Structural Properties of Cs1+ Doped H3PMo12O40 Nanocrystalline Polyoxometalate Thin Films

Authors

  • Prashant B. Patil P. G. Department of Chemistry, Smt. KRP Kanya Mahavidyalaya, Islampur, (MS), India Author
  • Bajarang B. Patil Department of Physics, Balwant College, Vita (MS), India Author
  • Tukaram J. Shinde P. G. Department of Physics, Smt. KRP Kanya Mahavidyalaya, Islampur, (MS), India Author
  • Sambhaji R. Mane P. G. Department of Chemistry, Smt. KRP Kanya Mahavidyalaya, Islampur, (MS), India Author

DOI:

https://doi.org/10.32628/IJSRST24114140

Keywords:

Cs doped PMA, MACBD, TGDTA, XRD, FTIR, SEM, EDAX

Abstract

The microwave assisted chemical bath deposition (MA-CBD) technique were used to deposite nanocrystalline thin films of polyoxometalates like phosphomolybdic acid (PMA) (H3PMo12O40) and Cesium (Cs+) doped phosphomolybdic acid (Cs-PMA) (Cs3-PMo12O40). Thermo gravimetric and Differential thermal analysis (TGDTA), Fourier transform infrared spectroscopy (FTIR), Energy dispersive X-ray analysis (EDAX), X-ray diffractometry (XRD) and Scanning electron microscopy (SEM) tools are used for the thermal, structural, morphological and compositional analysis of microwave treated H3PMo12O40 and Cs3- PMo12O40 thin films. The completion of decomposition process at 600 oC of Cs3-PMo12O40 compound is confirmed from TGDTA analysis. The polycrystalline spinel cubic crystal structure of H3PMo12O40 and Cs3-PMo12O40 thin films were confirmed from X-ray diffractometer. The crystallite size of H3PMo12O40 and Cs3-PMo12O40 compound found to be in the range of 50 - 53 nm. The formation of H3PMo12O40 and Cs3-PMo12O40 materials were confirmed from the presence of main four absorption peaks observed in the range from 800 cm-1 to 1100 cm-1. The SEM microphotographs analysis identify the microwave assisted H3PMo12O40 and Cs3-PMo12O40 films have spherical shaped porous nanocrystalline morphology. The grain size of H3PMo12O40 and Cs3-PMo12O40 synthesized material found to be in the range of 10 - 12 A˚ The stoichiometric preparation of H3PMo12O40 and Cs3-PMo12O40 thin films with presence of P, Mo, O and Cs peaks of metal ions is observed from EDAX spectra.

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Published

31-08-2024

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Research Articles

How to Cite

[1]
Prashant B. Patil, Bajarang B. Patil, Tukaram J. Shinde, and Sambhaji R. Mane , Trans., “Structural Properties of Cs1+ Doped H3PMo12O40 Nanocrystalline Polyoxometalate Thin Films”, Int J Sci Res Sci & Technol, vol. 11, no. 4, pp. 400–407, Aug. 2024, doi: 10.32628/IJSRST24114140.