Efficient and Faster Green Synthesis of GAP-Triol as a Potential Application tn The Energetic Binders
Keywords:
Glycidyl azide Polymers, Microwave, Polyepichlorohydrins, Thermal Property, BindersAbstract
The green root protocol of synthesized glycidyl azide-triol polymer from polyepichlorohydrin-triol polymer was achieved by microwave irradiation technique. The conversion of -CH2-Cl groups of polyepichlorohydrin-triol (PECH-triol) polymer to -CH2-N3 groups of glycidyl azide-triol polymer (GAP-triol) was in very short time. The synthesized glycidyl azide-triol polymer and their precursor of polyepichlorohydrin-triol were characterized by various spectral analyses. The thermal behavior of GAP-triol was studied by thermogravimetry analysis and differential scanning calorimetric.
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