CuI.PPh3 Based Functionalized Aromatic Organocopper Reagents Efficient in the Formation of Carbon-Carbon Bond with Epoxides

Authors

  • Santosh S. Devkate  S.M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Arvind S. Burungale  S.M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Sunil D. Jadhav  S.M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Ashok S. Pise  S.M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Ramesh B. Gawade  S.M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Mohan B. Kale  S.M. Joshi College Hadapsar, Pune, Maharashtra, India

Keywords:

Lithium napthalenide, active copper, triphenyl phosphine, napthalene, zero valent

Abstract

We have observed that the lithium napthalenide reduction of solution of CuI.PPh3 complex produced a highly reactive zero valent copper complex. The choice of phosphine based ligand was found to be crucial for the formation of subsequent reactivity of the organocopper species. The aromatic copper reagents derived from aromatic halides reacts with epoxides to form carbon carbon bond which are synthetically useful.

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International Journal of Scientific Research in Science and Technology

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Published

2017-12-31

Issue

Volume 3, Issue 8, November-December-2017

Section

Research Articles

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How to Cite

[1]
Santosh S. Devkate, Arvind S. Burungale, Sunil D. Jadhav, Ashok S. Pise, Ramesh B. Gawade, Mohan B. Kale "CuI.PPh3 Based Functionalized Aromatic Organocopper Reagents Efficient in the Formation of Carbon-Carbon Bond with Epoxides" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 3, Issue 8, pp.998-1001, November-December-2017.