Red Emitting Caal3(PO4)3F2:Eu3+ Phosphor for White Light Emitting Diodes
Keywords:
Luminescence, X-ray diffraction, LED & HaloPhosphate.Abstract
The Red-emitting phosphors of Eu3+ activated phosphate based phosphors prepared by combustion synthesis, characterized by XRD (X-ray diffraction), SEM (Scanning electron microscopy) and Photoluminescence (PL) techniques, has been reported. The luminescence properties were investigated by photoluminescence excitation and emission spectra. PL excitation spectrum of CaAl3(PO4)3F2:Eu3+ phosphors shows the excitation peaks ranging from 370 to 400 nm due to 4f→4f transitions of Eu3+ ions. PL emission spectrum of Eu3+ ion under 394 nm excitation gives PL emission at 615 nm (red) due to 5D0 ïƒ 7F2 transitions, 593 nm (orange) emission due to 5D0 ïƒ 7F1transitions. Hence PL emission in trivalent europium may be efficient photoluminescent materials for solid-state lighting phosphors.
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