Synthesis and Characterization of Cerium doped CaMnO3 Nanoparticles

Authors(2) :-S. Berbeth Mary, A. Leo Rajesh

Nanostructured cerium doped calcium manganite Ca1-xCexMnO3 (x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5) samples were synthesized successfully using the citric acid complexing coupled with hydrothermal method followed by annealing at 900°C. Powder X-ray diffraction (XRD) analysis showed that the single phases of orthorhombic pervoskite structure of CaMnO3 and the cell volume increased from undoped to cerium doped CaMnO3 structure due to the ionic radius of added R3+ cations. The crystallinity decreased with increased concentration of Ce3+ doping and the average crystallite size was about 10-20 nm. Sphere like nanoparticles observed by the scanning electron microscopy. FTIR analysis showed a strong peak around 600 cm-1 revealed the formation of pervoskite oxides and the obtained band gap was 3.56 eV.

Authors and Affiliations

S. Berbeth Mary
Department of Physics, St. Joseph’s College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, India
A. Leo Rajesh
Department of Physics, St. Joseph’s College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, India

calcium manganite, hydrothermal, single phase, pervoskite oxide

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Publication Details

Published in : Volume 3 | Issue 11 | November-December 2017
Date of Publication : 2017-12-15
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 140-145
Manuscript Number : IJSRST1731125
Publisher : Technoscience Academy

Print ISSN : 2395-6011, Online ISSN : 2395-602X

Cite This Article :

S. Berbeth Mary, A. Leo Rajesh, " Synthesis and Characterization of Cerium doped CaMnO3 Nanoparticles", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 11, pp.140-145, November-December-2017.
Journal URL : https://ijsrst.com/IJSRST1731125
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