Cu (MeCN) 4BF4 Catalyzed Addition of 2-Pyridylzinc Bromide to Acid Chlorides

Authors

  • Arvind S. Burungale  S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Ramesh B. Gawade  S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Ashok S. Pise  S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Santosh S. Devkate  S. M. Joshi College Hadapsar, Pune, Maharashtra, India
  • Sunil D. Jadhav  M. P. A. C. S.College Panvel, Raigad, Maharashtra, India

Keywords:

Highly Active Zinc Metal, 2-Pyridylzinc Bromide, Acid Chloride , Copper(I) Complex.

Abstract

The 2-pyridylzinc bromide was easily prepared via the direct insertion of active zinc into the corresponding bromopyridines. The subsequent addition reaction of the resulting 2-pyridyl zinc bromide to aryl acid chloride was catalyzed by several copper (I) complex catalyst. we have prepared benzoyl derivatives of pyridine using tetrakis acetonitrile copper (I) tetrafluroborate as efficient catalyst under mild condition.

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International Journal of Scientific Research in Science and Technology

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Published

2017-12-15

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Volume 3, Issue 9, November-December-2017

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Research Articles

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[1]
Arvind S. Burungale, Ramesh B. Gawade, Ashok S. Pise, Santosh S. Devkate, Sunil D. Jadhav "Cu (MeCN) 4BF4 Catalyzed Addition of 2-Pyridylzinc Bromide to Acid Chlorides" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 3, Issue 9, pp.90-94, November-December-2017.