Preparation of Some Complexes of Nickel (II) and Copper (II) Metals with Macrocyclic Ligand, 1,7,10,16- tetraaza-8, 9, 17, 18-dibenzo - 3,4,5,12,13,14 -Difuranyl Cyclo Octadeca - 1, 6, 10, 15-Tetraene

Authors

  • Md. Jamaluddin  Department of Chemistry, Gopeshwar College, Hathua , Gopalganj , J.P. University, Chapra, Bihar, India
  • Pooja Singh  Department of Chemistry, Gopeshwar College, Hathua , Gopalganj , J.P. University, Chapra, Bihar, India

DOI:

https://doi.org/10.32628/IJSRST523103200

Keywords:

Macrocyclic Ligand, Complex, Paramagnetic, Magnetic Mo- Ment, Mono-Meric, Octahedral Geometry

Abstract

The complexes of Nicke l(II) and Copper(II) salts have been prepared with the macrocyclic ligand-1,7,10,16-tetraaza-8, 9, 17, 18-di benzo - 3,4,5,12,13,14-difuranylcyclooctadeca- 1, 6, 10, 15-tetraene. On the basis of characterization of compledxes formed with the macrocyclic ligand by usual physico-chemical methods such as elemental analysis, mea- surement of electrical conductance, magnetic moment and electronic tran- sition spectra of the complexes and I.R. spectral behaviour of both the ligand and the complexes. All the complexes of both the metals have been found to be non-electrolyte, mono-meric, paramagnetic with octahedral geometryy . The general molecular formula of the complexes have been found to be [M(L) (X)2] Where M= Nickel(II) and Copper(II) Cations, L= macrocyclic ligand and X= monodentate anion.

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International Journal of Scientific Research in Science and Technology

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Published

2023-06-30

Issue

Volume 10, Issue 3, May-June-2023

Section

Research Articles

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[1]
Md. Jamaluddin, Pooja Singh "Preparation of Some Complexes of Nickel (II) and Copper (II) Metals with Macrocyclic Ligand, 1,7,10,16- tetraaza-8, 9, 17, 18-dibenzo - 3,4,5,12,13,14 -Difuranyl Cyclo Octadeca - 1, 6, 10, 15-Tetraene " International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 10, Issue 3, pp.1121-1125, May-June-2023. Available at doi : https://doi.org/10.32628/IJSRST523103200