Eggshell Waste : An Efficient Solid Catalyst for the Synthesisof 5-Arylidene Barbituric Acids under Solvent-Free Condition

Authors

  • B. K. Uphade  Research Center, Department of Chemistry, Padmashri Vikhe Patil College of Arts, Science and Commerce, Pravaranagar, India
  • A. G. Gadhave  Research Center, Department of Chemistry, Padmashri Vikhe Patil College of Arts, Science and Commerce, Pravaranagar, India

Keywords:

Chicken eggshell waste, 5-Arylidene barbituric acid derivatives, Green catalyst, Grinding, Solvent free condition.

Abstract

Efficient synthesis of 5-arylidene barbituric acid derivatives in presence of chicken eggshell waste at room temperature with grinding has been reported. Biologically active 5-arylidene barbituric acid derivatives were obtained in high yields (88-96 %) in a short reaction time (2-7 min) under solvent-free condition. This method has advantages such as avoidance of the organic solvents, short reaction times and production of pure products without any by product.

References

  1. J T. Bojarski, J. L. Mokrosz, H. J. Barton, M. H. Paluchowska, Adv. Heterocycl. Chem.,38 (1985) 229.
  2. F H. Ali Bamanie, A. S. Shehata, M. A. Moustafa, M. M. Mashaly, J. American Sci.,8 (2012) 481.
  3. A H. Shamroukh, M. E. Zaki, E. M.Morsy, F. M. Abdel-Motti, F. M. E. Abdel-Megeid, Arch. Pharm. (Weinheim)., 340 (2007) 236.
  4. I O. Zhuravel, S. A. Grashenkova, L. V. Yakovleva, O. V. Borisov, S. M. Kovalenko,V. P. Chernikh,Zh. Org. Khim., 4 (2006) 25.
  5. V K. Ahluwalia, R. Batla, A. Khurana, R. Kumar, Ind. J. Chem. B., 29 (1990) 1141.
  6. Y Frangin, C.Guimbal, F. Wissocq, H. Zamarlik, Synthesis, 12 (1986) 1046.
  7. K Tanaka, X.Chen, F. Yoneda,Tetrahedron, 44 (1988) 3241.
  8. J D. Figueroa-Villar,C. E. Rangel, L. N. Dos Santos,Synth. Commun., 22 (1992) 1159.
  9. M C. Rezende, P. Campodonico, E.Abuin, J. Kossanyi, Spectrochim. Acta A., 57 (2001) 1183.
  10. K Tanaka, X. Chen, T. Kimura, F. Yoneda, Tetrahedron Lett., 28 (1987) 4173.
  11. K Tanaka, X. Chen, T. Kimura, F. Yoneda, Chem. Pharm. Bull., 34 (1986) 3945.
  12. J T. Li, H. G. Dai, D. Liu, T. S. Li, Synth. Commun., 36 (2006) 789.
  13. S K. Dewan, R. Singh, Synth. Commun., 33 (2003) 3085.
  14. J R. Rajput, G. Kaur, Chin. J. Catal., 34 (2013) 1697.
  15. C Wang, J. Ma, X. Zhou, X. Zang, Z. Wang, Y. Gao, P. Cui, Synth. Commun., 35 (2005) 2759.
  16. G Alcerreca, R. Sanabria, R. Miranda, G. Arroyo, J. Tamariz, F. Delgado, Synth. Commun.,30 (2000) 1295.
  17. J M. Khurana, K.Vij, Catal. Lett., 138 (2010) 104.
  18. A Venkat Narsaiah, K. Nagaiah, Synth. Commun., 33 (2003) 3825.
  19. F Bigi, M. L. Conforti, R. Maggi, A. Piccinno, G. Sartori, Green Chem., 2 (2000) 101.
  20. M L. Deb, P. J. Bhuyan, Tetrahedron Lett., 46 (2005) 6453.
  21. J Lu, Y. Li, Y.Bai, M. Tian, Heterocycles, 63 (2004) 583.
  22. Y Hu, Z. C. Chen, Z. G. Le, Q. G.Zheng, Synth. Commun., 34 (2004) 4521.
  23. J H. Clark, Green Chem., 1 (1999) 1.
  24. A V. Borhade, B. K. Uphade, A. G. Gadhave, Res. Chem. Intermed., 42 (2016) 6301.
  25. A V. Borhade, B. K. Uphade, J. Iran. Chem. Soc., 12 (2015) 1107
  26. A V. Borhade, B. K.Uphade, D. R.Tope, Res. Chem. Intermed., 40 (2014) 211.
  27. A V. Borhade, B. K.Uphade, D. R. Tope, J. Chem. Sci., 125 (2013) 583.
  28. A V. Borhade, B. K.Uphade, A. G. Gadhave, Res. Chem. Intermed., 41 (2015) 1447.
  29. A V. Borhade,B. K. Uphade, Iranian J. Catalysis, 6 (2016) 197.
  30. A Dandia, V. Parewa, S. L. Gupta, K. S. Rathore, J. Mol. Catal. A.Chem., 373 (2013) 61.

International Journal of Scientific Research in Science and Technology

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Published

2019-01-04

Issue

Volume 5, Issue 4, January-2019

Section

Research Articles

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How to Cite

[1]
B. K. Uphade, A. G. Gadhave "Eggshell Waste : An Efficient Solid Catalyst for the Synthesisof 5-Arylidene Barbituric Acids under Solvent-Free Condition" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 5, Issue 4, pp.01-04, January-2019.