Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester

Authors

  • Ashok S. Pise  Department of Chemistry, Dada Patil Mahavidyalaya, Karjat, Ahmednagar, Maharashtra, India
  • Arvind S. Burungale  Department of Chemistry, S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Ramesh B. Gawade  Department of Chemistry, S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Santosh S. Devkate  Department of Chemistry, Mahatma Phule Mahavidyalaya, Panvel, Raigad, Maharashtra, India
  • Sunil D. Jadhav  Department of Chemistry, Dada Patil Mahavidyalaya, Karjat, Ahmednagar, Maharashtra, India
  • Shripad M. Patil  

Keywords:

Conjugate addition, Cyanoester, Cu (I) catalyst, Grignard reagent, Ultrasound irradiation.

Abstract

Treatment of α, β-unsaturated cyanoester with phenyl cadmium bromide, derived from dilithium tetrachloro cadmium (Li2CdCl4) and Grignard reagent in the presence of 10 mol % of Nitratobis (Triphenyl phosphine) Copper (I) i.e. Cu(PPh3)2NO3 catalyst afforded chemoselective conjugated product in high yields.

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International Journal of Scientific Research in Science and Technology

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Published

2018-02-28

Issue

Volume 4, Issue 2, January-February-2018

Section

Research Articles

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How to Cite

[1]
Ashok S. Pise, Arvind S. Burungale, Ramesh B. Gawade, Santosh S. Devkate, Sunil D. Jadhav, Shripad M. Patil, " Ultrasound Assisted Nitratobis (Triphenyl phosphine) Copper (I) catalyzed Addition of Organocadmium Reagents to α, β-Unsaturated Cyanoester, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 4, Issue 2, pp.121-124, January-February-2018.