Studies on Biosorption of Alizarin Red Dye onto Borassus Powder and Optimization Through Central Composite Design

Authors

  • Dr. Ch. A. I. Raju  Assistant Professor (Stage 3), Department of Chemical Engineering, Andhra University, Visakhapatnam, Andhra Pradesh, India
  • P. Jagadeesh  Research Scholar Department of Chemical Engineering,Andhra University, Visakhapatnam, Andhra Pradesh, India

Keywords:

Alizarine red dye, Borassus, RSM, CCD, kinetics.

Abstract

This work presents an alternative methodology for removal of a dyestuff Alizarin Red from aqueous solutions by using a new biosorbent, Borassus powder in a batch biosorption technique. The characterization of the biosorbent was performed by using FTIR and XRD techniques. The parameters investigated includes, agitation time, biosorbent size, pH, initial concentration of dye, dosage of biosorbent and temperature. The Kinetic study incorporated lagergren first order and pseudo second order models. The study also included thermodynamics and isotherms like Langmuir, Freundlich and Temkin. The experimental data was correlated for regression analysis and the data was very well fitted.

References

  1. J.A.S. Tenorio, D.C.R. Espinosa, Treatment of chromium plating process effluents with ion exchange resins, Waste Manage. 21 (2001) 637–642.
  2. M.M. Matlock, B.S. Howerton, D.A. Atwood, Chemical precipitation of heavy metals from acid mine drainage, Water Res. 36 (2002) 4757– 4764.
  3. L. Koene, L.J.J. Janssen, Removal of nickel from industrial process liquids, Electrochem. Acta 47 (2001) 695–703.
  4. Y. Benito, M.L. Ruiz, Reverse osmosis applied to metal finishing wastewater, Desalination 142 (2002) 229–234.
  5. B. Volesky, Z.R. Holan, Biosorption of heavy metals, Biotechnol. Prog. 11 (1995) 235–250.
  6. A. Kapoor, T. Viraraghavan, Fungal biosorption—an alternative treatment option for heavy metal bearingwastewaters: a review, Bioresource Technol. 53 (1995) 195–206.
  7. F. Veglio, F. Beolchini, Removal of metals by biosorption: a review, Hydrometallurgy 44 (1997) 301–316.
  8. S. Altenor, M.C. Ncibi, E. Emmanuel, S. Gaspard, "Textural characteristics, physiochemical properties and adsorption efficiencies of Caribbean alga Turbinaria turbinata and its derived carbonaceous materials for water treatment application”, Biochemical Engineering Journal 67 (2012) 35– 44
  9. Simeonova A, Godjevargova T, Ivanova D. Biosorption of heavy metals by dead Streptomyces fradiae. Environ Eng Sci 2008; 25:627–34.
  10. Han R, Li H, Li Y. Biosorption of copper and lead ions by waste beer yeast. J Hazard Mater 2006; 137:1569–76.
  11. Fu Y, Viraraghavan T. Dye biosorption sites in Aspergillus niger. Bioresour Technol 2002; 82:139–45.
  12. Asku Z, Donmez G. A comparative study on the biosorption characteristics of some yeast for Remazol Blue reactive dye. Chemosphere 2003; 50:1075–83.
  13. Calace N, Nardi E, Petronio BM. Adsorption of phenols by papermill sludges. Environ Pollut 2002; 118:315–9.
  14. Daughney CJ, Fein JB. Sorption of 2,4,6-trichlorophenol by Bacillus subtilis, Environ Sci Technol 1998;32:749–52.
  15. Lievremont D, Seigle-murandi FB, Benoit-guyod JL. Removal of PCNB from aqueous solution by a fungal adsorption process. Water Res 1998; 32:3601–6.
  16. Vijayaraghavan K, Yun Y. Bacterial biosorbents and biosorption. Biotechnol Adv 2008; 26:266–91.
  17. Chattopadhyaya G, Macdonald DG, Bakhshi NN, Mohammadzadeh JSS, Dalai AK. Adsorptive removal of sulfur dioxide by saskatchewan lignite and its derivatives. Fuel 2006; 85:1803–10.
  18. Bashkova S, Bagreev A, Locke DC, Bandosz TJ. Adsorption of SO2 on sewage sludge-derived materials. Environ Sci Technol 2001; 35:3263–9.
  19. Xu L, Guo J, Jin F, Zeng H. Removal of SO2 from O2-containing flue gas by activated carbon fiber (ACF) impregnated with NH3. Chemosphere 2006;62: 823–6.
  20. Mangun CL, Debarr JA, Economy J. Adsorption of sulfur dioxide on ammoniatreated activated carbon fibers. Carbon 2001; 39:1689–96.
  21. Gaur V, Asthana R, Verma N. Removal of SO2 by activated carbon fibers in the presence of O2 and H2O. Carbon 2006; 44:46–60.
  22. Hameed, B. H., A. A. Ahmad, and N. Aziz. "Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash." Chemical Engineering Journal 133, no. 1-3 (2007): 195-203.
  23. Chuah, T. G., A. Jumasiah, I. Azni, S. Katayon, and SY Thomas Choong. "Rice husk as a potentially low-cost biosorbent for heavy metal and dye removal: an overview." Desalination 175, no. 3 (2005): 305-316.
  24. Hameed, B. H., and A. A. Ahmad. "Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass." Journal of hazardous materials164, no. 2-3 (2009): 870-875.
  25. Lorenc-Grabowska, Ewa, and Grazyna Gryglewicz. "Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon." Dyes and pigments 74, no. 1 (2007): 34-40.
  26. Ahmad, Rais, and Rajeev Kumar. "Adsorption studies of hazardous malachite green onto treated ginger waste." Journal of environmental management 91, no. 4 (2010): 1032-1038.
  27. Mall, Indra Deo, Vimal Chandra Srivastava, Nitin Kumar Agarwal, and Indra Mani Mishra. "Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses." Colloids and Surfaces A: Physicochemical and Engineering Aspects 264, no. 1-3 (2005): 17-28.
  28. Ofomaja, Augustine E. "Kinetic study and sorption mechanism of methylene blue and methyl violet onto mansonia (Mansonia altissima) wood sawdust." Chemical Engineering Journal 143, no. 1-3 (2008): 85-95.
  29. Mckay, Gordon, M. El Geundi, and M. M. Nassar. "Equilibrium studies during the removal of dyestuffs from aqueous solutions using bagasse pith." Water research 21, no. 12 (1987): 1513-1520.
  30. Vogel, R., P. Hoyer, and H. Weller. "Quantum-sized PbS, CdS, Ag2S, Sb2S3, and Bi2S3 particles as sensitizers for various nanoporous wide-bandgap semiconductors." The Journal of Physical Chemistry 98, no. 12 (1994): 3183-3188.
  31. Annadurai, G., and M. R. V. Krishnan. "Adsorption of acid dye from aqueous solution by chitin: Equilibrium studies." (1997).
  32. Li, Yanhui, Qiuju Du, Tonghao Liu, Xianjia Peng, Junjie Wang, Jiankun Sun, Yonghao Wang et al. "Comparative study of methylene blue dye adsorption onto activated carbon, graphene oxide, and carbon nanotubes." Chemical Engineering Research and Design 91, no. 2 (2013): 361-368.
  33. Mittal, Alok, Jyoti Mittal, Arti Malviya, Dipika Kaur, and V. K. Gupta. "Decoloration treatment of a hazardous triarylmethane dye, Light Green SF (Yellowish) by waste material adsorbents." Journal of Colloid and Interface Science 342, no. 2 (2010): 518-527.
  34. Alpat, Sibel K?l?nç, ozge ozbayrak, ?enol Alpat, and Husamettin Akçay. "The adsorption kinetics and removal of cationic dye, Toluidine Blue O, from aqueous solution with Turkish zeolite." Journal of hazardous materials 151, no. 1 (2008): 213-220.
  35. Demirbas, E., M. Kobya, and M. T. Sulak. "Adsorption kinetics of a basic dye from aqueous solutions onto apricot stone activated carbon." Bioresource technology 99, no. 13 (2008): 5368-5373.
  36. Mittal, Atul K., and S. K. Gupta. "Biosorption of cationic dyes by dead macro fungus Fomitopsis carnea: batch studies." Water science and technology 34, no. 10 (1996): 81-87.
  37. Gulnaz, Osman, Aysenur Kaya, and Sadik Dincer. "The reuse of dried activated sludge for adsorption of reactive dye." Journal of Hazardous Materials 134, no. 1-3 (2006): 190-196.
  38. Aksu, Zumriye, and Gonul Donmez. "A comparative study on the biosorption characteristics of some yeasts for Remazol Blue reactive dye." Chemosphere 50, no. 8 (2003): 1075-1083.
  39. Lian, Lili, Liping Guo, and Chunjing Guo. "Adsorption of Congo red from aqueous solutions onto Ca-bentonite." Journal of Hazardous Materials 161, no. 1 (2009): 126-131.
  40. Mohammadi, Nourali, Hadi Khani, Vinod Kumar Gupta, Ehsanollah Amereh, and Shilpi Agarwal. "Adsorption process of methyl orange dye onto mesoporous carbon material–kinetic and thermodynamic studies." Journal of colloid and interface science 362, no. 2 (2011): 457-462.
  41. Daneshvar, N., H_ Ashassi-Sorkhabi, and A. Tizpar. "Decolorization of orange II by electrocoagulation method." Separation and purification Technology 31, no. 2 (2003): 153-162.
  42. Oladoja, N. A., C. O. Aboluwoye, Y. B. Oladimeji, A. O. Ashogbon, and I. O. Otemuyiwa. "Studies on castor seed shell as a sorbent in basic dye contaminated wastewater remediation." Desalination 227, no. 1-3 (2008): 190-203.
  43. Yasin, Yamin, Mohd Zobir Hussein, and Faujan Hj Ahmad. "Adsorption of methylene blue onto treated activated carbon." Malaysian Journal of analytical sciences 11, no. 2 (2007): 400-406.
  44. ALzaydien, Atef S. "Adsorption of methylene blue from aqueous solution onto a low-cost natural Jordanian Tripoli." American Journal of Applied Sciences 6, no. 6 (2009): 1047.
  45. Hameed, B. H. "Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent." Journal of hazardous materials 162, no. 1 (2009): 344-350.
  46. Wang, Qi, Zhaokun Luan, Ning Wei, Jin Li, and Chengxi Liu. "The color removal of dye wastewater by magnesium chloride/red mud (MRM) from aqueous solution." Journal of hazardous materials 170, no. 2-3 (2009): 690-698.
  47. Lian, Lili, Liping Guo, and Chunjing Guo. "Adsorption of Congo red from aqueous solutions onto Ca-bentonite." Journal of Hazardous Materials 161, no. 1 (2009): 126-131.
  48. Mohammadi, Nourali, Hadi Khani, Vinod Kumar Gupta, Ehsanollah Amereh, and Shilpi Agarwal. "Adsorption process of methyl orange dye onto mesoporous carbon material–kinetic and thermodynamic studies." Journal of colloid and interface science 362, no. 2 (2011): 457-462.
  49. Ho, Yuh-Shan, Chun-Chiao Chiang, and Yung-Chien Hsu. "Sorption kinetics for dye removal from aqueous solution using activated clay." Separation Science and Technology 36, no. 11 (2001): 2473-2488.
  50. Alkan, Mahir, ozkan Demirba?, Sermet Celikcapa, and Mehmet Dogan. "Sorption of acid red 57 from aqueous solution onto sepiolite." Journal of Hazardous Materials 116, no. 1-2 (2004): 135-145.
  51. McKay, Gordon. "Adsorption of dyestuffs from aqueous solutions with activated carbon I: Equilibrium and batch contact-time studies." Journal of chemical technology and biotechnology 32, no. 7-12 (1982): 759-772.
  52. Gimbert, Frédéric, Nadia Morin-Crini, François Renault, Pierre-Marie Badot, and Grégorio Crini. "Adsorption isotherm models for dye removal by cationized starch-based material in a single component system: error analysis." Journal of Hazardous Materials 157, no. 1 (2008): 34-46.
  53. Xue, Yongjie, Haobo Hou, and Shujing Zhu. "Adsorption removal of reactive dyes from aqueous solution by modified basic oxygen furnace slag: isotherm and kinetic study." Chemical Engineering Journal 147, no. 2-3 (2009): 272-279.
  54. Ho, Y. S., and C. C. Wang. "Pseudo-isotherms for the sorption of cadmium ion onto tree fern." Process Biochemistry 39, no. 6 (2004): 761-765.
  55. Porter, J. F., G. McKay, and K. H. Choy. "The prediction of sorption from a binary mixture of acidic dyes using single-and mixed-isotherm variants of the ideal adsorbed solute theory." Chemical Engineering Science 54, no. 24 (1999): 5863-5885.
  56. Sivaraj, Rajeshwari, C. Namasivayam, and K. Kadirvelu. "Orange peel as an adsorbent in the removal of acid violet 17 (acid dye) from aqueous solutions." Waste management 21, no. 1 (2001): 105-110.
  57. Walker, G. M., L. Hansen, J-A. Hanna, and S. J. Allen. "Kinetics of a reactive dye adsorption onto dolomitic sorbents." Water Research 37, no. 9 (2003): 2081-2089.
  58. Tan, I. A. W., B. H. Hameed, and A. L. Ahmad. "Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon." Chemical Engineering Journal 127, no. 1-3 (2007): 111-119.
  59. Al-Ghouti, M., M. A. M. Khraisheh, M. N. M. Ahmad, and S. Allen. "Thermodynamic behaviour and the effect of temperature on the removal of dyes from aqueous solution using modified diatomite: a kinetic study." Journal of Colloid and Interface Science 287, no. 1 (2005): 6-13.
  60. Hameed, B. H., A. A. Ahmad, and N. Aziz. "Isotherms, kinetics and thermodynamics of acid dye adsorption on activated palm ash." Chemical Engineering Journal 133, no. 1-3 (2007): 195-203.
  61. Wang, Li, Jian Zhang, Ran Zhao, Cong Li, Ye Li, and Chenglu Zhang. "Adsorption of basic dyes on activated carbon prepared from Polygonum orientale Linn: equilibrium, kinetic and thermodynamic studies." Desalination 254, no. 1-3 (2010): 68-74.
  62. Kyzas, George Z., Nikolaos K. Lazaridis, and Athanassios Ch Mitropoulos. "Removal of dyes from aqueous solutions with untreated coffee residues as potential low-cost adsorbents: Equilibrium, reuse and thermodynamic approach." Chemical engineering journal 189 (2012): 148-159.
  63. Wang, Lianggui. "Application of activated carbon derived from ‘waste’bamboo culms for the adsorption of azo disperse dye: Kinetic, equilibrium and thermodynamic studies." Journal of Environmental Management 102 (2012): 79-87.
  64. Boparai, Hardiljeet K., Meera Joseph, and Denis M. O’Carroll. "Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zerovalent iron particles." Journal of hazardous materials 186, no. 1 (2011): 458-465.
  65. El-Latif, MM Abd, Amal M. Ibrahim, and M. F. El-Kady. "Adsorption equilibrium, kinetics and thermodynamics of methylene blue from aqueous solutions using biopolymer oak sawdust composite." J. Am. Sci 6, no. 6 (2010): 267-283.
  66. Kayranli, Birol. "Adsorption of textile dyes onto iron based waterworks sludge from aqueous solution; isotherm, kinetic and thermodynamic study." Chemical Engineering Journal173, no. 3 (2011): 782-791.
  67. Alslaibi, Tamer M., Ismail Abustan, Mohd Azmier Ahmad, and Ahmad Abu Foul. "Application of response surface methodology (RSM) for optimization of Cu2+, Cd2+, Ni2+, Pb2+, Fe2+, and Zn2+ removal from aqueous solution using microwaved olive stone activated carbon." Journal of Chemical Technology and Biotechnology 88, no. 12 (2013): 2141-2151.
  68. Kafshgari, Leila Asadi, Mohsen Ghorbani, Asghar Azizi, Shilpi Agarwal, and Vinod Kumar Gupta. "Modeling and optimization of Direct Red 16 adsorption from aqueous solutions using nanocomposite of MnFe2O4/MWCNTs: RSM-CCRD model." Journal of Molecular Liquids 233 (2017): 370-377.
  69. Pi, Ke-Wu, Qu Xiao, Hui-Qin Zhang, Min Xia, and Andrea R. Gerson. "Decolorization of synthetic methyl orange wastewater by electrocoagulation with periodic reversal of electrodes and optimization by RSM." Process safety and environmental protection 92, no. 6 (2014): 796-806.
  70. Remenarova, Lucia, Martin Pipiska, Eva Florkova, Miroslav Hornik, Marian Rozlo?nik, and Jozef Augustin. "Zeolites from coal fly ash as efficient sorbents for cadmium ions." Clean Technologies and Environmental Policy 16, no. 8 (2014): 1551-1564.
  71. Ahmady-Asbchin, Salman, Reza Tabaraki, Naser Jafari, Abdollah Allahverdi, and Ashkan Azhdehakoshpour. "Study of nickel and copper biosorption on brown algae Sargassum angustifolium: application of response surface methodology (RSM)." Environmental technology 34, no. 16 (2013): 2423-2431.
  72. Khatri, Rajesh A., Steven SC Chuang, Yee Soong, and McMahan Gray. "Carbon dioxide capture by diamine-grafted SBA-15: A combined Fourier transform infrared and mass spectrometry study." Industrial & Engineering Chemistry Research 44, no. 10 (2005): 3702-3708.
  73. Bhargava, Rohit. "Towards a practical Fourier transform infrared chemical imaging protocol for cancer histopathology." Analytical and bioanalytical chemistry 389, no. 4 (2007): 1155-1169.
  74. Wahab, Mohamed Ali, Salah Jellali, and Naceur Jedidi. "Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling." Bioresource Technology101, no. 14 (2010): 5070-5075.
  75. Thistlethwaite, P. J., and M. S. Hook. "Diffuse reflectances Fourier transform infrared study of the adsorption of oleate/oleic acid onto titania." Langmuir 16, no. 11 (2000): 4993-4998.
  76. Wang, Yan, Koichi Murayama, Yoshiki Myojo, Roumiana Tsenkova, Nobuyuki Hayashi, and Yukihiro Ozaki. "Two-dimensional Fourier transform near-infrared spectroscopy study of heat denaturation of ovalbumin in aqueous solutions." The Journal of Physical Chemistry B 102, no. 34 (1998): 6655-6662.
  77. Qu, Lianhua, and Xiaogang Peng. "Control of photoluminescence properties of CdSe nanocrystals in growth." Journal of the American Chemical Society 124, no. 9 (2002): 2049-2055.
  78. Huang, Chih-Hung, Kai-Ping Chang, Hong-De Ou, Yu-Chun Chiang, E-E. Chang, and Chu-Fang Wang. "Characterization and application of Ti-containing mesoporous silica for dye removal with synergistic effect of coupled adsorption and photocatalytic oxidation." Journal of hazardous materials 186, no. 2-3 (2011): 1174-1182.
  79. Wang, Guoxiu, Juan Yang, Jinsoo Park, Xinglong Gou, Bei Wang, Hao Liu, and Jane Yao. "Facile synthesis and characterization of graphene nanosheets." The Journal of Physical Chemistry C 112, no. 22 (2008): 8192-8195.
  80. Liu, Wen, Ting Wang, Alistair GL Borthwick, Yanqi Wang, Xiaochen Yin, Xuezhao Li, and Jinren Ni. "Adsorption of Pb2+, Cd2+, Cu2+ and Cr3+ onto titanate nanotubes: Competition and effect of inorganic ions." Science of the Total Environment456 (2013): 171-180.
  81. Zhang, Xi, Lizhi Zhang, Tengfeng Xie, and Dejun Wang. "Low-temperature synthesis and high visible-light-induced photocatalytic activity of BiOI/TiO2 heterostructures." The Journal of Physical Chemistry C 113, no. 17 (2009): 7371-7378.
  82. Liang Lva, Jing Hea, Min Weia, D.G. Evansa, Xue Duan, "Uptake of chloride ion from aqueous solution by calcined layered double hydroxides: equilibrium and kinetic studies", Water Research, 40:4, 2006, 735-743.
  83. Gupta V.K and Rastogi A, "Biosorption of SCB dye from aqueous solutions by green algae spirogyra species: Kinetics and equilibrium studies”, Journal of Hazardous Materials, 152: 2008, 407–414.
  84. Flavio A. Pavan, Ana C. Mazzocato, Rosangela A. Jacques, Silvio L.P. Dias, "Ponkan peel A potential biosorbent for removal of Pb(II) ions from aqueous solution”, Biochemical Engineering Journal, 40: 2008, 357–362.

Downloads

Published

2018-06-30

Issue

Section

Research Articles

How to Cite

[1]
Dr. Ch. A. I. Raju, P. Jagadeesh, " Studies on Biosorption of Alizarin Red Dye onto Borassus Powder and Optimization Through Central Composite Design , International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 4, Issue 8, pp.255-274, May-June-2018.