The Development of PVA Based Proton Conducting Solid Polymer Composite Electrolyte System
DOI:
https://doi.org/10.32628/IJSRST.RAMAN2181Keywords:
Nano Composite System, XRD, polymer blend, proton conductivity.Abstract
In this Study the attempt was to improve the proton conductivity by dispersing the Nano sized GDC to obtain (100-x) (80PVA:20AN) (x)(GDC) Nano-composite system. X-ray diffraction (XRD) study shows that the addition of filer GDC in polymer not only reduces the intensity of the characteristic (110) peak but also broadens which is an indication of the increase in amorphousness. The Arrhenius plots for different concentrations of GDC in (80PVA:20AN) polymer blend shows the initial increase in ionic conductivity of the composite polymer electrolyte upto 20 wt% filler GDC. The proton conductivity increases with increased relative humidity within entire studied range of H2 partial pressures.
References
- C. C. Liang, J. Electrochem. Soc., 120 (1973) 1289.
- J. B. Wagner, Mater. Res. Bull., 15 (1980) 1691.
- K. Shahi and J. B. Wagner, Jr., J. Electrochem. Soc., 128 (1981) 6.
- O. Nakamura and J. B. Goodenough, Solid State Ionics, 7 (1982) 119.
- F. W. Poulsen, N. H. Andersen, B. Kindle and J. Scoonman, Solid State Ionics, 9/10 (1983) 131.
- T. Jow and J. B. Wagner, Jr., J. Electrochem. Soc., 135 (1988) 529.
- D. Stauffer, in Introduction to Percolation, Eds. Taylor and Francis, (London), (1985).
- R. Bouchet, E. Siebert, G. Vitter, J ElectrochemSoc 144(1997)L95-7.
- H. Pu, M. Luo and Z. Yang, Euro. Polym.J., 43 (2007) 5076.
- Z. Peng and L. X. Kong, Polym. Degrad. Stab., 92 (2007) 1061
- N. Chand, N. Rai, T. S. Natarajan and S. L. Agrawal, Fibers and Polym., 12 (2011) 438.
- Lord Raleigh, Phil. Mag. 34(1892) 481.
- M. A. K. L. Dissaanayake, P. A. R. D. Jayathilaka, R. S. P. Bokalawala, I. Albinsson and B. E. Mellander, J. Power Sources, 119-121 (2003) 409
- J. Fleig and J. Maier, Solid State Ionics, 85 (1996) 9.
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