Template Synthesis of 16-membered Octaazamacrocyclic Complexes of Zn(II) Ions

Authors

  • Rajeev Kumar Singh   Department of Chemistry, Awadh Bihari Singh Mahavidyalya , Lalganj, Vaishali, Bihar, India

Keywords:

Octaazamacrocyclic ligand, template synthesis, Zn(II)

Abstract

Template condensation of metal ion with hydrazine, 2,4-Pentanedione and acetaldehyde in a 1:4:2:2 molar ratio resulted in the formation of 16-membered octaazamacrocyclic complexes: dichloro/nitro[2,5,8,10,13,16-hexamethyl-3,4,6,7,11,12,14,15-octaazacyclohexadecane - 2, 7, 10, 15- tetraene)Zn(II). The formula of the complex was derived and found to be of the type [ZnLX2] where X=Cl or NO3. The geometry of the complexes has been characterized by elemental analysis IR measurements. An octahedral geometry is suggested for the complexes.

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International Journal of Scientific Research in Science and Technology

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Published

2020-12-30

Issue

Volume 7, Issue 6, November-December-2020

Section

Research Articles

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How to Cite

[1]
Rajeev Kumar Singh "Template Synthesis of 16-membered Octaazamacrocyclic Complexes of Zn(II) Ions" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 7, Issue 6, pp.242-245, November-December-2020.