Measurement of Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by Ylide

Authors

  • Akshay Kumar Shukla  Department of Chemistry, Brahmanand College, The Mall, Kanpur, India
  • Yousuf Akhtar Roomi  Department of Chemistry, Brahmanand College, The Mall, Kanpur, India

Keywords:

Copolymerization, Linalool, Methyl methacrylate, Reactivity ratio.

Abstract

Radical copolymerization methodology was explored by and making use of acyclic terpenoids namely linalool with methyl methacrylate (MMA) initiated by p-acetyl benzylidene triphenyl arsonium ylide (p-ABTAY) in xylene at 80±1 oC for 50 minutes under inert atmosphere of N2. The reaction results in alternating copolymer as evidenced from reactivity ratios. The system follows ideal kinetics . The overall activation energy is 93.0  kJ / mol . Alfrey Price, Q - e parameters for linalool has been evaluated as 5.02 and -2.30. The copolymer has been characterized by 1H-NMR, FTIR and TGA.

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International Journal of Scientific Research in Science and Technology

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Published

2020-05-30

Issue

Volume 7, Issue 3, May-June-2020

Section

Research Articles

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How to Cite

[1]
Akshay Kumar Shukla, Yousuf Akhtar Roomi, " Measurement of Reactivity Ratios and Kinetics in Radical Copolymerization of Linalool with Methyl Methacrylate Initiated by Ylide, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 7, Issue 3, pp.492-503, May-June-2020.