Novel Interacting Blends Based on Acryl Terminated Oligoimides Using Bismalamide with Michael Addition Reaction

Authors

  • Dr. Rita R. Patel  P.B. Science College, Kapadwanj Gujarat, India

Keywords:

Amino terminated oligomides (AOIs), Acryl end capped oligoimides (AcOIs), Acryl amide and AIBN and glass fiber reinforced composites, Michael addition reaction.

Abstract

New amino terminated oligoimides (AOIs) were prepared by the Michael addition reaction of various bismaleimide (1), namely 1-(4-((4-((2,5-dioxocyclopent-3 enylamino)methyl)cyclohexyl)methyl) cyclohexyl)-1,6-dihydropyridine-2,5-dione with excess of various diamines(2a-c). Characterization of these AOIs was carried out by elemental analysis, FT-IR spectral studies and number average molecular weight estimated by non-aqueous conductometric titrations. After the treatment of AOIs with acrylol chloride and resultant acryl terminated oligoimides (AcOIs) samples were also characterized thermogravimetrically. Each of these AcOI was then combined with the N-phenyl maleimide (PM) in THF solvent. The resultant suspensions were then heated in the presence of azobisisobutyronitrile (AIBN) as an initiator. The AcOI and PM polymerized through double bond simultaneously and form interacting blends, which were analyzed thermogravimetrically. The glass fiber reinforced composites were fabricated by using the suspensions of the AcOI and PM. The composites of Interacting blends were analyzed for their mechanical, chemical and electrical properties.

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International Journal of Scientific Research in Science and Technology

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Published

2017-10-30

Issue

Volume 3, Issue 7, September-October-2017

Section

Research Articles

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How to Cite

[1]
Dr. Rita R. Patel, " Novel Interacting Blends Based on Acryl Terminated Oligoimides Using Bismalamide with Michael Addition Reaction, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 3, Issue 7, pp.1305-1312, September-October-2017.