Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds

Authors

  • B. A. Mukhitdinova  ISC, Institute of Chemical Sciences named after A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, Republic of Kazakhstan
  • E. E. Ergozhin  ISC, Institute of Chemical Sciences named after A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, Republic of Kazakhstan
  • G. S. Polimbetova  JSC Institute of Fuel, Catalysis and Electochemistry named after D.V. Sokolsky, 142, D.Kunaev Str., 050010, Almaty, Republic of Kazakhstan
  • A. K. Borangazieva  JSC Institute of Fuel, Catalysis and Electochemistry named after D.V. Sokolsky, 142, D.Kunaev Str., 050010, Almaty, Republic of Kazakhstan
  • K. Ch. Chakimbolatova  ISC, Institute of Chemical Sciences named after A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, Republic of Kazakhstan
  • A. Tasmagambet  ISC, Institute of Chemical Sciences named after A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, Republic of Kazakhstan
  • N. T. Dauletkulova   ISC, Institute of Chemical Sciences named after A.B. Bekturov, 106, Sh. Ualichanov Str.,050010 Almaty, Republic of Kazakhstan

Keywords:

Redox ?olymer, Quinone, Anion Exchanger, Phosphine, Oxidation, Green Chemistry

Abstract

The synthesis of aminoquinoid redox polymers and their oxidation of a toxic gas of phosphine is described. An effect of the nature of solvents, catalysts, relationship between initial components, temperature and time modes of condensation of reactants on the yield and properties of redox polymers formed have been researched into by way of chemical modification of industrial weak-basic anion exchangers by quinones and their derivatives, in an environment similar to green chemistry positions. Synthesized redox-polymers have been tested as oxidants of toxic gas phosphine. The process is based on the oxidation of phosphine by quinones and redox polymers on their basis. Molecular iodine is used as a catalyst. Two-, three-, four- and multicomponent systems are studied in order to determine optimal conditions of the oxidation of phosphine. The rate and selectivity of reaction were monitored by the absorption of ??3. As alcohols used aliphatic alcohols: BuOH, PrOH, EtOH, MeOH. Organophosphorus compounds were analyzed by a chromatographic method. Conversion of phosphine constitutes 80-86%.

References

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International Journal of Scientific Research in Science and Technology

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Published

2017-06-30

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Volume 3, Issue 4, May-June-2017

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Research Articles

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[1]
B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova , " Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds , International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 3, Issue 4, pp.180-185, May-June-2017.