Green and Efficient Synthesis, Spectroscopic, Characterization, Antibacterial Activity of Some Selected Transition Metal Complexes of Novel Schiff Base Ligand Derived from 2-amino 5-methyl benzimidazole with 2-bromo Isophthalaldehyde

Authors

  • Sadashiv N. Sinkar Department of Chemistry, MSS’S Arts Science and Commerce College Ambad, Dist. Jalna. India Author
  • Ram. B. Kohire Department of Chemistry Swami Vivakanand Sr. College Mantha, Dist.Jalna. India Author
  • Dnyaneshwar T. Nagre Department of Chemistry, RMIG College, Jalna. India Author

DOI:

https://doi.org/10.32628/IJSRST24114101

Keywords:

Green Synthesis, Schiff base, Thermal Analysis, Antibacterial activity

Abstract

A Green and efficient environmentally synthesis using scientific microwave method of novel ligand derived from 2-amino 5-methyl benzimidazole with 2-bromo Isophthalaldehyde. Metal complexes were derived from Mn(II) chloride and nitrate of Co(II), Ni(II), Cu(II), Zn(II), Cd(II), salts with novel ligand at the end of the reaction all metal complexes show fine colour. By TLC and melting point of each complex was confirming the formation of metal complex. Characterization of novel ligand carried out by elemental analysis, IR,1HNMR, Mass spectroscopy and characterization of metal complexes carried out by UV, IR. The thermal stability of Zn (II) and Cd (II) complexes was studied by thermo-gravimetric analyses (TGA). All metal complexes show antibacterial activity against E-Coli, S.Aureus and S.Typhi.

Downloads

Download data is not yet available.

References

Das, S.; Das, V.K.; Saikia, L.; Thakur AJ. Environmentally friendly and solvent free synthesis of symmetric bis-imines under microwave irradiation.Green Chem. Lett. Rev. 2012,5,457-474,https://doi.org/10.1080/17518253.2012.667443 DOI: https://doi.org/10.1080/17518253.2012.667443

Sharma K, Singh RV,Fahmi N and Singh RV“Microwave Assisted Synthesis, Characterization and Bio-logical Evaluation of Palladium and Platinum Complexes with Azomethines. Spectro- chimica Acta 2010 75A, 422-427.

T. Jeeworth, H.L.K.Wah, M.G. Bhowon, D. Ghoorhoo, K. Babooram, Synt.React. Inorg. Met-Org. Chem. 30 (2000) 1023. DOI: https://doi.org/10.1080/00945710009351817

N. Dharmaraj, P. Viswanalhamurthi, K. Natarajan, Trans. Met. Chem. 26 (2001) 105. DOI: https://doi.org/10.1023/A:1007132408648

Refaat, H.M.; Synthesis and anticancer activity of some novel 2-substituted benzimidazole derivatives. European Journal of Medicinal Chemistry 2010, 45, 2949- 2956, https://doi.org/10.1016/j.ejmech.2010.03.022. DOI: https://doi.org/10.1016/j.ejmech.2010.03.022

De la Hoz, A.; Diaz-Ortiz, A.; Moreno, A. Microwaves in organic synthesis. Thermal and non-thermal microwave effects. Chem.Soc. Rev. 2005, 34, 164–178. DOI: https://doi.org/10.1039/B411438H

Schmink, J.R.; Leadbeater, N.E. Microwave Heating as a Tool for Sustainable Chemistry: An Introduction. In Microwave Heating as a Tool for Sustainable Chemistry; CRC Press: Boca Raton, FL, USA, 2011; pp. 1–24. DOI: https://doi.org/10.1201/9781439812709

Dallinger, D.; Kappe, C.O. Microwave-assisted synthesis in water as solvent. Chem. Rev.2007, 107, 2563–2591. DOI: https://doi.org/10.1021/cr0509410

Mahato, A.K.; Sahoo, B.M.; Banik, B.K.; Mohanta, B.C. Microwave-assisted synthesis: Paradigm of green chemistry. J. Indian Chem. Soc. 2018, 95, 1327–1339.

Díaz-Ortiz, Á.; Carrillo, J.R. Microwaves in green and sustainable chemistry. In Microwave Chemistry; Cravotto, G., Carnaroglio, D.,Eds.; De Gruyter: Berlin, Germany, 2017; pp. 167–183. DOI: https://doi.org/10.1515/9783110479935-010

Subbaraj P, Ramu A, Raman N, Dharmaraja J (2015) Synthesis, characterization, DNA interaction and pharmacological studies of substituted Benzophenone derived Schiff base metal (II) complexes: Journal of Saudi Chemical Society, 19, 207-216. DOI: https://doi.org/10.1016/j.jscs.2014.05.002

K. Sharma, R. Singh, N. Fahmi, R. V. Singh, Spectrochim. Acta, A 75 (2010) 422. DOI: https://doi.org/10.1016/j.saa.2009.10.052

K. Mohanan, B. S. Kumari, G. Rijulal, J. Rare Earths 26 (2008) 16. DOI: https://doi.org/10.1016/S1002-0721(08)60028-9

R. K. Dubey, U. K. Dubey, C. M. Mishra, Indian J. Chem., A 47 (2008) 1208.

Shinde A, Zangade S, Chavan S, Vibhute Y. Microwave induced synthesis of bis-Schiff base! From propane-1,3-diamine as promising antimicrobial analogs. Org Commun. 2014;7(2):60-67.

Mishra A, Purwar H, Jain R, Gupta S. Microwave Synthesis, Spectral, Thermal and Antimicrobial Studies of Some Co(II), Ni(II) and Cu(II) Complexes Containing 2-Aminothiazole Moiety. E-Journal of Chemistry. 2012;9(4):77-85. DOI: https://doi.org/10.1155/2012/106460

Xavier A, Srividhya N. Synthesis and Study of Schiff base Ligands. IOSR Journal of Applied Chemistry, 2014;7(11):6-15. DOI: https://doi.org/10.9790/5736-071110615

Abdulla A K and Ismail K Z (1994): Canadian J. Chemistry 1994, 72, 1785. DOI: https://doi.org/10.1139/v94-226

A.M.Guidote, J.K.Ando, Y.Kurusu, H.Nagao and Y.Masuyama, Inorg. Chim. Acta,314,27, (2001). DOI: https://doi.org/10.1016/S0020-1693(01)00294-8

C.T.Zeyrek, A.Elmali, Y.Elerman and I.Svoboda, Z.Naturforsch, 60b, 143, (2005). DOI: https://doi.org/10.1515/znb-2005-0203

C.D.Brandt, J.A.Kitchen, U.Beckmann, N.G.White, G.B.Jameson and S.Brooker, Supramolecular Chemistry, 19,17, (2007).

M.B.Alvarez, M.Palmeri, D.Davis and J.S.,Fritz, Talanta, 34,473, (1987). DOI: https://doi.org/10.1016/0039-9140(87)80164-9

Z.Y.Wu, D.J.Xu and Z.X.Feng, Polyhedron, 20,281, (2001). DOI: https://doi.org/10.1016/S0277-5387(00)00625-2

P.Phatak, V.S.Jolly and K.P.Sharma, Orient. J.Chem., 16,493, (2000).

D.M.Kar, S.K.Sahu, D.Paradhan, G.K.Dash and P.K.Mistra, J.Teach. Res. Chem.,10,20,(2003).

S.J.Wadher, N.A.Karande, D.S.Borkar and P.G.Yeole, Int.J.Chem. Tech. Res.,1(4),1297, (2009).

M.Padmaja, J.Pragathi and C.G.Kumari, J. Chem.Pharm. Res., 3(4), 602,(2011).

Kumar J, Rai A, Raj V. A Comprehensive Review on the Pharmacological Activity of Schiff Base Containing Derivatives. Organic &Medicinal Chem 1. 2018;1(3):5-20. DOI: https://doi.org/10.19080/omcij.2017.01.555564

Pahlavani E, Kargar H, Sepehri Rad N. A study on Antitubercular and Antimicrobial activity of Isoniazid derivative. Zahedan journal of Research in Medical Sciences 2014; 17(7):7-10. DOI: https://doi.org/10.17795/zjrms1010

Yadav G. Mani J. Green Synthesis of Schiff Bases by Using Natural Acid Catalysts. International Journal of Science and Research. 2015;4(2):121-127.

Nakamoto K (1971) Infrared Spectra of Inorganic and Coordination Compounds, Part B, Fifth ed.: Wiley Interscience, New York.

Campbell M J M and Grzeskowiak R (1967) J. Chem. Soc., A, 396. DOI: https://doi.org/10.1039/j19670000396

Min Wang, Liu-Fang Wang, Yi-Zhi Li and Qin-Xi Li (2001) Transition Metal Chemistry, 26, 307. DOI: https://doi.org/10.1023/A:1007159301849

Kulkarni A, Patil S A, Badami P S (2009) Eur. J. Med. Chem., 44, 2904. DOI: https://doi.org/10.1016/j.ejmech.2008.12.012

Silverstein M R, Bassler G C and Morril T C (1981) “Spectrometric Identification of Organic Compounds”: John Wiley and Sons, 4th Edn. P. 111-130.

ABP Lever. Electronic spectra of dn ions Inorganic electronic spectroscopy 2nd Ed. 1984.

Selbin J (1966) Coord Chem. Rev. 1, 293-314. DOI: https://doi.org/10.1016/S0010-8545(00)80142-3

Sinn E, Morris C M (1969) Coord Chem. Rev. 4, 891.

Nakamoto K (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds: John Wiley & Sons, New York.

Rajendra K. Jain, Anand P. Mishra (2012) Microwave synthesis and spectral, thermal and antimicrobial activities of some novel transition metal complexes with tridentate Schiff base ligands: J. Serb. Chem. Soc, 77 (8), 1013-1029. DOI: https://doi.org/10.2298/JSC111001023J

Prajapati P, Brahmbhatt M, Vora J, Prajapati K (2019) Synthesis, Characterization, Catalytic and Antibacterial activities of some transition metal chelates with tridentate Schiff base ligand: RJLBPCS, 5(2),825-838.

M.S.Ray,R.Bhattacharya, S.Chaudhuri, L.Righi, G.Bocelli,G.Mukhopa-dhyay, A.Ghosh,Polyhedron. 2003; 22:617-629. DOI: https://doi.org/10.1016/S0277-5387(02)01435-3

Downloads

Published

05-07-2024

Issue

Section

Research Articles

How to Cite

Green and Efficient Synthesis, Spectroscopic, Characterization, Antibacterial Activity of Some Selected Transition Metal Complexes of Novel Schiff Base Ligand Derived from 2-amino 5-methyl benzimidazole with 2-bromo Isophthalaldehyde. (2024). International Journal of Scientific Research in Science and Technology, 11(4), 23-29. https://doi.org/10.32628/IJSRST24114101

Similar Articles

1-10 of 170

You may also start an advanced similarity search for this article.