Estimation Crystal Size and Lattice Strain of Nanocrystal Bi2O3 using the Scherrer and Size-Strain Plot Method

Authors

  • Inten Rafika Duri  Department of Physics, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
  • Heri Sutanto  Department of Physics, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia
  • Eko Hidayanto   Department of Physics, Faculty of Sciences and Mathematics, Diponegoro University, Indonesia

DOI:

https://doi.org//10.32628/IJSRST2293128

Keywords:

Bi2O3, Precipitation assisted by microwave, Size-Strain Plot

Abstract

Crystal size is an important parameter that affects the physical properties of nanocrystals that are correlated in determining the characteristics of crystal structure. This study aimed to estimate the crystal size and view the Bi2O3 nanoparticle lattice stretching. Synthesized nanoparticles Bi2O3 using the precipitation method assisted by microwave with variations in microwave power 100 W, 300 W, 450 W, 600 W, and 850 W, respectively. Bi2O3 with crystal structures identified through X-ray diffraction peak profiles. The size of the crystal and lattice stretch obtained through the size-strain plot method is more accurate than the Scherrer method, as seen from the correlation coefficient value (R2 > 0.9).

References

  1. Divya, J., Shivaramu, N. J., Purcell, W., Roos, W. D., & Swart, H. C. Effects of annealing temperature on the crystal structure, optical and photocatalytic properties of Bi2O3 needles. Applied Surface Science. 2020; 520:146-294.
  2. Chen, T., Hao, Q., Yang, W., Xie, C., Chen, D., Ma, C., Yao, W., & Zhu, Y. A honeycomb multilevel structure Bi2O3 with highly efficient catalytic activity driven by bias voltage and oxygen defect. Applied Catalysis B: Environmental. 2018; 237: 442–448.
  3. Sahoo, A. K., & Panigrahi, M. R. A study on strain and density in graphene-induced Bi2O3 thin film. Bulletin of Material Science. 2021; 44 :232.
  4. Jiang, H. Y., Li, P., Liu, G., Ye, J., & Lin, J. Synthesis and photocatalytic properties of metastable β-Bi2O3 stabilized by surface-coordination effects. Journal of Materials Chemistry A. 2015; 3(9): 5119–5125.
  5. Faisal, M., Ismail, A. ., Ibrahim, A. ., Bouzid, H., & Al-Sayari, A. Highly Efficient Photocatalyst based on Ce doped ZnO Nanorod: Controllable Synthesis and Enhanced Photocatalytic Activity. Chemical Engineering Journal. 2013; 229: 225–233.
  6. Wang, H., Lu, J., Wang, R., Dong, Y., & Ding, L. Synthesis and characterization of the catio3: Eu3+ red phosphor by an optimized microwave-assisted sintering process. Materia. 2020; 13(4).
  7. Grundas, S. Advances in Induction and Microwave Heating of Mineral and Organic Materials(1stEd). InTech. 2011.
  8. Kalita, A., & Kalita, M. P. C. Size dependence of lattice parameters in ZnO nanocrystals. Applied Physics A: Materials Science and Processing. 2015; 121(2): 521–524.
  9. Bindu, P., & Thomas, S. Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis. Journal of Theoretical and Applied Physics. 2014; 8(4): 123–134.
  10. Augustin, M., & Balu, T. Estimation of Lattice Stress and Strain in Zinc and Manganese Ferrite Nanoparticles by Williamson-Hall and Size-Strain Plot Methods. International Journal of Nanoscience. 2017; 16(3): 1–7.
  11. Nath, D., Singh, F., & Das, R. X-ray diffraction analysis by Williamson-Hall, Halder-Wagner and size-strain plot methods of CdSe nanoparticles- a comparative study. Materials Chemistry and Physics. 2020; 239, 122021.
  12. Mote, V., Purushotham, Y., & Dole, B. Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles. Journal of Theoretical and Applied Physics. 2021; 6(1): 2–9.
  13. Suwarni, S. Struktur Mikro dan Sifat Listrik Material Ferroelektrik Barium Titanat dengan doping Stronsium. Jurnal Fisika Dan Aplikasinya. 2015; 11(3): 99.

International Journal of Scientific Research in Science and Technology

Downloads

Published

2022-06-30

Issue

Volume 9, Issue 3, May-June-2022

Section

Research Articles

License

Copyright (c) IJSRST

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

How to Cite

[1]
Inten Rafika Duri, Heri Sutanto, Eko Hidayanto , " Estimation Crystal Size and Lattice Strain of Nanocrystal Bi2O3 using the Scherrer and Size-Strain Plot Method, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 9, Issue 3, pp.647-652, May-June-2022. Available at doi : https://doi.org/10.32628/IJSRST2293128