Home > Archives > IJSRST173730 IJSRST-Library

Synthesis and Characterization of Some Mixed Ligand Complexes of Th(IV) with Salicylyl hydrazine and its Derivatives

Authors(2) :-Jisha. M. J, G. Rajendran

Some mixed ligand complexes of Th (IV) with Salicylyl hydrazine (SH) and its derivatives as primary ligands and two different anions viz., nitrate and thiocyanate as secondary ligands have been synthesized and characterized on the basis of elemental analysis, molecular weight, molar conductance, IR spectra TG and DTG data. In these complexes the primary ligands salicylyl hydrazine (SH), acetyl salicylyl hydrazine (ASH) and benzoyl salicylyl hydrazine (BSH) act as neutral bidentate ligand and the secondary ligands, viz., the monovalent ions NO3- and NCS act as unidentate ligands.
Jisha. M. J, G. Rajendran
BSH, DTG, Molar conductance, SH, TG.
  1. M. S. Abashmadze, N.K. Pirtshalava, Yu Ya Kheritonov and R. I. Muchlehoslivito, Russian. J. Inorg. Chem., 23,1467(1978)
  2. S. R. Tewari, S. K. Bajpai, S. K. Misra and G. N. Shukla, J. Indian Chem. Soc., 59,891(1982)
  3. E. Canpolat, Synthesis and Characterization of Dioxouranium (VI) Complexes of Schiff Bases (Mixed- Ligands Part 2), Turkish Journal of Science & Technology, 9(2), 145-151, 2014
  4. Vogel A I, A Text Book of Quantitative ChemicalAnalysis,6thEd., Pearson Education, (1998)
  5. W. G. Palmer, Experimental Physical Chemistry, The University press, Cambridge (1954)
  6. G. Rajendran and P. Indrasenan, Synth. React. Inorg. Met-Org. Chem., 22(6), 715(1992)
  7. L. J. Bellamy and L. Becher, J. Chem. Soc., 4488, 1954
  8. W. J. Geary, "The use of conductivity measurements in organic solvents for the characterization of coordination compounds", Coordination Chemistry Reviews, 7,1971,122
  9. J. R. Ferroro, J. Molecular Spectrum,4,99, (1960)
  10. Ferrero J R, Low Frequency Vibrations of Inorganic and Coordination compounds, NewYork: John Wiley, (1971).
  11. J. Lewis, R. S. Nyholm and P. W. Smith, The Structure of Complex Molybdenum Thiocyanates, J. Chem. Soc.,4590(1961)
Publication Details
  Published in : Volume 3 | Issue 7 | September-October 2017
  Date of Publication : 2017-10-31
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 110-114
Manuscript Number : IJSRST173730
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
Jisha. M. J, G. Rajendran, "Synthesis and Characterization of Some Mixed Ligand Complexes of Th(IV) with Salicylyl hydrazine and its Derivatives", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 7, pp.110-114, September-October-2017
URL : http://ijsrst.com/IJSRST173730