Measurement of Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by Ylide

Authors

  • Akshay Kumar Shukla  Department of Chemistry, Brahmanand College, The Mall, Kanpur, India
  • Yousuf Akhtar Roomi  Department of Chemistry, Brahmanand College, The Mall, Kanpur, India

Keywords:

Copolymerization, Linalool, Methyl methacrylate, Reactivity ratio.

Abstract

Radical copolymerization methodology was explored by and making use of acyclic terpenoids namely linalool with methyl methacrylate (MMA) initiated by p-acetyl benzylidene triphenyl arsonium ylide (p-ABTAY) in xylene at 80±1 oC for 50 minutes under inert atmosphere of N2. The reaction results in alternating copolymer as evidenced from reactivity ratios. The system follows ideal kinetics . The overall activation energy is 93.0  kJ / mol . Alfrey Price, Q - e parameters for linalool has been evaluated as 5.02 and -2.30. The copolymer has been characterized by 1H-NMR, FTIR and TGA.

References

  1. Tomita, I.; Kondo, Y.; Takagi, K.; Endo, T. Macromolecules 1994, 27, 4413.
  2. Porri, J.; Giarrusso, A. In Comprehensive Polymer Science, Eastmond, G.; Ledwith, A.; Russo, S.; Sigwalt, P.,Ed., Pergamon Press: Oxford, 1989, Vol. 4, p. 53.
  3. Masuda, T.; Higashimura, T. Acc Chem Res 1984, 17, 51.
  4. Schwab, P.; Grubbs, R. H.; Ziller, J. W. J Am Chem Soc 1996, 118, 100.
  5. Sudo, A.; Uchino, S.; Endi, T. Macromolecules 1999, 32, 1711.
  6. Zhu, S.; Tian, Y.; Hamielac, A. E.; Eaton, D. R. Polymer 1990, 31,154.
  7. Zhu, S.; Tian, Y.; Hamielac, A. E.; Eaton, D. R. Polymer 1990, 31, 1726.
  8. Huo, H.; Dube, M. A. Polymer 2001, 42, 6009.
  9. Pandey, P.; Srivastava, A. K. Polym Int 2001, 50, 937.
  10. Pandey, P.; Srivastava, A. K. J Polym Sci 2002, A40, 1243.
  11. Shukla, A.; Srivastava, A. K. Polymer-Plastics Tech & Eng in press.
  12. Shukla, A.; Srivastava, A. K. J Macromol Sci in press.
  13. Ham, G. E. Copolymerization; Interscience: New York, 1964.
  14. Mayo, F. R.; Lewis, F. M.; Walling, C. Discussions Faraday Soc 1947, 2, 285.
  15. Hayashi, K.; Yonezawa, T.; Nagata, C.; Okamura, S., Fukui, K. J Polym Sci 1956, 20, 537.
  16. Joshi, R. M. Makromol Chem 1962, 55, 35.
  17. Miller, M. L. The Structure of Polymers, Reinhold Publishing Corporation: London, 1966,p. 450.
  18. Snyder, C.; McIver, W.; Sheffer, H. J Appl Polym Sci 1977, 21, 131.
  19. Pietila, H.; Sivola, A. K.; Sheffer, H. J Polym Sci 1970, A1(8), 727.
  20. Adur, A. M.; Williams, F. J Polym Sci 1981, 19, 669.
  21. Maslinka, J.; Rudnicka, I. Eur Polym J 1988, 24(5), 453.
  22. Douglas, L.; Gasney, I.; Orminston, R. Am Chem Soc Review 1987, 16, 455
  23. Daniel, N.; Srivastava, A. K. Adv Polym Tech 2002, 21(2), 108.
  24. Vogel, A. I. A Text book of Practical Organic Chemistry, 5th Ed., Longmann: London, 1994, p.395.
  25. Simenson, J. L. The Terpenes, Cambridge: London, 1969, Vol. 1, p. 61.
  26. Tewari, R. S.; Chaturvedi, S.C. Synthesis 1978, 616.
  27. Jackman, L. M.; Sternhell, S. Application of Nuclear Magnetic Resonance Spectroscopy in Organic Chemistry, 2nd Ed., Pergamon Press: London, 1969, p. 215.
  28. Silverstein, R. M.; Webster, F. X. Spectrophotometric Identification of Organic Compounds, 6th Ed., John Wiley and Sons: New York, 2001, Appendix D, p.249.
  29. Gronowski, A.; Wojtczak, Z. J Therm Anal 1983, 26, 233.
  30. Balcerowiak, W.; Hetper, J.; Beres, J.; Olkowska, J. J Therm Anal 1977, 11, 101.
  31. Kelen, T.; Tudos, F. J Macromol Sci Chem Ed 1975, A9, 1.
  32. Gronowski, A.; Wojtczak, Z. Makromol Chem 1989, 190, 2063.
  33. Wojtczak, Z.; Gronowski, A. Makromol Chem 1985, 186, 139.
  34. Vasishtha, R.; Srivastava, A. K. Polymer 1990, 31, 150.

International Journal of Scientific Research in Science and Technology

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Published

2020-05-30

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Volume 7, Issue 3, May-June-2020

Section

Research Articles

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How to Cite

[1]
Akshay Kumar Shukla, Yousuf Akhtar Roomi "Measurement of Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by Ylide" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 7, Issue 3, pp.492-503, May-June-2020.