Cyclic Voltammetric Behaviour of 4-Nitroacetanilide at Glassy Carbon Electrode at different pH
Keywords:
Cyclic voltammetry, 4- nitro acetanilide, Irreversible, Stainless steel (SS-316) electrodeAbstract
The cyclic voltammetric behaviour of 4- nitro acetanilide has been studied with the help of cyclic voltammetry technique at various scan rates and pH values in aqueous methanol solvent. The voltammograms of studied compound exhibits the one reduction peak. The effect of scan rate on cathodic peak potential indicates that these reactions are irreversible. The constant current electrolysis of 4-nitroacetanilide in acidic media was carried out galvanostatically using economically viable stainless steel (SS-316). The product was isolated purified and characterized by combined application of chromatographic and spectroscopic techniques.
References
- Electrochemical and spectroscopic behaviour of bis(2-mercaptopyridine-N-oxide) oxovanadium (IV) ; Parajoan-Costa B.S., González-Baro A.C., Baran E.J.Z. Anorg. Allg. Chem. 628(6), 1419-1424, (2002)
- Electrochemical methods, fundamentals and applications; A.J.Bar and L.R. Faulkner, (Wiley, New York), 2 1980.
- Synthesis and electrochemical investigations on 2-phenyl-4-[4’-(3”-ethoxy) phenylazophenyl]-3-thioxo-3,4-dihydro-2H, 2, 4, 9, 10-tetraazaphenanthrene-1-one; Sharma P, Kumar A, Sharma M. Indian J. Chem., 45(4),872-876,(2006).
- Electrochemical Reduction of 2- Methylcyclohexane-1, 3-Dione at Stainless Steel (Ss-316) Electrode in Basic Media ; Sharma S.k ,Wadhvani G., I. K. Sharma I. K., Verma P. S. Int. J. Inno. Res. Sci. Eng. Technol., 3(12), 1-5,(2014).
- Fichter F. (1942): Orgaische Electrochemie : Steinkopff, Dresden and Leipzi.
- Nicholson R.S. (1965): Theory and Application of Cyclic Voltammetry for Measurement of Electrode Reaction Kinetics. Anal. Chem. 37, 1351.
- Electrochemical Reduction of m-Nitroaniline at Stainless Steel [SS-316] Cathode in Basic and Acidic Aqueous Methanol Medium. Singhal N., Sharma I.K. and Verma P.S. Trans SAEST, 32, 77. . (1997):
- Swan S. Jr. (1956): in A Weissberger, ed, Technique of Organic Chemistry, 2nd ed, Wiley, New York 2, 385-523.
- Electrochemical reduction of o-Aminoacetophenone and Acetophenone at Stainless Steel cathode in basic aqueous ethanol medium. Yadav S.R., Yadav R., Sharma A., Sharma I.K. and Verma P.S. , Bull. Electrochem. 18(2) ,87- 90, (2002a).
- Electrochemical reduction of Benzil and Salicylaldehyde at Stainless Steel Cathode in Basic Aqueous Ethanol Medium. Yadav S.R., Goyal P., Sharma A., Sharma I.K. and Verma P.S. J. Ind. Chem. Soc. 79, 695-697. (2002a).
Downloads
Published
Issue
Section
License
Copyright (c) IJSRST

This work is licensed under a Creative Commons Attribution 4.0 International License.