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Direct One Pot Synthesis of Iodoarenes from Aromatic Amine Using TCT-Wet.Sio2 as an Effective Heterogeneous Catalyst

Authors(1) :-Somnath S. Gholap

The present article described the one pot direct synthesis of structurally diverse aryl iodides from primary aromatic amines in aprotic media. 1,3,5-Trichlorotriazene (TCT)-Wet. SiO2 (50 % W/W) was found to be an effective heterogeneous catalyst for in situ generation of diazonium salt followed by iodination with potassium iodide. The methodology presented here was worked well for the variety of aromatic amines possessing electron donating as well as electron withdrawing substituents on aromatic ring at room temperature. The corresponding aryl iodides are obtained in good to excellent yield.
Somnath S. Gholap
Trichlorotriazene, diazonium salt, HCl
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Publication Details
  Published in : Volume 3 | Issue 9 | November-December 2017
  Date of Publication : 2017-12-15
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 297-300
Manuscript Number : IJSRST173959
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
Somnath S. Gholap, "Direct One Pot Synthesis of Iodoarenes from Aromatic Amine Using TCT-Wet.Sio2 as an Effective Heterogeneous Catalyst", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 3, Issue 9, pp.297-300, November-December-2017
URL : http://ijsrst.com/IJSRST173959