The Different Phases of Lithium Sulphate and Its Transition at Different Temperature
Keywords:
Lithium Sulfate, Phase TransitionAbstract
The present review is focused on Li2SO4 salt and its different temperature phases. The enhancement in the conductivity with addition of different compounds in it has been observed by many researchers. Lithium sulphate is a material that has received quite a bit of attention in recent years. It is an ionic salt, presenting a reversible solid-solid phase transition (monoclinic ± FCC) at a relatively high temperature (5780C). The high temperature form of lithium sulfate is a plastic (rotator) phase, presenting an unusually high ionic conductivity, deserving therefore the name of solid electrolyte. From the practical point of view its importance may rest on its application as an electrolyte for high-energy batteries, or as a stable nontoxic material for thermal energy storage.
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