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Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester

Authors(6) :-Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil

Treatment of α, β-unsaturated cyanoester with phenyl cadmium bromide, derived from dilithium tetrachloro cadmium (Li2CdCl4) and Grignard reagent in the presence of 10 mol % of Nitratobis (Triphenyl phosphine) Copper (I) i.e. Cu(PPh3)2NO3 catalyst afforded chemoselective conjugated product in high yields.
Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil
Conjugate addition, Cyanoester, Cu (I) catalyst, Grignard reagent, Ultrasound irradiation.
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Publication Details
  Published in : Volume 4 | Issue 2 | January-February 2018
  Date of Publication : 2018-02-28
License:  This work is licensed under a Creative Commons Attribution 4.0 International License.
Page(s) : 121-124
Manuscript Number : IJSRST184151
Publisher : Technoscience Academy
PRINT ISSN : 2395-6011
ONLINE ISSN : 2395-602X
Cite This Article :
Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil, "Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester", International Journal of Scientific Research in Science and Technology(IJSRST), Print ISSN : 2395-6011, Online ISSN : 2395-602X, Volume 4, Issue 2, pp.121-124, January-February-2018
URL : http://ijsrst.com/IJSRST184151