Synthesis of a Macrocyclic Schiff Base Ligand H4 mac1-3 and Their Nickel (II) Complexes

Authors

  • Dr. Shakti Dhar Jha Sunit  University Department of Chemistry, B. R. A. Bihar University Muzaffarpur, Bihar, India

Keywords:

Macrocyclic complexes, Oxalodihydrazide, Nickel (II)

Abstract

Macrocyclic complexes of the type [Ni H2 mac1-3] containing a pair of alpha diimine groups were synthesized by metal ion catalysed template condensation of bis- oxalo dihydrazide Ni (II) complexes with biacetyl, benzil or furil. Cyclisation has taken place due to organizational role of metal ions. Characterization of the complexes has been done on the basis of elemental analysis for molecular formula, IR spectra for node of bonding, magnetic moment and electronic spectra for stereochemistry & molar conductivity for electrolytic nature of the complexes. Amidic nitrogens have taken part in coordination. Structure of the complexes has been found to be square planar. Complexes are non- electrolytic in nature.

H4mac1=1,2,5,6,9,10,13,14-octaaza-7,8,15,16-tetraoxo-3,4,11,12-tetramethyl-1,6,9,14-tetrahydro-cyclohexadeca-2,4,10,12-tetraene

H4mac2=1,2,5,6,9,10,13,14-octaaza-7,8,15,16-tetraoxo-3,4,11,12-tetrafuryl-1,6,9,14-tetrahydro-cyclohexadeca-2,4,10,12-tetraene

H4mac3=1,2,5,6,9,10,13,14-octaaza-7,8,15,16-tetraoxo-3,4,11,12-tetraphenyl-1,6,9,14-tetrahydro-cyclohexadeca-2,4,10,12-tetraene

References

  1. Gull, P., Malik, M.A., Dar, O.A., Hashmi, A.A.: Design, synthesis and characterization of macrocyclic ligand based transition metal complexes of Ni(II), Cu(II) and Co(II) with their antimicrobial and antioxidant evaluation. J. Mol. Struct. 1134, 734–741 (2017)
  2. EL-Gammal, O.A., Bekheit, M.M., El-Brashy, S.A.: Synthesis, characterization and in vitro antimicrobial studies of Co(II), Ni(II) and Cu(II) complexes derived from macrocyclic compartmental ligand. Spectrochim. Acta A. 137, 207–219 (2015)
  3. Kumar, U., Chandra, S.: Synthesis, spectral and antifungal studies of some coordination compounds of cobalt(II) and copper(II) of a novel 18-membered octaaza [N8] tetradentate macrocyclic ligand. J. Saudi Chem. Soc. 15, 187–193 (2011)
  4. Abou-Hussein, A.A.A., Linert, W.: Synthesis, spectroscopic and biological activities studies of acyclic and macrocyclic mono and binuclear metal complexes containing a hard-soft Schiff base. Spectrochim. Acta A. 95, 596–609 (2012)
  5. Shankarwar, S.G., Nagolkar, B.B., Shelke, V.A., Chondhekar, T.K.: Synthesis, spectral, thermal and antimicrobial studies of transition metal complexes of 14-membered tetraaza [N4] macrocyclic ligand. Spectrochim. Acta A. 145, 188–193 (2015)
  6. Tsubomura, T., Chiba, M., Nagai, S., Ishihira, M., Matsumoto, K., Tsukuda, T.: Dinuclear macrocyclic palladium complexes having pincer coordinating groups and their catalytic properties in MizorokieHeck reactions. J. Organomet. Chem. 696, 3657–3661 (2011)
  7. El-Boraey, H.A., El-Din, S.A.A: Transition metal complexes of a new 15-membered [N5] penta-azamacrocyclic ligand with their spectral and anticancer studies. Spectrochim. Acta A. 132, 663–671 (2014)
  8. El-Boraey, H.A., El-Gammal, O.A.: New 15-membered tetraaza (N4) macrocyclic ligand and its transition metal complexes: spectral, magnetic, thermal and anticancer activity. Spectrochim. Acta A. 138, 553–562 (2015)
  9. El-Boraey, H.A., El-Salamony, M.A., Hathout, A.A.: Macrocyclic [N5] transition metal complexes: synthesis, characterization and biological activities. J. Incl. Phenom. Macrocycl. Chem. 86, 153–166 (2016)
  10. El-Boraey, H.A., El-Din, S., El Sayed, A.A.: I.: New complexes with 19-membered pyridine-based macrocycle ligand synthesis, characterization, thermal and in vitro anticancer activity. J. Therm. Anal. Calorim. 129, 1243–1253 (2017)
  11. West, T.S.: Complexometry with EDTA and related reagents, 3rd edn. DBH Ltd. Pools, London (1969)
  12. Skehan, P., Storeng, R., Scudiero, D., Monks, A., Mahon, J.M., Vistica, D., Warren, J.T., Bokesch, H., Kenney, S., Boyd, M.R.: New colorimetric cytotoxicity assay for anticancer-drug screening. J. Natl. Cancer Inst. 82, 1107–1112 (1990)
  13. Bayoumi, H.A., Alaghaz, A.M.A., Aljahdali, M.S.: Cu(II), Ni(II), Co(II) and Cr(III) complexes with N2O2-Chelating Schiff’s base ligand incorporating azo and sulfonamide moieties: spectroscopic, electrochemical behavior and thermal decomposition studies. Int. J. Electrochem. Sci. 8, 9399–9413 (2013)
  14. Geary, W.G.: The use of conductivity measurements in organic solvents for the characterization of coordination compounds. Coord. Chem. Rev. 7, 81–122 (1971)
  15. Swamy, S.J., Pola, S.: Spectroscopic studies on Co(II), Ni(II), Cu(II) and Zn(II) complexes with N4-macrocylic ligands. Spectrochem. Acta A. 70, 929–933 (2008)
  16. Masoud, M.S., Khalil, E.A., Hindawy, A.M., Ali, A.E., Mohamed, E.F.: Spectroscopic studies on some azo compounds and their cobalt, copper and nickel complexes. Spectrochim. Acta A. 60, 2807–2817 (2004)
  17. Shakir, M., Abbasi, A., Azam, M., Khan, A.U.: Synthesis, spectroscopic studies and crystal structure of the Schiff base ligand L derived from condensation of 2-thiophenecarboxaldehyde and 3,3-diaminobenzidine and its complexes with Co(II). Ni(II), Cu(II), Cd(II) and Hg(II): comparative DNA binding studies of L and its Co(II), Ni(II) and Cu(II) Complexes. Spectrochim. Acta A. 79, 1866–1875 (2011)
  18. Kavitha, N., Lakshmi, A.P.V.: Synthesis, characterization and thermogravimetric analysis of Co(II), Ni(II), Cu(II) and Zn(II) complexes supported by ONNO tetradentate Schiff base ligand derived from hydrazino benzoxazine. J. Saudi Chem. Soc. (2015).
  19. Mahapatra, B.B., Mishra, R.R., Sarangi, A.K.: Synthesis, characterization, XRD, molecular modelling and potential antibacterial studies of Co(II), Ni(II), Cu(II), Zn(II), Cd(II) and Hg(II) complexes with bidentate azodye ligand. J. Saudi Chem. Soc. 20, 635–643(2016)
  20. Kavitha, P., Rama Chary, M., Singavarapu, B.V.V.A., Laxma Reddy, K.: Synthesis, characterization, biological activity and DNA cleavage studies of tridentate Schiff bases and their Co(II) complexes. J. Saudi Chem. Soc. 20, 69–80 (2016)
  21. Zafar, H., Kareem, A., Sherwani, A., Mohammad, O., Ansari, M.A., Khan, H.M., Khan, T.A.: Synthesis and characterization of Schiff base octaazamacrocyclic complexes and their biological studies. J. Photochem. Photobiol. B. 142, 8–19 (2015)
  22. Vogel A.I, Furniss  B.S and Tatchell A.R., Vogel’s Textbook of Practical Organic Chemistry., ELBS/Longman, England (1978) 1125.

International Journal of Scientific Research in Science and Technology

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Published

2020-12-30

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Volume 7, Issue 6, November-December-2020

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Research Articles

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[1]
Dr. Shakti Dhar Jha Sunit "Synthesis of a Macrocyclic Schiff Base Ligand H4 mac1-3 and Their Nickel (II) Complexes" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 7, Issue 6, pp.176-181, November-December-2020.