Thermal and Thermokinetic Studies of Schiff Base Metal Complexes
Keywords:
Schiff Base, conductance, Thermal Studies.Abstract
Schiff base have been synthesized by condensing 2-hydroxy-5-chloro acetophenone and 4-(p-hydroxyphenyl)-2-aminothiazole. The metal complexes were obtained as a result of interaction of Schiff base ligand and metal ions Co(II), Ni(II), Cu (II), Cr (III), Mn(III), Fe (III), VO (IV), Zr (IV) and UO2 (VI). The complexes have been characterized on the basis of elemental analysis, infrared, molar conductance, magnetic Susceptibilities, and theromogravimetric analysis. The kinetic analysis of the thermogravimetric data was performed by using Broido, Horowitz-Metzger and Freeman-Carroll method, which confirm first order kinetics and kinetic compensation effect.
References
- Chittilappilly P.S. and Mohammed K.K., Indian J. Chem., 47A, 2008, 848
- Roy B., Inorg.Chim. Acta. 2009, 362, 1709.
- Voguri H. K., Rao V., Podisetty H., Srinivas B, More A., Int. J. ChemTech Research, 2017,10(5): 136.
- Mohamad J. K., Int. J. of ChemTech Research, 2016, 9(7), 516.
- Mohammed H. S., Int. J.of ChemTech Research, 2016, 9(10), 111.
- Aswar A.S, Bahad P., Pardhi A. and Bhave N., J. Poym. Mater., 5, 1988, 232.
- Pattan S., Ali M., Pattan J., Purohit S., Reddy V. and Nataraj B., Indian J. Chem.,45B, 2006, 1929.
- Khrustalev D., Suleimenova A. and Fazylov S., Russian J. App. chem., 81(5), 2008, 900.
- Maradiya H., and Patel V., J. Fibers and poly., 3(1), 2002, 43.
- Furniss B., Hannaford A., Smith P. and Tatchell A., Vogel’s practical organic chemistry 5thEd. Logman Scientific Technical, John Wiley and Sons, 1989.
- Vogel AI, “A Text book of quantitative inorganic chemistry” 3 thEd., (ELBS,London,1961).
- Sadigova S., Magerramov A. and Allakhverdiev M., Russian J. Org.Chem., 81(5), 2008, 900.
- Campbell E. and Nguyen S., J. Tetrahedron, 42, 2001, 1221.
- Pietikainen P. and Haikarainen A. J. Mole. Catalysis., 180, 2002, 59.
- Kidwai M., Poddar P. and Singhal K., Indian J. Chem., 48B, 2009, 59.
- Sonwane S., Srivastava S. and Srivastava S., Indian J. Chem., 47B, 2008, 633.
- Patel K. and Mehata A., E. J. Chem., 3(13), 2006, 267.
- Maurya R., Antony D., Gopinathan S., Puranic V., Tavale S. and Gopinathan C., Bull. Chem. Soc. Jpn., 68, 1995, 2847.
- Boghaei D. and Mohebi S. J. Tetrahedron, 58, 2002, 5357.
- Kassem M.E., Al Kibaisi A.H., Amin R.R., J. Therm. Anal. Calorim., 51(2), 1998, 617.
- Patel I.A and Thaker B.T., Indian J. Chem., 38A, 1999, 427.
- Padalkar V.S., Patil V.S., Gupta V.D., Phatangare K.R., Umap P.G. and Sekar N. Int. J. Sch.Res.Net.Org.Chem., ID738361, 2011, 1.
- Mallikarjun K., E. J. Chem., 1(2), 2004, 105.
- Horowitz H. and Metzger G., Anal. Chem., 35, 1963, 1464.
- Broido A., J. Polym. Sci., Part A2,1964, 1761.
Downloads
Published
Issue
Section
License
Copyright (c) IJSRST

This work is licensed under a Creative Commons Attribution 4.0 International License.