Study of Some Novel Complexes of Ni(Ii) and Cu(Ii) with Schiff Base Ligand Derived from Hydroxamic ACID

Authors

  • Sanjay Kumar  Department of Chemistry, Jagdam College, Chapra, Saran, Bihar, India
  • Mahavir Upmanyu  Department of Chemistry, Jagdam College, Chapra, Saran, Bihar, India
  • Priyanka   Department of Chemistry, Jagdam College, Chapra, Saran, Bihar, India

Keywords:

Hydroxamic Acid, Chelating Ligand, Spectral Investigation, Magnetic Susceptibility, Molar Conductance, Tridentate

Abstract

In this paper, we report the synthesis and characterisation of some novel complexes of Ni(II) and Cu(II) with 2-(o-hydroxybenzophenoneimino) benzohydroxamic acid in presence of bases like ammonia, pyridine, phenyl isocyanide, quinoline and -picoline. The complexes have been characterised on the basis of elemental analyses, molar mass determination, molar conductance and magnetic susceptibility measurements, UV-visible and IR spectroscopic investigations. The complexes have been formulated as [M(L)(B)3] where,L=dideprotonated 2-(o-hydroxybenzophenone imino) benzohydroxamic acid (LH2), B=NH3, pyridine, phenyl isocyanide, quinoline and -picoline and M=Ni(II) and Cu(II). The ligand (L) behaves as dianionic tridentate ligand. The complexes have been found to be paramagnetic and non-electrolytic in nature. All the complexes are found to have octahedral geometry as indicated by the values of magnetic moments and the positions of u.v.-visible spectral bands. The nature of metal-ligand bonding has been established on the basis of IR spectral studies.

References

  1. H. Jahangirian, J. Harson, S. Silong, N.Z. Yusof, K. Shameli, S. Eissazadeh, R. R. Moghaddam, B. Mahdavi, M. Jafarzade : J. Med. Plants Res., 5(19), 4826, 2011.
  2. H.Agarwal, O. P. Agarwal, R.Karnawat, I.K.Sharma, P.S.verma: Int. J. Appl. Biol. & Pharm. Tech, 1(3), 1293, 2010.
  3. A.O. Aliyu, J.N. Wabueze: Int. J. Physical Sci., 2(7), 167, 2008.
  4. S.Sonika, S.Neeraj : Der Chemica Sinica, 4(3), 108, 2013
  5. M.J. Miller: Chem. Rev., 89, 1563, 1989.
  6. H.L. Elford, G.L. Wampler, B.V. Riet : Cancer Res., 39, 844, 1979.
  7. Naqeebullah, F.Yang, M.C. Kok, K.M. Lo, F.R. Nor, C.O. Theng: Molecules, 18, 8696, 2013.
  8. D. Pal, S.Saha : J. Adv. Pharm. Tech. Res., 3(2), 92, 2012.
  9. C.J. Marmion, T. Murphy, J. R. Docherty, K.B. Nolan: Chem. Commun, 1153-115, 2000.
  10. D. Veale, J. Carmichael, B.M. Cantwell, H.L.Elford, R. Blackic, D.J.Kerr, S.B. Kaye, A.L. Harris,: Br. J. Cancer, 58(1), 70, 1988.
  11. M. Arnold, D.A. Brown, O.Deeg, W.Errington, W. Haase, K.Herlihy, T.J. Kemp, H. Nimir, R. Wemer: Inorg. Chem., 37, 2920, 1998.
  12. S.S.C. Tam, D.H. S. Lee, E.Y. Wang, D.G. Munroe, C.Y.Lau: J. Biol. Chem., 270, 13948, 1995.
  13. I. Botos, L. Scapozza, D. Zhang, L.A. Liotta, E.F. Meyer: Proc. Nat. Acad. Sci., 93, 2749, 1996.
  14. I.K. Larsen, B.M. Sjberg, L. Thelander: Eur.J. Biochem., 125, 75, 1982.
  15. J.P. Demers, V.M. William: U.S. Patent Appl. Pat. No. 4, 820, 828, 1989.
  16. M.Z. Koncic, M. Barbaric, V. Perkovic, B.Zoric: Molecules, 16(8), 6232, 2011.
  17. A. M. A. Gary, A.L. Crumbliss: Metal Ions in Biological Systems, Marcel Dekker, New York, 35, 239, 1998.
  18. J.B. Neilands: J. Biol. Chem., 270, 26723, 1995.
  19. G. Borland, G. Murphy, A. Ager: J. Bio-Chem, 274, 2810, 1999.
  20. K.M. Bttomley, W.H. Johnson, D.S. Waltor: J. Enzy. Inhibition, 13(2), 79, 1998.
  21. K.W. Vogel, D.G. Druckhammer: J Am. Chem. Soc., 120, 3275, 1998.
  22. K.K.Ghosh, P. Tamrakar: Indian J. Chem., 40(A), 524, 2001.
  23. B.A. Holmen, M.I. Tejedor, W.H. Casey: Langmuir, 13, 2197, 1997.
  24. J. Mendham, R.C. Denney, J.D.Barns, M. Thomas, B. Sivasankar: Vogel’s Test book of Quantitative Chemical Analysis, Sixth Edition, Pearson Education Ltd. 411-412, 200.
  25. E. Sonn, C.M. Harris: Coord. Chem. Rev. 4, 391, 1989.
  26. M. Mohapatra, C.D. Kailash: Indian J. Chem, 29A, 342, 1990.
  27. N. Raman, J. Josheph, A. Senthil Kumara Velan, C. Pothiraj: The Korean Society of Mycology, 34(4), 214, 2006.
  28. R. Poppalardo: Phill, Mag., 4, 219, 1959.
  29. ABP Lever: Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.
  30. ABP Lever, E. Montovani: Inorg. Chem., 10, 817, 1971.
  31. R.L. Carlin: Trans. Met. Chem., 4, 211, 1968.
  32. R.K. Patel, R.N. Patel: J. Ind. Chem. Soc., 67, 238, 1990.
  33. Bhawani Shankar, Rashmi Tomar, Rakesh Kumar, Madhu Godhara, Vijay Kumar Sharma: J. Chem. Pharm. Res., 6(5), 925, 2014.
  34. M. Hazra, T. Dolai, A. Pandey, S.K. Dey, A. Patra: Bioinorg. Chem. Appl., Doi: 10.1155/2014/104086.
  35. C. Cenol, Z. Hayvali, H. Dal, T. Hokelek: J. Mol. Struct., 997, 53, 2011.
  36. A.H. Azza, L. Wolfgang: Spectrochimica Acta Part A, 95, 596, 2012.
  37. N. Raman, T. Baskaran, A. Selvan, R. Jeyamurugan: J. Iran. Chem. Res., 1, 129, 2008.
  38. A.E. Ozel, Y. Buyukmurat, S. Akyuz: J. Mol. Struct., 565-566, 455, 2001.

International Journal of Scientific Research in Science and Technology

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Published

2019-06-30

Issue

Volume 6, Issue 3, May-June-2019

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Research Articles

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How to Cite

[1]
Sanjay Kumar, Mahavir Upmanyu, Priyanka , " Study of Some Novel Complexes of Ni(Ii) and Cu(Ii) with Schiff Base Ligand Derived from Hydroxamic ACID, International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011, Volume 6, Issue 3, pp.934-940, May-June-2019.