UV Emission In Li2CaMg(SO4)3:Ce Phosphor For Phototherapy
Keywords:
Li2CaMg(SO4)3; XRD; SEM; Photoluminescence; Wet chemical method.Abstract
A series of Li2Ca(SO4)2 and Li2CaMg(SO4)3 phosphors doped with Ce3+ ions were prepared using the wet chemical method. X-Ray diffraction and SEM micrographs studies were used to determine their phase formation, purity and morphology. The photoluminescence (PL) excitation spectra indicate that the Li2CaMg(SO4)3:Ce3+ phosphors can be effectively excited by ultraviolet (293nm) light. The photoluminescence (PL) properties of the as-prepared phosphors were investigated. Two strong resolved peaks in emission spectra are observed at 309 and 329 nm in the UV range, which are assigned to the 5d-4f transition of Ce3+ ions. The concentration quenching effect for Ce3+ was found at the optimum doping concentration of 2 mol%. The presence of Mg in the host affects the photoluminescence characteristics of Li2Ca(2-x)Mgx(SO4)3:Ce (2m%) were observed.
References
- Shinde KN, Dhoble NS, Gedam SC, Dhoble SJ.2015, Luminescence, 30, 898-903.
- Kadukar MR, Yawalkar PW, Choithrani R, Dhoble SJ. 2015, Luminescence, 30, 1219-1225.
- Wani JA, Dhoble NS, Dhoble SJ. 2015,Luminescence, 30, 163-7.
- Luo Y, Xia Z, Liu H, He Y. 2014, Opt Mater, 36, 723-6.
- Lijun L, Hongmei F, Yan T, Wanjun T. 2011, Opt Mater, 34, 175-8.
- Bhake AM, Nair GB, Zade GD and Dhoble SJ.2016, Luminescence, DOI 10.1002/bio.3131
- BrikMG,Ma C-G, Liang H, Ni H, Liu G. 2014, J Lumin, 152, 203-5.
- Bhoyar P, Dhoble SJ. 2013, Mater Chem Phys,140, 104-7.
- Brik MG, Avram NM. 2011, Mater ChemPhys,128, 326-30.
- Wang T, Xia Z, Xiang Q, Qin S, Liu Q. 2015, J Lumin, 166, 106-10.
- Nair GB, Dhoble SJ. 2015, Luminescence, 30,1167.
- Singh V, Sivaramaiah G, Rao JL, Kim SH. 2015,J Lumin, 157, 82.
- Shinde VV, Kunghatkar RG, Dhoble SJ. 2015,Luminescence, 30, 1257.
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