Kinetic Study of Oxidation of Thiophene-2-Carbaldehyde by Imidazolium Dichromate Promoted By 1, 10-Phenanthroline
DOI:
https://doi.org/10.32628/IJSRST2411491Keywords:
Thiophene-2-Carbaldehyde, Oxidation, Imidazolium Dichromate, 1,10-PhenanthrolineAbstract
Kinetic study of oxidation of Thiophene-2-carbaldehyde by Imidazolium dichromate in aqueous acetic acid medium using 1,10-phenanthroline have been studied. In the absence of mineral acids, the oxidation kinetics of Thiophene-2-carbaldehyde acid by Imidazolium dichromate shows a first-order dependence on Imidazolium dichromate and fractional order on Thiophene-2-carbaldehyde. The variation of ionic strength, H+ and reaction product have in significant effect on reaction rate. Activation parameters have been studied for the reaction from the Arrhenius plot by studying the reaction at different temperatures.
Downloads
References
Mathiyalagan N and Sridharan R, Indian J Chem., 2005, 44A, 2044.
Corey E J and Boger D L, Tetrahedron Lett., 1978, 28, 2461.
Narayanan N and Balasubramanium T R, J Chem Res (S)., 1991, 336.
Grover A, Varshney S and Banerji K K, Indian J Chem., 1994, 33A, 622.
Narayanan N and Balasubramanian T R, Indian J Chem., 1986, 25B, 229.
Krishnasamy K, Devanathan D, Dharmaraja J, Trans Met Chem., 2007, 922.
Bell R P, Adv Phys Org Chem., 1964, 4, 1.
Chaubey G S, Das S, Mahanti M K, Kinetics and Catalysis., 2002, 43, 789.
Mohamed Farook N A, J Solution Chem., 36, 2007, 345.
Amis E S, Solvent Effects on Reaction Rates and Mechanisms, Academic Press, New York, 1967
Srinivasan C and Subramanian P, J Chem Soc., Perkin Trans 2, 1990, 1061.
Hammett L P, Physical Organic Chemistry, 1st Edn. McGraw-Hill, New York, 1940.
Wiberg K B, Oxidations in Organic Chemistry, Academic Press, NewYork, 1965.
Krishnapillai M and Jameel A A, Indian J Chem., 1992, 31A, 46.
Fathimajeyanthi G, Vijayakumar G and Elango K P, J Serb Chem Soc., 2002, 67, 803.
Pandurangan A and Murugesan V, Oxidn Commun., 1997, 20, 93.
Dhariwal V, Yajurvedi D and Sharma P K, Indian J Chem., 2006, 45A, 1158.
Pandurangan A, Murugesan V and Palanisamy M, J Indian Chem Soc., 1995,72, 479.
Pandurangan A, Kavitha S and Alphonse I, Indian J Chem., 2005, 44A, 715.
Bhattacharjee M N, Chaudhuri M K, Dasgupta H S, Roy N and Khathing D T, Synthesis, 1982, 588.
Banerji K K, J Org Chem., 1988, 53, 2154.
Banerji K K, J Chem Soc., Perkin Trans 2, 1978, 639.
Sekar K G, Oxid Commun., 2003, 26, 198.
Medien H A A, Z Naturforsch., 2003, 58b, 1201.
Agarwal S, Chowdhury and Banerji K K, J Org Chem., 1991, 56, 5111.
Downloads
Published
Issue
Section
License
Copyright (c) 2024 International Journal of Scientific Research in Science and Technology

This work is licensed under a Creative Commons Attribution 4.0 International License.