Studies on Ultrasonic Velocity and Acoustical Properties of Poly (4, 4' – Cyclohexylidene diphenylene toluene – 2, 4-Disolfonate) in Different Solvents at 300 C

Authors

  • K. M. Rajkotia  

Keywords:

Solvent- polymer and polymer - polymer interactions exist in the solvent systems studied.

Abstract

Various acoustical Parameters of Poly (4, 4'-Cyclopentylidene diphenylene toluene - 2,4-disulfonate) (PSBT) in Chloroform, 1-2-dichloroethane, 1,4-dioxane and tetra hydrofuran were evaluated at 30< sub>0 C using an interferometer operating at a frequency of 3 MHz. Some of these parameters, except the internal pressure, relaxation time, classical absorption coefficient and solvation number, were correlated with concentration. Excellent linear correlations between the parameters U, Z, KS, R, b, Lf and nand concentration are observed.

References

  1. Dunn, F. Edmonds, P. D. and Fry, W. J. Biological Engineering, MCGraw-Hill, New York, 1969.
  2. Matheson, A. J. Molecular Acoustics, Wiley Inter-science, London, 1971.
  3. Pethrick, R. A. J. Macromol, Chem. 1973, C-9, 91.
  4. Suryanarayan, C. V. and Pugazhendhi, P. Indian J. Pune Appl. Phys. 1986, 24, 406.
  5. Kor, S. K. and Srivastava, A. K. Acustica, 1984, 55, 244.
  6. Sundaresan, B. and Rao, A. S. Polym. Int. 1994, 33, 425.
  7. Venkatnaidu, S. and Rao, C. J. Polym. Mater. 1990, 7, 149
  8. Naidu, S. V. Rajulu, A. V. and Rao, C. K. 1989, J. Polym, Mater, 6, 293
  9. Rao, A. V. Raman, G. K. and Rajulu, A. V. Asian J. Chem. 1993, 5, 582.
  10. Dunbar, J. I. North, A. M. Pethrick, A. and Steinhauer, D. B. J. Polym. Sci-Phys Edn, 1977, 15, 263.
  11. Dunbar, J. I. and Pethrick, R. A. J. Polym. Sci-Phys Edn, 1977, 15, 279.
  12. Desai, J. A. and Parsania, P. H. J. Polym. Mater. 1996, 13, 79.
  13. Kamani, M. M. and Parsania, P. H. J. Polym. Mater, 1996, 13, 191.
  14. Shah, A. R. and Parsania, P. H. Eur. Polym. J. (in press)
  15. Vogel's Textbook of Practical Organic Chemistry, ELBS, 4th Edn.
  16. Rajkotia, K. M. Kamani, M. M. and Parsania, P. H. Polymer 1997, 38, 715.
  17. Well, W. and Pethrick, R. A. Polymer, 1982, 23, 369.
  18. Hassun, S. K. Acoustics Lett. 1988, 11, 195.
  19. Eyring, H. and Kincaid, J. F. J. Chem, Phys. 1938, 6, 620

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Published

2016-12-31

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Section

Research Articles

How to Cite

[1]
K. M. Rajkotia, " Studies on Ultrasonic Velocity and Acoustical Properties of Poly (4, 4' – Cyclohexylidene diphenylene toluene – 2, 4-Disolfonate) in Different Solvents at 300 C, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 2, Issue 6 , pp.544-547, November-December-2016.