Determination of Extraction Efficiency of Different Solvents for Organic Carbon Content in Biomass Combustion Aerosols

Authors

  • Anupam Pragya  National Institute of Technology Warangal, Telangana, India
  • Sahu S. K  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India
  • Tiwari M.  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India
  • Rathod T. D.  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India
  • Bhangare R. C.  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India
  • Ajmal P. Y.  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India
  • Ajey Kumar Patel  National Institute of Technology Warangal, Telangana, India
  • Pandit G. G.  Bhabha Atomic Research Centre, Trombay, Mumbai, Maharashtra, India

Keywords:

Abstract

Biomass combustion is a major source of organic carbon (OC) aerosols found in the atmosphere. In this study OC generated from biomass combustion was sampled and treated with different solvents to determine their extraction efficiency. Commonly used biomass fuels (wood and dung cake) were combusted in a temperature controlled chamber and the generated aerosols were sampled on Quartz filter paper. The dried filter paper pieces were analysed for their OC content in Total Carbon and Nitrogen Analyzer (PrimacsSNC, Skalar). From the obtained OC data extraction efficiencies were determined. The extraction process was repeated with four different solvents viz. deionised water, hexane, acetone and methanol. The extraction efficiency of each solvent was determined using difference in OC of filter paper before and after extraction. Extraction efficiency for OC samples obtained from wood combustion in water, hexane, acetone and methanol were 54, 30, 83 and 92 % respectively. And for dung cake, it is observed as 20, 37, 76 and 80 % respectively. The extraction efficiency depended on the polarity index of the solvent used.

References

  1. Gelencser, Andras.,2005 Carbonaceous aerosol. Vol. 30. Springer Science & Business Media.
  2. Y. Chen and T.C. Bond,2010 atmospheric chemistry and physics,10,1773-1787.
  3. Bond, T. C., Streets, D. G. et al., 2004. Journal of Geophysical Research-Atmospheres, 109, D14203, 10.1029/2003jd003697.
  4. Tianhai Cheng, Yu Wu et al., 2015. Optics express, 23(8), 10808-10821.
  5. Ramanathan et al., 2001. Journal of Geophysical Research: Atmospheres, 106(D20), 24097-24105.
  6. Chemistry of atmospheric Brown Carbon, Alexander Laskin, Julia Laskin, and Sergey A. Nizkorodov; 2015.
  7. Molnar A., Meszaros, E. et al.,1999 Atmospheric Environment, 33, 2745-2750.
  8. Murphy D. M., Cziczo D. J. et al., 2006 Journal of Geophysical Research., 111, D23S32, doi:10.1029/2006JD007340.
  9. Alexander Laskin, Julia Laskin et al., 2015. Chemical reviews 115.10 (2015): 4335-4382.
  10. Andreae, M. O., and Gelencser, A, 2006, Atmospheric Chemistry and Physics, 6, 3131-3148.
  11. Feng Y.; Ramanathan, V.; Kotamarthi et al., 2013, Atmospheric Chemistry and Physics, 8607.
  12. Yang, M.; Howell, S.G.; Zhuang, J. et al.; 2009, Atmospheric Chemistry and Physics 9,2035.
  13. Liousse C., Penner, J. E., Chuang, C. et al.,1996 Walton, J. J., Journal of Geophysical Research 101, 19411??? 19432.
  14. Y. Chen and T.C. Bond,2010 atmospheric chemistry and physics,10,1773-1787.
  15. Roden, Christoph A. Parameterizing Climate-Relevant Properties of Biofuel and Biomass Particulate Emissions Based on Combustion Conditions. Diss. University of Illinois at Urbana-Champaign, 2008.
  16. Polidori, Andrea, Barbara J. Turpin, Cliff I. Davidson, Lisa A. Rodenburg, and Francesco Maimone. "Organic PM 2.5: fractionation by polarity, FTIR spectroscopy, and OM/OC ratio for the Pittsburgh aerosol." Aerosol Science and Technology 42, no. 3 (2008): 233-246.
  17. Chen, Y.; Bond, T.C. 2012, atmospheric chemistry and physics 12,6067, Zhang, X; Lin, Y.H.; Surratt, J.D.; Weber, R. J. Environ. Sci. Technol. 2013, 47,3685.

Downloads

Published

2018-03-10

Issue

Section

Research Articles

How to Cite

[1]
Anupam Pragya, Sahu S. K, Tiwari M., Rathod T. D., Bhangare R. C., Ajmal P. Y., Ajey Kumar Patel, Pandit G. G., " Determination of Extraction Efficiency of Different Solvents for Organic Carbon Content in Biomass Combustion Aerosols, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 4, Issue 4, pp.92-96, March-April-2018.