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Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds
Authors(7) :-B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova
The synthesis of aminoquinoid redox polymers and their oxidation of a toxic gas of phosphine is described. An effect of the nature of solvents, catalysts, relationship between initial components, temperature and time modes of condensation of reactants on the yield and properties of redox polymers formed have been researched into by way of chemical modification of industrial weak-basic anion exchangers by quinones and their derivatives, in an environment similar to green chemistry positions. Synthesized redox-polymers have been tested as oxidants of toxic gas phosphine. The process is based on the oxidation of phosphine by quinones and redox polymers on their basis. Molecular iodine is used as a catalyst. Two-, three-, four- and multicomponent systems are studied in order to determine optimal conditions of the oxidation of phosphine. The rate and selectivity of reaction were monitored by the absorption of ??3. As alcohols used aliphatic alcohols: BuOH, PrOH, EtOH, MeOH. Organophosphorus compounds were analyzed by a chromatographic method. Conversion of phosphine constitutes 80-86%.
B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova
Redox ?olymer, Quinone, Anion Exchanger, Phosphine, Oxidation, Green Chemistry
- Cassidy, H.J., Kun, K.A., (1967). Oxidation-reduction polymers, Chemistry: Leningrad.
- Ergozhin, E.E., Mukhitdinova, B.A., (1983). Redoxionites, Nauka: Alma-Ata.
- Ergozhin,E.E., Mukhitdinova, B.A., (2000). Oxidation-reduction ion exchangers, RIO VAK RK: Almaty.
- Ergozhin, E.E.; Mukhitdinova, B.A.; Stefanova,O.K.; Bakirova,R.Kh.; Rozhdestvenskaya,N.V.; (1991/1992). Redox polymers based on polyamines. Reactive Polymers, 16, 321-334.
- Anastas,P.T., Warner, J.C., (1998). Green Chemistry: Theory and Practice, Oxford University Press: New York.
- Cook, S.; (1999). Green chemistry ? evolution or revolution. Green Chemistry. 10,? G138-G140
- Mukhitdinova,B.A.;Ergozhin,E.E.; Nikitina, A.I.; (2013). Realization of some positions of Green Chemistry in the synthesis of redox-polymers. STEPI BOOK. Proceedings. Stepi 9. 9th European Technical Symposium on Polyimides&High Performance Functional Polymers. IAE. University Montpellier II. S.T.A. 246-251.
- Mukhitdinova, B.A.; Ergozhin, E.E.; (2015). Green chemistry conception in redox polymers synthesis. Intern. J. Chem. and Biomed. Sci., 1(2), 44-51
- Mukhitdinova,B.A.; Ergozhin, E.E.; Polimbetova G.S.; et al; (2016). Applying Certain Green Chemistry Positions During the Synthesis Of Redox-Polymers, as Sorbents and Oxidants,? STEPI 10. 10th European Technical Symposium on Polyimides & High Performance Functional Polymers.@ IAE, Universit? Montpellier II, S.T.L.:? June 6-8. Posters Session I-PI-7,? Montpellier (France)
- Mukhitdinova, B.A.; Ergozhin, E.E.; Polimbetova, G.S.; Boangazi?va, A.K.; (2012).?? The Synthesis of Organophosphorus? Compounds from Phosphine and Alcohols in the Presence of Quinones and Redox Polymers on their Basis. Euras.Chem-Technol. J., 6, 191-199.
- Saldadze, K.M., (1967). Oxidation-reduction polymers and their application, Chemistry: Leningrad.
- Kruglikova, N.M., Pashkov, A.B., ibid, P. 14.
- Kozhevnikov,A.V., (1972).? Electron ion exchangers, Chemistry: Leningrad.
- Purdela, D., Vilchanu, R., (1972). Chemistry of organic compounds of phosphor. Chimia: ?oscow.
- Budnikova, Yu.G.; Gryaznova, ?.V.; ?rasnov, S.?.; Magdeev, I.?.; Sinyashin, ?.G.; (2007). Creation of ecologically safe and high electrochemical technologies. Electrochimiya, 43, 1291-1296.
- Polimbetova, G.S.; Abdreimova, R.R.; Faisova, F.Kh.; (2000). Catalytic synthesis of organophosphorus compounds from inorganic derivatives of low valence phosphorus. Eurasian Chem.Tech.J., 2, 21-27.
- ?Valentine,D.H., Hillhouse,? J.H., (2003). Alkyl phosphines as reagents and catalysts in organic synthesis, Synthesis: Stuttgart, 3, 317-334.
- ?Honaker, M.T.; Hovland, J.M.; Salvatone, R.N.; (2007). The synthesis of tertiary and secondary phosphines and their applications in organic synthesis. Current Organic Synthesis, 4, 31-45.
- Ulah, E.; McNulty, J.; Sliwinski, M. R.; (2012). One step synthesis of reusable, polymer-supported tri-alkyl phosphine ligands. Application in Suzuki-Miyaura and alcoxycarbonylation reaction. Tetrahedron Letters, 53, 3990-3993.
- ?rastov, O.E., Nikonov,G.N., (1986). Functional substituted phosphines and their derivatives, Science: ?oscow.
- Kutyrev, A.A.; V.V Moskva V.V.; (1991). Nucleophilic reactions of quinones.? Uspehi Chim.,60, 134-168.
Published in : Volume 3 | Issue 4 | May-June 2017
Date of Publication : 2017-06-30
License: This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 180-185
Manuscript Number : IJSRST173440
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
B. A. Mukhitdinova, E. E. Ergozhin, G. S. Polimbetova, A. K. Borangazieva, K. Ch. Chakimbolatova, A. Tasmagambet, N. T. Dauletkulova , "Oxidation of Ph3 By Redox Polymers - Convenient Method For Synthesis Organic Phosphorus Compounds
", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 4, pp.180-185, May-June-2017
URL : http://ijsrst.com/IJSRST173440