Micellar Studies of Magnesium Caproate after Addition of Amide Additives Using Ion-Selective Electrode

Authors

  • Dushyant Pareek  Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India
  • Chandresh Pareek   Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India
  • Narendra Nirwan  Department of Chemistry, S.D. Govt. College, Beawar, Rajasthan, India

Keywords:

Ice-Berg, Palisade Layers, Ion-Selective Electrode, EMF, Hydrophilic Oleo-Micelle, Lipophilic Hydro-Micelle

Abstract

Magnesium soaps of caproic acid were prepared and a cell was set up for the measurement of EMF of the cell containing referred soap solutions in methanol water solvent system with the aid of Ion-Selective Electrode. The Critical Micelle Concentration of soap solutions was determined by plotting the electromotive force of the cell against soap concentration. The effect of various organic additives on CMC values of referred soaps has been studied by using electrometric method with the add of ion selective electrode.

References

  1. Lehman, A.J. : Assoc. Food and Drug Officials, U.S. Quart. Bull., 15 (1951) 82-89.
  2. Bershold, E., Hoyer, H. and Rosenberg, G.V. : U.S., 2, Aug. 5 (1958) 846, 330.
  3. Cunder, J. and Licata, F.J. : U.S., 2, Aug. 23 (1955) 716, 073.
  4. Ninich, A. and Levinson, H. : U.S., 2, March 25 (1941) 236, 296.
  5. Soc. Anon. Ghent. : Brit., March 21 (1962) 891, Neth. Appl. July 17 (1958) 858.
  6. Robert, A. : Fr., 2, Oct. 13 (1972) 123, 38,. Appl., Sept. 25 (1970) 7034, 744.
  7. Reynolds Maatschappij, N.V. : Neth., June 5 (1962) 101, Appl. May 5 (1956) 474.
  8. Instytul Mechaniki Precyzyjnej : Pol., Spt. 20 (1962) 46, Appl. Decl. Lpp. (1960) 092.
  9. Alvisatos, A.P. : Science, 271(1996) 933.
  10. Henglein, A. : Ber. Bunsenges. Phys. chem., 101 (1997) 1562.
  11. Kim, S.H., Medeiros-Ribeiro, G., Ohlberg, D.A., Williams, R.A. and Heath, Z.R. : J. Phys. chem.,103 (1999) 10341.
  12. McConnel, W.P., Novak, J.P., Brousseav III, L.C, Fuierer, R.R., Tenent, R.C. and Feldhem, D.L.: J. Phys. Chem. B, 104 (2000) 8925.
  13. Pradhan, N., Pal A. and Pal, T. : Langmuir, 17 (2001) 1800.
  14. Mallick, K., Wong, Z.L. and Pal, T. : J. Photo Chem., Photobio. A, 140 (2001) 75.
  15. Varma, R.P. and Kumar, K.: Cellulose Chem. Technol., 9 (1975) 23-30.
  16. Mehta, V.P., Hasan, M., Mathur, S.P. and Rai, G.L. : Tenside Deterg., 16 (2) (1979) 79-80.
  17. Koga, Y., and Matuura : Mem. Fac. Sci. Kyushu Univ. Ser., C. 4 (1961) 1.
  18. Kagarise, R.E. : J. Phy. Chem., 59 (1955) 271.
  19. Mehrotra, K.N., Rajpurohit, M.S. and Godara, V.K. : J. Macromol. Sci. Chem. 19 (1983) 181.
  20. Mehrotra, K.N. and Saroha, S.P.S. : J. Ind. Chem. Soc., 56 (1979) 466.
  21. Duval, C., Lacomte, J. and Douville, F. : Ann. Phys., 17 (1942) 95.
  22. Varma, R.P. and Kumar, K. : J. Indian Chem. Soc. Vth, (1978) 675.
  23. L.C. Heda, D. Pareek, C. Pareek and S. Mosalpuri, Tenside Surf. Det. 45 (2005) 268-271
  24. Vesely, J., Weiss, D. and Stulic, K.: Analysis with Ion Selective Electrodes, Page - 15 - 6, Edit. by John Wiley & Sons (1978).
  25. Saleh, M. B. : Ind. J. Chem., 30A, (1991) 444-446.
  26. Tiwari, K. K. and Chattopadhyaya, M.C. : Ind. J. Chem., 40 A (2001) 619-621.
  27. Kobayashi, T., Kataoka, M. and Kambara, T. : Talanta., 27 (1980) 253-256.
  28. Frank, H.S. and Evans, M.W. : J. Phys. Chem, 13, 507 (1945).
  29. Goddard, E.D. and Benson, G.C. Can. J. Chem., 35 978 (1957).
  30. Goddard, E.D. ; Hoeve, C.A. J. and Benson, G.C. : J. Phys. Chem. 61, 593 (1957).
  31. Xue-Gog Lei, Chinese Journal of Chemistry, 10(3) (2010) 185-192
  32. M.S. Alam, V. Naresh Kumar, N Vijaykumar, Journal of Molecular Vol-XI (2014) 58-61
  33. Pareek, D.t, Pareek, C., Nirwan, N.: IJSRSET, Vol. 1, (2015), 435-444.

International Journal of Scientific Research in Science and Technology

Downloads

Published

2015-07-30

Issue

Volume 1, Issue 3, July-August-2015

Section

Research Articles

License

Copyright (c) IJSRST

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Dushyant Pareek, Chandresh Pareek , Narendra Nirwan, " Micellar Studies of Magnesium Caproate after Addition of Amide Additives Using Ion-Selective Electrode, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 1, Issue 3, pp.231-240, July-August-2015.