A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization

Authors

  • Y. Samson  Department of Physics, Annai Velankanni College, Tholayavattam, Tamil Nadu, India
  • S. Anbarasu  Department of Physics, St. Joseph’s College (Autonomous), Tiruchirappalli, Tamil Nadu, India
  • M. Ambrose Rajkumar  Department of Physics, Kristu Jayanthi College (Autonomous), K. Narayanapura, Kothanur, Bengaluru, Karnataka, India
  • P. Ajith  Department of Physics, St. Xavier's College (Autonomous), Palayamkottai, Tamil Nadu, India
  • D. Prem Anand  Department of Physics, St. Xavier's College (Autonomous), Palayamkottai, Tamil Nadu, India

DOI:

https://doi.org//10.32628/IJSRST18401160

Keywords:

Mixed Crystal, FASA, UV Transmittable, Dielectric, SHG

Abstract

A UV transmittable NLO crystal Hydrofluoric acid mixed Sulphamic acid (FASA) was synthesized and explored in aqueous solution by slow solvent evaporation technique at ambient temperature. Centimeter sized 3 × 2.8 × 1 cm3 crystal was harvested in a period of 25-30 days. Single crystal X-ray diffraction data manifest FASA crystallizes in Tetragonal P crystal system with lattice parameters of a = 8.12 Å, b = 8.12 Å, c = 9.29 Å and α=β=γ =90?. The peaks in powder X-ray diffractogram were indexed corresponding to the (hkl) plane orientations showing the crystalline purity and perfection. FTIR spectrum authenticate the functional groups exist in FASA crystal system. UV-vis-NIR spectrum validated a wide transparency range with short UV cut-off edge closer to 200 nm. FASA endowed with larger dielectric polarizability. Kurtz-Perry powder test flashed the Phase matchable SHG efficiency 0.43 times KDP. Soft nature of FASA suits itself for crystal feasibility. The presence of HF with sulphamic acid delivered a mixed crystal system FASA suitable for UV nonlinear optical applications.

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International Journal of Scientific Research in Science and Technology

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Published

2018-12-30

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Volume 4, Issue 11, November-December-2018

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Research Articles

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[1]
Y. Samson, S. Anbarasu, M. Ambrose Rajkumar, P. Ajith, D. Prem Anand, " A UV Transmittable NLO crystal Hydrofluoric Acid Mixed Sulphamic acid (FASA) : Synthesis, Growth and Characterization, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 4, Issue 11, pp.259-271, November-December-2018. Available at doi : https://doi.org/10.32628/IJSRST18401160