Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester

Authors(6) :-Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil

Treatment of α, β-unsaturated cyanoester with phenyl cadmium bromide, derived from dilithium tetrachloro cadmium (Li2CdCl4) and Grignard reagent in the presence of 10 mol % of Nitratobis (Triphenyl phosphine) Copper (I) i.e. Cu(PPh3)2NO3 catalyst afforded chemoselective conjugated product in high yields.

Authors and Affiliations

Ashok S. Pise
Department of Chemistry, Dada Patil Mahavidyalaya, Karjat, Ahmednagar, Maharashtra, India
Arvind S. Burungale
Department of Chemistry, S. M. Joshi College Hadapsar, Pune, Maharashtra, India
Ramesh B. Gawade
Department of Chemistry, S. M. Joshi College Hadapsar, Pune, Maharashtra, India
Santosh S. Devkate
Department of Chemistry, Mahatma Phule Mahavidyalaya, Panvel, Raigad, Maharashtra, India
Sunil D. Jadhav
Department of Chemistry, Dada Patil Mahavidyalaya, Karjat, Ahmednagar, Maharashtra, India
Shripad M. Patil

Conjugate addition, Cyanoester, Cu (I) catalyst, Grignard reagent, Ultrasound irradiation.

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Publication Details

Published in : Volume 4 | Issue 2 | January-February 2018
Date of Publication : 2018-02-28
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 121-124
Manuscript Number : IJSRST184151
Publisher : Technoscience Academy

Print ISSN : 2395-6011, Online ISSN : 2395-602X

Cite This Article :

Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil, " Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 4, Issue 2, pp.121-124, January-February-2018.
Journal URL : http://ijsrst.com/IJSRST184151

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