Catalytic Synthesis Of Tetraazamacrocyclic Complexes Using Silica Supported Perchloric Acid (Hclo4-Sio2) At Room Temperature

Authors

  • Pradip Bajirao Wagh  School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, Maharashtra, India
  • Dnyaneshwar Shamrao Wankhede  School of Chemical Sciences, Swami Ramanand Teerth Marathwada University, Nanded, Maharashtra, India

Keywords:

Isatin, ethylenediamine, octahedral, powder x-ray analysis, antimicrobial activity.

Abstract

Catalytic synthesis of a series of twelve tetraazamacrocyclic complexes of first row transition metals such as Co(II), Ni(II), Cu(II) and Zn(II) was carried out using chloride, nitrate and acetate salts of metals, isatin and ethylenediamine in ethanolic medium using silica supported perchloric acid (HClO4-SiO2) as catalyst. The use of catalyst has avoided the traditional reflux method and facilitated the synthesis of complexes within shorter period of time at room temperature. The synthesized complexes have been characterized with the help of molar conductance, magnetic susceptibility measurements, IR, electronic, 1H-NMR, mass spectra, thermogravimetric (TGA) curve and powder x-ray analysis. Based on the results obtained a six coordinated octahedral geometry has been proposed for all these complexes. The synthesized complexes were also tested for antimicrobial activity.

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International Journal of Scientific Research in Science and Technology

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Published

2018-01-30

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Volume 4, Issue 1, January-February-2018

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Research Articles

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How to Cite

[1]
Pradip Bajirao Wagh, Dnyaneshwar Shamrao Wankhede, " Catalytic Synthesis Of Tetraazamacrocyclic Complexes Using Silica Supported Perchloric Acid (Hclo4-Sio2) At Room Temperature, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 4, Issue 1, pp.397-404, January-February-2018.