Crystallization and Characterization of Zinc Thiourea Sulphate Doped Triglycine Sulphophosphate Single Crystals

Authors

  • Dr. T. S. Jayanthi   Associate Professor, Department of Physics, Vivekananda College, Agasteeswaram-629701, Kanniyakumari District, Tamilnadu, India

Keywords:

Optical Communication, Triglycinesulphophosphate, Semiorganic, Zinc Thiourea Sulphate, Potassium Dihydrogen Ortho Phosphate

Abstract

The rapid development of optical communication system has led to a demand for non-linear optical materials. Phosphorus substituted Triglycinesulphate is a ferroelectric material suitable for infra ray detectors. In the present study an attempt has been made to crystallize Triglycinesulphophosphate single crystals doped Zinc thiourea sulphate. The effect of the dopant on the crystal habit and Non-Linear Optical property has been investigated. Habit modification was observed in the doped crystal. The NLO property of the doped TGSP was enhanced 2 times greater than the standard Potassium dihydrogen Ortho phosphate.

References

  1. B. T. Mathias, C. E. Miller and J.P.Remeika,Phy.Rev.104 ,pp.849(1956).
  2. Hoshino S.Okaya Y. and PepinskyR,’Crystal structure of the ferroelectric phase of (Glycine)3H2SO4’,Phys.Rev.115,pp.323-330(1959).
  3. Fang C.S.,Yao X.,Bhalla A.S. and Cross L.E.’The growth and properties of a new alanine and phosphate substituted triglycinesulphate(ATGSP)crystal’,Ferroelectrics.51,pp.9-13(1983).
  4. Wang O.W. and Fang C.S’Investigation of the solution status of TGS and ATGSP crystals crystals’,Cryst.Res.Technol.21,pp.245-251(1992).
  5. Ravi G.,Anbukumar S. and RamasamyP,’Growth and Characterization of triglycinesulpho- phosphate mixed crystals’,Mater.Chem.Phys.37,pp.180-183(1994a).
  6. Stankowska J. and JasinskiT,’The influence of rejuvenation process on dielectric properties of LATGS crystals’,Acta Phys.Pol.A.70,pp.559-563(1986).
  7. Mihaylova E. and StoyanovS.’Ferroelectric behavior of rare earth doped TGS’,Phys.Stat.Sol.(a).154 ,pp.797-802(1996).
  8. Zikumund Z. and FousekJ,’Stabilization of polarization vector in uniaxial ferroelectrics by mean of chiraldopants’,Phys.Stat.Sol.(a).112,pp.625-634(1989).
  9. Ravi G.,Arunmozhi G.,Anbu Kumar S. and RamasamyP.’Influence of macromolecular additives on the characterization of triglycinesulphate single crystals’,Ferroelectrics.174,pp.241- 247(1995).
  10. Wang O.W. and Fang.C.S.’Investigation of the solution status of TGS and ATGSP crystals’,Crys.Res.Technol.27,pp.245-251(1992).
  11. Arunmozhi G.,JayavelR.and Subramanian C.’Growth and Characterization of aminoacids mixed Triglycinesulphophosphate singlecrystals’,Mater.Sci.Engg.B.49,pp.57-62(1997b).
  12. Mihaylova E. and StoyanovS,’Ferroelectric behavior of rare earth doped TGS’,Phys.Stat.Sol.(a).154,pp.797-802(1996).
  13. N.Nakatani,M.Yoshio.,Jpn.J.Appl.Phys.35,pp.5752(1996).
  14. N.Nakatani,M.Yoshio.,Jpn.J.Appl.Phys.35,pp.L508(1996).
  15. Mihaylova E. and Byrne H.J.’Raman Studies of TGS dope with Nd’,J.Phys.Chem.Solids.61,pp.1919-1925(2000).
  16. MuralidharanR.,Mohan Kumar R.,Ushasree P.M.,Jayavel R. and RamasamyP.’Effect of rare earth dopants on the growth and properties of triglycinesulphate single crystals’,J.Crystal Growth.234,pp.545-550(2001).
  17. Drozhdin S.N. and KuyantsevM.A.’Dielectric relaxation indeuteratedtriglycine sulfate crystals’,Phys.Solid State.40,pp.281-287(1998).
  18. Dunning, W.J. and N.Albon.In:Growth and perfection of Crystals(R.H.Doremus,B.W.Roberts and D.Turnbull,eds.), Wiley,New York 411(1958).
  19. G.Arunmozhi,R.Jayavel,C.Subramonian,Materials Letters 54,pp.329-336(2002).
  20. Sarig.s,’Growth Habit Modification by water soluble polymers’,J.Cryst.Growth,24/25,pp.338-341(1974).
  21. Sangwal.K,’Effect of impurities on the process of crystal growth’,J.Cryst.Growth. pp.1224- 1236(1993).
  22. B.Leema Rose and C.GnanaSambandam,’Crystallization and Characterization of Lauric acid doped Triglycinesulphophosphate singlecrystals’,JETIR,5(2018).
  23. D.S.Chemla and J.Zyss :Non-linear optical properties of organic molecules and crystals Academic Press,NewYork,N.Y.,(1987).

International Journal of Scientific Research in Science and Technology

Downloads

Published

2017-06-30

Issue

Volume 3, Issue 4, May-June-2017

Section

Research Articles

License

Copyright (c) IJSRST

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Dr. T. S. Jayanthi "Crystallization and Characterization of Zinc Thiourea Sulphate Doped Triglycine Sulphophosphate Single Crystals" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 3, Issue 4, pp.639-648, May-June-2017.