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A Mercury Free Dopamine Dithiocarbamate Modified Electrode For Pb (II) Determination by Anodic Stripping Voltammetry

Authors(4) :-J. Kavitha, S. Vasanthi, M. Devendiran, S. Sriman Narayanan

A mercury free dopamine dithiocarbomate (DDTC) modified electrode has been proposed for the anodic stripping voltammetric (ASV) determination of Pb (II). DDTC synthesized from dopamine and carbon disulfide. An ethanolic solution of this compound was drop casted on paraffin impregnated graphite electrode to prepare the modified electrode. This electrode was used for Pb (II) determination by ASV. Various parameters such as background electrolyte, pH and preconcentration time were optimized. Under optimized condition, the stripping method provided a linear range from 0.33 to 35 µM for the determination of Pb (II) by ASV. The proposed method is simple, sensitive and selective for the determination of Pb (II) by ASV.
J. Kavitha, S. Vasanthi, M. Devendiran, S. Sriman Narayanan
DDTC, ASV, pH, EDTA, MWCNT
  1. Mejare M, Bulow, L, Metal  binding     proteins and peptides in bioremediation and phytoremediation of heavy metals, Trends Biotechnology 19 (2001) 67.
  2. M.A. El. Mhammedi, M. Achak, M. Bakasse, A. Chtaini, Electroanalytical methods for the determination of lead (II) in orange and apple using kaolin modified platinum electrode, Chemosphere 76 (2009) 1130-1134.
  3. J.O. Nriagu, J.M. Pacyna, Quantitative assessment of worldwide contamination of air, water  and soil by trace metals, Nature 333 (1988) 134.
  4. L. Zhu, L. Xu, B. Huang, N. Jia, L. Tan, S. Yao, Simultaneous determination of Cd (II) and Pb (II) using square wave anodic stripping voltammetry at GNP-graphene-cysteine composite modified bismuth film electrode, Electrochimica acta, 115 (2014) 471-477.
  5. Mei-Rong Huang, Yong-Bo Ding, and Xin-Gui Li, Combinatorial Screening of Potentiometric Pb(II) Sensors from Poly sulfoamino anthraquinone Solid Ionophore, American Chemical Society – Combinational Science, 16 (2014) 128 − 138.
  6. Sema Gunduz, Suleyman Akman, Determination of lead in rice grains by solid sampling HR-CS GFAAS, Food Chemistry 141 (2013) 2634 – 2638.
  7. Homeira Ebrahimzadeha, Ali Akbar Asgharinezhada, Elahe Moazzenav, Mostafa M. Aminia, Omid Sadeghib, A magnetic ion-imprinted polymer for lead (II) determination: A study on the adsorption of lead (II) by beverages, Journal of Food Composition and Analysis 41 (2015) 74 – 80.
  8. Aristidis N. Anthemidis, Ibrahim S.I. Adam, George A. Zachariadis, Poly (etheretherketone)-turnings a novel sorbent material for lead determination by flow injection flame atomic absorption spectrometry and factorial design optimization, Talanta 81 (2010) 996 – 1002.
  9. N. Rajesh, S. Manikandan, Spectrophotometric determination of lead after preconcentration of its diphenylthiocarbazone complex on an Amberlite XAD-1180 column, Spectrochimica Acta Part A 70 (2008) 754 – 757.
  10. Latif E, Zikri Arslanb, Julian F. Tyson, Determination of lead in wine and rum samples by flow injection-hydride generation-atomic absorption spectrometry, Journal of Hazardous Materials 162 (2009) 880 – 885.
  11.  T. Frentiu, M. Ponta, A.I. Mihaltan, E. Darvasi, M. Frentiu, E. Cordos, Quenching of the OH and nitrogen molecular emission by methane addition in an Ar capacitively coupled plasma to remove spectral interference in lead determination by atomic fluorescence spectrometry, Spectrochimica Acta Part B 65 (2010) 565 – 570.
  12. R.S. Praveena, G.R.K. Naidub, T. Prasada Raoa, Dithiocarbamate functionalized or surface sorbed Merrifield resin beads as column materials for on line flow injection–flame atomic absorption spectrometry determination of lead, Analytica Chimica Acta 600 (2007) 205 – 213.
  13. Wirat Ruengsitagoon, Alberto Chisvert, Saisunee Liawruangrath, Flow injection spectrophotometric determination of lead using 1,5-diphenylthiocarbazone in aqueous micellar, Talanta 81 (2010) 709 – 713.
  14. Vedat Yilmaz, Zikri Arslana, Lakeysha, Determination of lead by hydride generation inductively coupled plasma mass spectrometry (HG-ICP-MS): On-line generation of plumbane using potassium hexacyanomanganate(III), Analytica Chimica Acta 761 (2013) 18 – 26.
  15. Ariel Maratta, Sandra Vazquez, Ayelen Lopez, Miriam Augusto and Pablo H. Pachecol, Lead preconcentration by solid phase extraction using oxidized carbon xerogel and spectrophotometric determination with dithizone, Microchemical Journal 128 (2016) 166 - 171.
  16. Adil Mandil, Laila Idrissi and Aziz Amine, Stripping voltammetric determination of mercury (II) and lead (II) using screen-printed electrodes modified with gold films, and metal ion preconcentration with thiol-modified magnetic particles, Microchim Acta 170 (2010) 299 – 305.
  17. C. Rojas-Romo, N.Serrano, C. Arino, V. Arancitria, J. M Diaz-Cruz, M. Esteban, Determination of Antimony (II) using an ex-situ bismuth screen printed carbon electrode by adsorptive stripping voltammetry, Talanta, 155 (2016) 21-27.
  18. Bengi Uslu and Sibel A. Ozkan, Electroanalytical methods for the Determination of pharmaceuticals: A review of recent trends and developments, Analytical Letters 44 (2011) 2644 – 2702.
  19. Sudkate Chaiyoa, Orawon Chailapakul, Weena Siangproha, Highly Sensitive determination of mercury using copper enhancer by diamond electrode coupled with sequential injection–anodic stripping voltammetry, Analytica Chimica Acta 852 (2014) 55 – 62.
  20. Lorena C. Martiniano, Vivia R. Abrantesa, Sakae Y. Netoa, Edmar P. Marquesa,b, Teresa C.O. Fonsecac, Leonardo L. Paimd, Antônio G. Souzab, Nelson R. Stradiottod, Ricardo Q. Aucelioe, Glene H.R. Cavalcantea, Aldalea L.B. Marquesa, Direct simultaneous determination of Pb (II) and Cu (II) in biodiesel by anodic stripping voltammetry at a mercury-film electrode using microemulsions, Fuel 103 (2013) 1164 – 1167.
  21. S.J. Richard Prabakar, C. Sakthivel, S. Sriman Narayanan, Hg (II) immobilized MWCNT graphite electrode for the anodic stripping voltammetric determination of lead and cadmium, Talanta 85 (2011) 290 – 297.
  22. Qiang Zhao, Yaqin Chai, Ruo Yuan, Junhua Luo, Square wave anodic stripping voltammetry determination of lead based on the Hg(II) immobilized graphene oxide composite film as an enhanced sensing platform, Sensors and Actuators B: 178 (2013) 379 – 384.
  23. Joseph Wang, Stripping Analysis at Bismuth Electrodes: A Review, Electroanalysis 17 (2005) 15–16.
  24. Economou, Bismuth – film electrodes: recent developments and potentialities for electroanalysis, Trends in Analytical Chemistry, 24 (2005) 4 - 10.
  25. Nuria Serrano, Aristides Alberich, Jose manuel Diaz Cruz, Cristina Arino, Miquel Esteban, Coating methods, modifiers and applications of bismuth screen – printed electrodes, Trends in Analytical Chemistry 46 (2013) 15 – 29.
  26. Kannika Keawkima, Suchada Chuanuwatanakula, Orawon Chailapakula, Shoji Motomizuc, Determination of lead and cadmium in rice samples by sequential injection/ anodic stripping voltammetry using a bismuth film/crown ether/Nafion modified screen-printed carbon electrode, Food Control 31 (2013) 14 – 21.
  27. Nuria Serrano, Jose Manuel Diaz-Cruz, Cristina Arino, Miquel Esteban, Antimony- based electrodes for analytical determinations, Trends in Analytical Chemistry 77 (2016) 203 – 213.
  28. Bine Sebeza, Bozidar Ogorevca, Samo B. Hocevara, Marjan Veberb, Functioning of antimony film electrode in acid media under cyclic and anodic stripping voltammetry conditions, Analytica Chimica Acta 785 (2013) 43 – 49.
  29. Veronica Arancibia, Edgar Nagles, Carlos Rojas, Marisol Gomez, Ex Situ prepared nafion- coated antimony film electrode for adsorptive stripping voltammetry of model metal ions in the presence of pyrogallol red, Sensors and Actuators B: Chemical 182 (2013) 368 – 373.
  30.  V. Jovanovski, N.I. Hrastnik, S.B. Hocevar, Copper film electrode for anodic stripping voltammetric determination of trace mercury and lead, Electrochemistry Communications 57 (2015) 1– 4.
  31. Jie Jiang, Miao - Qing Xu, Jin- Feng Liu, Guang-Chao Zhao, A novel tellurium film electrode for simultaneous determination of Cd (II) and Pb (II) using anodic stripping voltammetry, International Journal of Electrochemical Science 9 (2014) 6572 – 6579.
  32. Zhuo Guo, Dong-di Li, Xian-ke Luo, Ya-hui Li, Qi-Nai Zhao, Meng-meng Li, Yang-ting Zhao, Tian-shuai Sun, Chi Ma, Simultaneous determination of trace Cd(II), Pb(II) and Cu(II) by differential pulse anodic stripping voltammetry using a reduced grapheme oxide-chitosan/poly-L-lysine nanocomposite modified glassy carbon electrode, Journal of Colloid and Interface Science 490 (2017) 11 – 22.
  33. Nuria Serrano, Beatriz Prieto-Simon, Xavier Ceto, Manel del Valle, Array of peptide-modified electrodes for the simultaneous determination of Pb(II), Cd(II) and Zn(II), Talanta 125 (2014) 159 – 166.
  34. Nuria Serrano, Andreu Gonzalez-Calabuig, Manel del Valle, Crown ether-modified electrodes for the simultaneous stripping voltammetric determination of Cd(II), Pb(II) and Cu(II), Talanta 138 (2015) 130 – 137.
  35. S. Vasanthi, M. Devediran, S. Sriman Narayanan. A mercury free electrode for anodic stripping voltammetric determination of Pb (II) ions using poly zincon film modified electrode, Applied Surface Science, 422 (2017) 138-146.
  36. J. Kavitha, M. Devendiran, K. Krishna Kumar, S. Sriman Narayanan, Electrochemical Sensor for the Determination of Hydrazine Using Mwcnt/Dopamine Dithiocarbamate Modified Electrode, International Journal of Scientific Research in Science and Technology, 2017 (3) 6: 227-232.
  37. Damian. C Onwudine, Peter A. Ajibada, Synthesis and characterization of metal complexes of N- alkyl – N – phenyl dithiocarbamates, Polyhedron, 29 (2010) 1431- 1436.
  38. Arda Alden green, The preparation of acetate and phosphate buffer solutions of known pH and ionic strength, Journal of the American Chemical Society, 55 (1933) 2331 – 2336.
  39. K. Suresh-Kumar, W. Hui-Fen, One-pot synthesis of dopamine dithiocarbamate functionalized gold nanoparticles for quantitative analysis of small molecules and phosphopeptides in SALDI- and MALDI-MS, Analyst 137 (2012) 1629-1638.
  40. F. Scholz, B. Lange, Abrasive stripping voltammetry - an electrochemical solid state spectroscopy of wide applicability, Trends Anal. Chem. 11 (1992) 359-367.
Publication Details
  Published in : Volume 3 | Issue 6 | July-August 2017
  Date of Publication : 2017-08-31
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 294-301
Manuscript Number : IJSRST173688
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
J. Kavitha, S. Vasanthi, M. Devendiran, S. Sriman Narayanan, "A Mercury Free Dopamine Dithiocarbamate Modified Electrode For Pb (II) Determination by Anodic Stripping Voltammetry", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 6, pp.294-301, July-August-2017
URL : http://ijsrst.com/IJSRST173688