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Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds

Authors(7) :-B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova

The synthesis of aminoquinoid redox polymers and their oxidation of a toxic gas of phosphine is described. An effect of the nature of solvents, catalysts, relationship between initial components, temperature and time modes of condensation of reactants on the yield and properties of redox polymers formed have been researched into by way of chemical modification of industrial weak-basic anion exchangers by quinones and their derivatives, in an environment similar to green chemistry positions. Synthesized redox-polymers have been tested as oxidants of toxic gas phosphine. The process is based on the oxidation of phosphine by quinones and redox polymers on their basis. Molecular iodine is used as a catalyst. Two-, three-, four- and multicomponent systems are studied in order to determine optimal conditions of the oxidation of phosphine. The rate and selectivity of reaction were monitored by the absorption of ??3. As alcohols used aliphatic alcohols: BuOH, PrOH, EtOH, MeOH. Organophosphorus compounds were analyzed by a chromatographic method. Conversion of phosphine constitutes 80-86%.
B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova
Redox ?olymer, Quinone, Anion Exchanger, Phosphine, Oxidation, Green Chemistry
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Publication Details
  Published in : Volume 3 | Issue 4 | May-June 2017
  Date of Publication : 2017-06-30
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 180-185
Manuscript Number : IJSRST173440
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova , "Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds ", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 4, pp.180-185, May-June-2017
URL : http://ijsrst.com/IJSRST173440