Synthesis and Characterization of Cerium doped CaMnO3 Nanoparticles

Authors

  • S. Berbeth Mary  Department of Physics, St. Joseph’s College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, India
  • A. Leo Rajesh  Department of Physics, St. Joseph’s College (Autonomous), Tiruchirappalli-620 002, Tamil Nadu, India

Keywords:

calcium manganite, hydrothermal, single phase, pervoskite oxide

Abstract

Nanostructured cerium doped calcium manganite Ca1-xCexMnO3 (x=0.0, 0.1, 0.2, 0.3, 0.4, 0.5) samples were synthesized successfully using the citric acid complexing coupled with hydrothermal method followed by annealing at 900°C. Powder X-ray diffraction (XRD) analysis showed that the single phases of orthorhombic pervoskite structure of CaMnO3 and the cell volume increased from undoped to cerium doped CaMnO3 structure due to the ionic radius of added R3+ cations. The crystallinity decreased with increased concentration of Ce3+ doping and the average crystallite size was about 10-20 nm. Sphere like nanoparticles observed by the scanning electron microscopy. FTIR analysis showed a strong peak around 600 cm-1 revealed the formation of pervoskite oxides and the obtained band gap was 3.56 eV.

References

  1. G. Chen, M. S. Dresselhaus, D. Dresselhaus, J.P. Fleurial, T. Caillat, Int. Mater. Rev., 48, 45 (2003).
  2. J. Pei, G. Chen, N. Zhou, D.Q. Lu, F.Q Xiao, Physica B., 406, 571 (2011)
  3. M.A. Pena, J.L.G. Flerro, Chem. Rev., 101, 7 (2001)
  4. E. Konysheva, J.T.S. Irvine, J. Mater. Chem., 18, 5147 (2008).
  5. F. Azough, C. Leach, R. Freer, J. Eur. Ceram. Soc., 26, 10 (2006).
  6. J. Dho, W.S. Kim, E.O. Chi, N.H. Hur, S.H. Park, H.-C. Ri, Solid State Commun., 125, 143?? (2003)
  7. Michitaka Ohtaki, Hisako Koga, Tsutomu Tokunaga, Koichi Eguchi, Hiromichi Arai, J. Solid State Chem., 120, 105 (1995)
  8. R.V. Mangalaraja, J. Mouzon, P. Hedstr??m, I. Kero, K.V.S. Ramam, C.P. Camurri, M. Od??n, J. Mater. Process. Technol., 208 415 (2008)
  9. N.P. Bansal, J. Mater. Sci. 27, 2922 (1992)
  10. C.S. Sanmathi, Y. Takahashi, D. Sawaki, Y. Klein, R. Retoux, I. Terasaki, J.G. Noudem, Mater. Res. Bull., 45, 558 (2010)
  11. Jianrong Niu, Jiguang Deng, Wei Liu, Lei Zhang, Guozhi Wang, Hongxing Dai, Hong He, Xuehong Zi, Catal. Today., 126, 420 (2007)
  12. Yoshimura M, Yoo S. E,?? Hayashi M, Ishizawa N,?? J. Appl. Phys., 28, 2007 (1989)
  13. Sridhar Komarneni , Young Dong Noh , Joo Young Kim , Seok Han Kim , Hiroaki Katsuki,?? Naturforsch., 65b, 1033 (2010)
  14. A. Pathak , P. Pramanik, Pinsa., 67, 47 (2001)
  15. T. Okuda, Y. Fujii, J. Appl. Phys., 108, 103702 (2010)
  16. D. Sousa, M.R. Nunes, C. Silveira, I. Matos, A.B. Lopes, M.E. Jorge, Mater. Chem. Phys., 109, 311 (2008)
  17. G. Xu, R. Funahashi, Q. Pu, B. Liu, R. Tao, G. Wang, Z. Ding, Solid State Ionics., 171, 147 (2004).
  18. Y.H. Zhu, C.L. Wang, W.B. Su, J.C. Li, J. Liu, Y.L. Du, L.M. Mei, Ceram. Int., 40, 15531 (2014)
  19. Mohamed Mouyane, Brahim Itaalit, J??r??me Bernard, David Houivet, Jacques G. Noudem, Powder Technology.,?? 264 ,71 (2014)
  20. Ma R, Takada K, Fukuda K, Iyi N, Bando Y, Sasaki T, Angew, Chem. Int. Ed., 47, 86 (2008)
  21. Mohamed Mouyane, Brahim Itaalit, Jerome Bernad, David Houuivet, Jacques G Noudem, Powder Tech., 264, 71 (2014)
  22. Millini R, Gagliardi MF, Piro G, J. Mater. Sci., 29, 4065 (1994)
  23. Gaudon M, Laberty-Robert C, Ansart F, Stevens P, Rousset A, Solid State Sci., 4, 125 (2002)
  24. S. Enzo, G. Fagherazzi, A. Benedetti, S. Polizzi, J. Appl. Cryst., 21, 536 (1988)
  25. N.V. Nong, Chia Jyi Liu, M. Othaki, J. Alloys. Compds., 509, 977 (2011)
  26. W. Koshibae, K. Tsutsui, S. Maekawa, Phys. Rev. B., 62, 6869 (2000)
  27. R. Asahi, J. Sugiyama, T. Tani, Phys. Rev. B., 66, 155103 (2002)
  28. R. K. Gupta, C.M. Whang, Solid State Ionics., 178, 1617 (2007)
  29. M. Daturi, G. Busca, R. J. Willey, Chem. Mater., 7, 2115 (1995)
  30. Rizwan Wahab, Young-Soon Kim, Hyung-Shik Shin, Mater.Trans., 50, 2092 (2009)
  31. G. De Marzi, Z. V. Popovic, A. Cantarero, Z. Dohcevic-Mitrovic N.Paunovic, J. Bok, F. Sapina, Phys. Rev. B., 68, 064302 (2003)
  32. K. Rekha, M. Nirmala, Manjula G.Nair, A. Anukaliani, Physica B, Cond Matr., 405, 3180 (2010)
  33. K. Omri, J. El Ghoul , O. M. Lemine, M.?? Bououdina , B. Zhang, L. El Mir, Superlattices and Microstructures., 60, 139 (2013)

International Journal of Scientific Research in Science and Technology

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Published

2017-12-15

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Volume 3, Issue 11, November-December-2017

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Research Articles

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[1]
S. Berbeth Mary, A. Leo Rajesh "Synthesis and Characterization of Cerium doped CaMnO3 Nanoparticles" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 3, Issue 11, pp.140-145, November-December-2017.