Dielectric Relaxation Study of Liquid Polymers of Ethylene glycol oligomers using Picosecond Time Domain Reflectometry
DOI:
https://doi.org/10.32628/IJSRST.RAMAN2181Keywords:
Polymers, Dielectric Relaxation, time domain reflectometry, static dielectric constant (e0), high frequency permittivity (e¥) , relaxation time (t) etc.
Abstract
The dielectric relaxation measurement of polymers in water mixtures have been carried out over entire concentrations, at temperatures 250C using picoseconds time domain reflectometry technique in the frequency range of 10 MHz to 30 GHz. The complex permittivity spectra of polymer - water mixtures were fitted using Havriliak-Negami equation. The static dielectric constant (e0), high frequency permittivity (e¥) and relaxation time(t) for all concentrations have determined using least square fit method. The variations in dielectric parameters with molecular size is studied.
References
- Zamir S. Khan, M.P.Lokhande, Avadhut Deshmukh and A.C.Kumbharkhane, Journal of Advanced Dielectrics, Vol.10, No.03,2050004(2020).
- A. A. Sonkamble , S.M. Dongarge , M. Malathi and U.V. Biradar, International Journal of Scintific Research in Physics and Applied Sciences, Vol.8, issue 4, pp 13-17 (2020).
- S. X. Drakopoulos, J. Karger-Kocsis, A. Kmetty, L. Lendvai, G. C. Psarras, Carbohydrate Polymers ,Vol.157, 711-718(2017).
- Abdulrahman W. Pathan & Ashok C Kumbharkhane,Physics and chemistry of liquids: An International Journal Vol.55, issue 2, 179-185(2017).
- S D Chavan, B D Watode, P G Hudge, D B Suryawanshi, C G Akode, A C Kumbharkhane and S C Mehrotra, Indian J.of Physics.84(3),275(2010).
- Arvind V Sarode and Ashok C Kumbharkhane, Journal of Molecular Liquids 160, 109 (2011).
- Y S Joshi and A C Kumbharkhane, Journal of Molecular Liquids 161, 120 (2011).
- P. Debye, Polar Molecules, Chemical Catlog Company,New York(1929).
- P B Undre, P W Khirade, S B Jagdale, S N Helambe and S C Mehrotra, Lithuanian Journal of Physics, Vol 51, No.2, 147 (2011).
- S.D. Chavan, A.C. Kumbharkhane, S.C. Mehrotra, J. Chin. Chem. Soc. 54, 1457(2007)
- S Havriliak and S Negami, J. Polym. Sci. 14, 91 (1966).
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