113B, 189 (2004).
  24. R. C. Zielke and T. J. Pinnavaia, Clay Clay Miner., 36, 403 (1988).
  25. M. B. McBride, T. J. Pinnavaia and M. M. Mortland, Air Water Environ., 8, 145 (1977).
  26. L. P. Mcir, R. Nueesch and F. T. Medsen, J. Colloid Interface Sci., 238, 20 (2001).
Publication Details
  Published in : Volume 3 | Issue 10 | November-December 2017
  Date of Publication : 2017-12-31
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 87-89
Manuscript Number : IJSRST1731020
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
P. J. Parmar, "pH-Metric Study on Determination of Metal-Ligand Stability Constants of some Substituted Isoxazolines", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 10, pp.87-89, November-December-2017
URL : http://ijsrst.com/IJSRST1731020