Kinetic Study of Oxidation of Thiophene-2-Carbaldehyde by Imidazolium Dichromate Promoted By 1, 10-Phenanthroline
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https://doi.org/10.32628/IJSRST2411491Keywords:
Thiophene-2-Carbaldehyde, Oxidation, Imidazolium Dichromate, 1,10-PhenanthrolineAbstract
Kinetic study of oxidation of Thiophene-2-carbaldehyde by Imidazolium dichromate in aqueous acetic acid medium using 1,10-phenanthroline have been studied. In the absence of mineral acids, the oxidation kinetics of Thiophene-2-carbaldehyde acid by Imidazolium dichromate shows a first-order dependence on Imidazolium dichromate and fractional order on Thiophene-2-carbaldehyde. The variation of ionic strength, H+ and reaction product have in significant effect on reaction rate. Activation parameters have been studied for the reaction from the Arrhenius plot by studying the reaction at different temperatures.
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References
Mathiyalagan N and Sridharan R, Indian J Chem., 2005, 44A, 2044.
Corey E J and Boger D L, Tetrahedron Lett., 1978, 28, 2461. DOI: https://doi.org/10.1016/S0040-4039(01)94800-2
Narayanan N and Balasubramanium T R, J Chem Res (S)., 1991, 336.
Grover A, Varshney S and Banerji K K, Indian J Chem., 1994, 33A, 622.
Narayanan N and Balasubramanian T R, Indian J Chem., 1986, 25B, 229.
Krishnasamy K, Devanathan D, Dharmaraja J, Trans Met Chem., 2007, 922. DOI: https://doi.org/10.1007/s11243-007-0250-2
Bell R P, Adv Phys Org Chem., 1964, 4, 1.
Chaubey G S, Das S, Mahanti M K, Kinetics and Catalysis., 2002, 43, 789. DOI: https://doi.org/10.1023/A:1021634603629
Mohamed Farook N A, J Solution Chem., 36, 2007, 345. DOI: https://doi.org/10.1007/s10953-006-9116-z
Amis E S, Solvent Effects on Reaction Rates and Mechanisms, Academic Press, New York, 1967
Srinivasan C and Subramanian P, J Chem Soc., Perkin Trans 2, 1990, 1061. DOI: https://doi.org/10.1039/p29900001061
Hammett L P, Physical Organic Chemistry, 1st Edn. McGraw-Hill, New York, 1940.
Wiberg K B, Oxidations in Organic Chemistry, Academic Press, NewYork, 1965.
Krishnapillai M and Jameel A A, Indian J Chem., 1992, 31A, 46.
Fathimajeyanthi G, Vijayakumar G and Elango K P, J Serb Chem Soc., 2002, 67, 803. DOI: https://doi.org/10.2298/JSC0212803J
Pandurangan A and Murugesan V, Oxidn Commun., 1997, 20, 93.
Dhariwal V, Yajurvedi D and Sharma P K, Indian J Chem., 2006, 45A, 1158.
Pandurangan A, Murugesan V and Palanisamy M, J Indian Chem Soc., 1995,72, 479.
Pandurangan A, Kavitha S and Alphonse I, Indian J Chem., 2005, 44A, 715.
Bhattacharjee M N, Chaudhuri M K, Dasgupta H S, Roy N and Khathing D T, Synthesis, 1982, 588. DOI: https://doi.org/10.1055/s-1982-29872
Banerji K K, J Org Chem., 1988, 53, 2154. DOI: https://doi.org/10.1021/jo00245a004
Banerji K K, J Chem Soc., Perkin Trans 2, 1978, 639. DOI: https://doi.org/10.1039/p29780000639
Sekar K G, Oxid Commun., 2003, 26, 198. DOI: https://doi.org/10.1093/oxartj/26.2.198
Medien H A A, Z Naturforsch., 2003, 58b, 1201. DOI: https://doi.org/10.1515/znb-2003-1207
Agarwal S, Chowdhury and Banerji K K, J Org Chem., 1991, 56, 5111. DOI: https://doi.org/10.1021/jo00017a023
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