Preparation and Properties of binuclear Schiff Base Complexes of Cu(II) Co(II)and Ni(II) Inter - complex Reaction

Authors

  • Mahananda A. Raut  Department of Chemistry, Prathisthan mahaviadhylaya Paithan .dist Aurangabed (M.S.) India
  • Prabhakar R. Kute  Department of Chemistry, Prathisthan mahaviadhylaya Paithan .dist Aurangabed (M.S.) India
  • Aashish O. Dhokte  Department of Chemistry, Prathisthan mahaviadhylaya Paithan .dist Aurangabed (M.S.) India
  • Dnyanoba R. Kasab  Department of Fishery Science, Prathisthan mahaviadhylaya Paithan .dist Aurangabed (M.S.) India
  • Shankar N. Ipper  Department of Chemistry Sunderrao Solanke Mahavidyalaya, Majalgaon, dist Beed (M.S.), India
  • Pavan R. Kale  Rajarshi Shahu Arts, Commerce and Science College Pathri dist Aurangabad (M.S.), India
  • Archana A. Kachare  

Keywords:

Schiff Base, Inter-Complex Reaction, Binuclear Complex, Biological Activity

Abstract

Homo and hetero binuclear Schiff base complexes of Cu (II), Co (II) , and Ni (II) were prepared by inter-complex reaction between the corresponding metal complexes of 2-hydroxy1- napthaldehyde and 2-amino 3-hydroxy pyridine. The complexes were characterized by elemental analysis and estimation of metals. Thermal behavior of the complexes was studied by TG-DTA analysis. Structures of the complexes were elucidated by spectroscopic methods like, infrared spectroscopy, UV-visible spectroscopy, mass spectrometry and 1HNMR spectroscopy. The powder X-ray diffraction study suggested crystalline nature of the complexes with tetragonal geometry. Magnetic moments and electronic spectra reveal tetrahedral structure of the complexes. Antibacterial activity of complexes were studied against Gram-positive bacteria, Staphylococcus aureus, Bacillus subtilis and Gram-negative bacteria, Salmonella typhi, Escherishia coli by agar cup method. Their antifungal activity was also tested against Aspergillus niger, Penicillium chrysogenum, Fusarium moneliforme and Aspergillus flavus by poison plate method using potato dextrose agar medium at one percent concentration. All complexes show considerable antimicrobial activity.

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International Journal of Scientific Research in Science and Technology

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Published

2023-10-30

Issue

Volume 10, Issue 5, September-October-2023

Section

Research Articles

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How to Cite

[1]
Mahananda A. Raut, Prabhakar R. Kute, Aashish O. Dhokte, Dnyanoba R. Kasab, Shankar N. Ipper, Pavan R. Kale, Archana A. Kachare "Preparation and Properties of binuclear Schiff Base Complexes of Cu(II) Co(II)and Ni(II) Inter - complex Reaction" International Journal of Scientific Research in Science and Technology(IJSRST), Online ISSN : 2395-602X, Print ISSN : 2395-6011,Volume 10, Issue 5, pp.16-25, September-October-2023.