Synthesis and Characterization of Some Mixed Ligand Complexes of Th(IV) with Salicylyl hydrazine and its Derivatives

Authors

  • Jisha. M. J  Department of Chemistry, Christian College Kattakada, India
  • G. Rajendran  Department of Chemistry, University College (Rtd.), Trivandrum, India

Keywords:

BSH, DTG, Molar conductance, SH, TG.

Abstract

Some mixed ligand complexes of Th (IV) with Salicylyl hydrazine (SH) and its derivatives as primary ligands and two different anions viz., nitrate and thiocyanate as secondary ligands have been synthesized and characterized on the basis of elemental analysis, molecular weight, molar conductance, IR spectra TG and DTG data. In these complexes the primary ligands salicylyl hydrazine (SH), acetyl salicylyl hydrazine (ASH) and benzoyl salicylyl hydrazine (BSH) act as neutral bidentate ligand and the secondary ligands, viz., the monovalent ions NO3- and NCS act as unidentate ligands.

References

  1. M. S. Abashmadze, N.K. Pirtshalava, Yu Ya Kheritonov and R. I. Muchlehoslivito, Russian. J. Inorg. Chem., 23,1467(1978)
  2. S. R. Tewari, S. K. Bajpai, S. K. Misra and G. N. Shukla, J. Indian Chem. Soc., 59,891(1982)
  3. E. Canpolat, Synthesis and Characterization of Dioxouranium (VI) Complexes of Schiff Bases (Mixed- Ligands Part 2), Turkish Journal of Science & Technology, 9(2), 145-151, 2014
  4. Vogel A I, A Text Book of Quantitative ChemicalAnalysis,6thEd., Pearson Education, (1998)
  5. W. G. Palmer, Experimental Physical Chemistry, The University press, Cambridge (1954)
  6. G. Rajendran and P. Indrasenan, Synth. React. Inorg. Met-Org. Chem., 22(6), 715(1992)
  7. L. J. Bellamy and L. Becher, J. Chem. Soc., 4488, 1954
  8. W. J. Geary, "The use of conductivity measurements in organic solvents for the characterization of coordination compounds", Coordination Chemistry Reviews, 7,1971,122
  9. J. R. Ferroro, J. Molecular Spectrum,4,99, (1960)
  10. Ferrero J R, Low Frequency Vibrations of Inorganic and Coordination compounds, NewYork: John Wiley, (1971).
  11. J. Lewis, R. S. Nyholm and P. W. Smith, The Structure of Complex Molybdenum Thiocyanates, J. Chem. Soc.,4590(1961)

Downloads

Published

2017-10-31

Issue

Section

Research Articles

How to Cite

[1]
Jisha. M. J, G. Rajendran, " Synthesis and Characterization of Some Mixed Ligand Complexes of Th(IV) with Salicylyl hydrazine and its Derivatives, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 3, Issue 7, pp.110-114, September-October-2017.