Study of Polyvinyl Chloride Composites Based on CaCO3 and Alkali Treated Coconut Fibers

Authors

  • Shaikh V. A. E.  Polymer Chemistry Research Laboratory, Department of Polymer Engineering, MIT World Peace University (MIT-WPU), Kothrud, Pune, India

Keywords:

Polymer Composites, Natural Fiber Reinforcement, Polyvinyl Chloride Composite, Coconut Fibers.

Abstract

The present paper deals with mechanical and morphological study of polyvinyl chloride (PVC) hybrid-composites using CaCO3 as a filler and coconut fibers as a reinforcing material. A series of batches were compounded by using both, alkali-treated and untreated coconut fibers (1%, 3%, 5%, 7.5% to 10%) separately while the CaCO3 content was maintained uniform in all the formulations. The formulation was first dry blended and then compounded on a two-roll mill. The dry blended composition was then compression molded into sheets in the temperature range of 160-180°C. A study was done as per ASTM standards to evaluate tensile properties, impact strength, shore hardness, coefficient of friction, water absorption and using SEM. The mechanical properties keep on increasing till the coir content (treated and untreated) reaches 5% and then starts decreasing beyond 5%. Alkali treated fiber composites have shown superior properties to untreated ones. SEM study supports the fact that the alkali treated fiber reinforced composites are morphologically more uniform than untreated ones resulting in better properties.

References

  1. N. Netravali, in; "Natural Fiber Plastic Composites", F. T. Wallenbergerand E. Norman Weston (Eds), Springer Science+Business Media: New York, 2004, p. 321
  2. A. Kelly, J. Cer. Proc. Res. (2004) 2, 2, 147
  3. A. C. N. Singleton, Comp. B. (2003) 34, 5, 519
  4. M. T. Moe and K. Liao, Comp. Sci. Tech. (2003) 63, 375
  5. E. M. F. Aquino, L. P. S. Sarmento and W. Oliveira, Rein. Plas. Comp. (2007) 26, 2, 219
  6. S. Biswas, Q. Ahsan, I. Verpoestet al. , Adv. Mat. Res. (2011) 264-265, 445
  7. M. M. Haque, M. R. Rahman, M. N. Islamet al. , J. Rein. Plas. Comp. (2010) 29, 222
  8. R. Mahlberg, L. Paajanen, A. Nurmiet al. , Holzals Roh-und Werkstoff (2001) 59(5), 319
  9. J. Brandstrom, IAWA J. (2001) 22 (4), 333
  10. X. H. Li, Y. Z. Meng, S. J. Wang, A. V. Rajulu et al. , J. Polym. Sci. Part B: Polym. Phy. (2004) 42(4), 666
  11. M. Shibata, K. Takachiyo, K. Ozawa et al. , J. Appl. Polym. Sci. (2002) 85(1), 129
  12. M. Shibata, K. Ozawa, N. Teramotoet al. , Macromol. Mat. Eng. (2003) 288(1), 35
  13. K. K. Mathur, S. B. Driscoll, J. Vinyl Tech. (1982) 4(2), 81
  14. Q. Fu, G. H. Wang, J. Shen, J. Appl. Polym. Sci. (1993) 49, 673
  15. Z. Bartczak, A. S. Argo, R. E. Cohen et al. , Polymer (1999) 40, 2347
  16. R. Karnani, M. Krishnan and R. Narayan, Polym. Eng. Sci. (1997) 37(2), 476
  17. K. Joseph, L. H. C. Mattoso, R. D. Toledo et al. , in; "Natural Polymers and Agro Fibers Based Composites", E. Frollini, A. L. Le?o and L. H. C. Mattoso (Eds) Embrapa Agricultural Instrumentation, 2000, p. 159
  18. J. George, M. S. Sreekala and S. Thomas, Polym. Eng. Sci. (2001) 41(9), 1471
  19. M. B. Norbert, in; "Cellulose and Cellulose Derivatives Part II", E. Ott, H. M. Spurlin and M. W. Grafflin (Eds), New York: Interscience 1954, p. 863.
  20. P. B. Sarkar, Ind. J. Chem. Soc. (1935)12, 23.
  21. A. Mukherjee, P. K. Ganguli and D. Sur, J. Tex. Inst. (1993)84, 348. R. K. Samal, M. Mohanty and B. B. Panda, J. Polym. Mater. (1995) 12, 235
  22. J. Gassan and A. K. Bledzki, Comp. Sci. Tech. (1999) 59, 1303
  23. J. Gassan and A. K. Bledzki, J. Appl. Polym. Sci. (1999) 71, 623
  24. A. K. Bledzki and J. Gassan, Prog. Polym. Sci. (1999) 24, 221
  25. A. Choudhury, S. Kumar and B. J. Adhikari, Appl. Polym. Sci. (2007) 106 (2), 775
  26. E. Corradini, L. C. Morais, M. F. Rosa et al. , in; "Macromolecular Symposia, Special Issue: World Polymer Congress - MACRO 2006", 2006, 245-246 p. 558
  27. S. Harisha, D. Peter Michaelb, A. Benselybet al. , Mater. Charact. (2009) 60, 44
  28. K. G. Satyanarayana, C. K. S. Pillai, K. Sukumaranet al. , J. Mater. Sci. (1982) 17, 2453
  29. V. G. Geethamma, M. K. Thomas, R. Lakshminarayan et al. , Polym. (1998) 39 (6-7), 1483
  30. A. Paul and S. Thomas, J. Appl. Polym. Sci. (1997) 63(2), 247
  31. H. P. S. Abdul Khalil and H. D. Rozman, M. N. Ahmad et al. , Polym. Plast. Tech. Eng. (2000) 39(4), 757
  32. D. Ray, B. K. Sarkar, A. K. Ranaet al. , Bull. Mater. Sci. (2001) 24, 2, 129
  33. P. Ramadevi, S. Dhanalakshmi, V. Chikkolet al. , Bioresour. (2012) 7 (3), 3515
  34. V. Baheti, J. Militky, and S. Z. Ul Hassan, International conference on natural fibers-sustainable materials for advanced applications-2013, Guimaraes, Portugal 9-11 June 2013.

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Published

2017-12-15

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Research Articles

How to Cite

[1]
Shaikh V. A. E., " Study of Polyvinyl Chloride Composites Based on CaCO3 and Alkali Treated Coconut Fibers, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 3, Issue 9, pp.207-214, November-December-2017.