A Review on Recent Trends of Sb2Se3 Thin Film Technology
DOI:
https://doi.org/10.32628/IJSRST251222662Keywords:
Energy, Solar, thin filmsAbstract
Antimony selenide (Sb2Se3) thin films have emerged as a promising material for energy applications due to their unique optoelectronic properties, including high absorption coefficients, a suitable bandgap (~1-1.5 eV), and a polycrystalline orthorhombic structure. The material's abundance, non-toxic nature, and compatibility with sustainable manufacturing methods have further elevated its significance in photovoltaic and optoelectronic devices. This review provides a comprehensive analysis of the material properties, focusing on structural, optical, and electrical characteristics, along with recent advancements in synthesis techniques such as chemical and physical deposition methods. The potential of Sb2Se3 thin films in solar cell applications is highlighted, where power conversion efficiencies have steadily improved through innovative device architectures and material optimization. Additionally, this review addresses key challenges, including carrier recombination and stability issues, while proposing future research directions to enhance the performance and commercial viability of Sb2Se3-based devices. By consolidating existing knowledge, this study aims to serve as a foundation for advancing Sb2Se3 thin-film technologies.
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References
Net Zero by 2050, IEA, Paris. IEA (2021), 2021.
Green, M.A., et al., Solar cell efficiency tables (version 56). 2020. 28(7): p. 629-638.
Shockley, W. and H.J. Queisser, Detailed Balance Limit of Efficiency of p‐n Junction Solar Cells. Journal of Applied Physics, 1961. 32(3): p. 510-519.
Rühle, S., Tabulated values of the Shockley–Queisser limit for single junction solar cells. Solar Energy, 2016. 130: p. 139-147.
Jackson, P., et al., New world record efficiency for Cu(In,Ga)Se2 thin-film solar cells beyond 20%. Progress in Photovoltaics: Research and Applications, 2011. 19: p. 894-897.
Green, M.A., et al., Solar cell efficiency tables (Version 53). 2019. 27(1): p. 3-12.
Mineral commodity summaries 2023, in Mineral Commodity Summaries. 2023: Reston, VA. p. 210.
Fthenakis, V., Life cycle impact analysis of Cadmium in CdTe PV production. Renewable and Sustainable Energy Reviews, 2004. 8: p. 303-334.
Marquez-Prieto, J., et al., Earth abundant thin film solar cells from co-evaporated Cu2SnS3 absorber layers. Journal of Alloys and Compounds, 2016. 689.
Nguyen, C.T.Q., et al., High energy storage responses in all-oxide epitaxial relaxor ferroelectric thin films with the coexistence of relaxor and antiferroelectric-like behaviors. Thin Solid Films, 2017. 636: p. 188-192.
Kaiwen, S., L. Fangyang, and H. Xiaojing, Kesterite Cu2ZnSnS4-xSex Thin Film Solar Cells, in Thin Films Photovoltaics, Z. Beddiaf and S. Chander, Editors. 2021, IntechOpen: Rijeka. p. Ch. 4.
Wang, Y., et al., Metal oxide charge transport layers in perovskite solar cells—optimising low temperature processing and improving the interfaces towards low temperature processed, efficient and stable devices. Journal of Physics: Energy, 2021. 3(1): p. 012004.
Hahm, J., et al., Increasing ambient temperature progressively disassembles Arabidopsis phytochrome B from individual photobodies with distinct thermostabilities. Nature Communications, 2020. 11(1): p. 1660.
Chen, C., K. Li, and J. Tang, Ten Years of Sb2Se3 Thin Film Solar Cells. 2022. 6(7): p. 2200094.
Dogra, P., et al., Intermolecular Charge-Transfer Modulates Liquid-Liquid Phase Separation and Liquid-to-Solid Maturation of an Intrinsically Disordered pH-Responsive Domain. J Am Chem Soc, 2019. 141(51): p. 20380-20389.
Chen, C., et al., Efficiency Improvement of Sb 2 Se 3 Solar Cell via Grain Boundary Inversion. ACS Energy Letters, 2018. 3.
Bae, S.K., et al., Transparent ultra-thin silver electrodes formed via a maskless evaporation process for applications in flexible organic light-emitting devices. Nano Energy, 2020. 71: p. 104649.
Wang, H., et al., A Liquid Gripper Based on Phase Transitional Metallic Ferrofluid (Adv. Funct. Mater. 32/2021). Advanced Functional Materials, 2021. 31.
Lei, H., et al., Efficient planar Sb2S3 solar cells using a low-temperature solution-processed tin oxide electron conductor. Physical Chemistry Chemical Physics, 2016. 18(24): p. 16436-16443.
Zhang, G., et al., Naphthalenothiophene imide-based polymer exhibiting over 17% efficiency. Joule, 2021. 5(4): p. 931-944.
Hussain, I., et al., Electrochemical Properties of Mo4VC4Tx MXene in Aqueous Electrolytes. ACS Applied Materials & Interfaces, 2024.
Chang, K., et al., The impact of capital leverage on green firms’ investment: New evidence regarding the size and age effects of Chinese green industries. Finance Research Letters, 2020. 38: p. 101529.
Terlemezoğlu, M., Structural, Morphological, and Temperature-Tuned Bandgap Properties of Single-Step Thermally Evaporated Sb2Se3 Thin Films. Applied Physics A, 2024. 130(4).
Herrmann, M.G., et al., Lattice Dynamics of Sb2Se3 From Inelastic Neutron and X‐Ray Scattering. Physica Status Solidi (B), 2020. 257(6).
Li, Z., et al., 9.2%-efficient Core-Shell Structured Antimony Selenide Nanorod Array Solar Cells. Nature Communications, 2019. 10(1).
Liang, X., et al., Nanoepitaxy Growth of Sb2Se3 Nanorod Arrays on Mixed‐Oriented Transparent Conducting Oxide‐Coated Glass for Efficient and Quasiomnidirectional Solar Cells. Solar RRL, 2021. 6(4).
Tse, G., Evaluation of the Structural, Electronic, Optical, and Mechanical Properties of Sb2Se3 Using Density Functional Theory. International Journal of Modern Physics B, 2023. 37(23).
Milligan, G., et al., Single Quasi-1d Chains of Sb2Se3 Encapsulated Within Carbon Nanotubes. 2023.
Liu, T., et al., Conduction Band Energy‐Level Engineering for Improving Open‐Circuit Voltage in Antimony Selenide Nanorod Array Solar Cells. Advanced Science, 2021. 8(16).
Wang, Y., S. Ji, and B. Shin, Interface Engineering of Antimony Selenide Solar Cells: A Review on the Optimization of Energy Band Alignments. Journal of Physics Energy, 2022. 4(4): p. 044002.
Olimov, A., et al., Morphological and Structural Properties of Antimony Selenide Thin Films Deposited With External Electric Field Assistance. «узбекский Физический Журнал», 2024. 26(3).
Chen, S., et al., Simultaneous Band Alignment Modulation and Carrier Dynamics Optimization Enable Highest Efficiency in Cd‐Free Sb2Se3 Solar Cells. Advanced Functional Materials, 2024. 34(40).
Momma, K. and F. Izumi, VESTA 3 for Three-Dimensional Visualization of Crystal, Volumetric and Morphology Data. Journal of Applied Crystallography, 2011. 44.
González, J.C., et al., Deciphering the Role of Defects in the Ambipolar Electrical Transport in Nanocrystalline Sb2Se3 Thin Films. Advanced Electronic Materials, 2021. 8(4).
Kumar, K.V., et al., Electronic and Optical Properties of Sb2Se3 and Sb2S3: Theoretical Investigations. Zeitschrift Für Physikalische Chemie, 2024.
Sun, D., et al., Ultrafast Broadband Nonlinear Optical Response in Co-Doped Sb2Se3 Nanofilms at Near-Infrared. Frontiers in Materials, 2021. 8.
Birkett, M., et al., Band Gap Temperature-Dependence of Close-Space Sublimation Grown Sb2Se3 by Photo-Reflectance. Apl Materials, 2018. 6(8).
Liu, X., et al., Controlled Epitaxial Growth of (Hk1)‐Sb2Se3 Film on Cu9S5 Single Crystal via Post‐Annealing Treatment for Photodetection Application. Small, 2023. 20(22).
Duan, Z., et al., Sb2Se3 Thin‐Film Solar Cells Exceeding 10% Power Conversion Efficiency Enabled by Injection Vapor Deposition Technology. Advanced Materials, 2022. 34(30).
Chen, C., et al., Optical properties of amorphous and polycrystalline Sb2Se3 thin films prepared by thermal evaporation. Applied Physics Letters, 2015. 107: p. 043905.
El Radaf, I.M., Structural, optical, optoelectrical and photovoltaic properties of the thermally evaporated Sb2Se3 thin films. Applied Physics A, 2019. 125.
Mavlonov, A., et al., Structural and morphological properties of PLD Sb2Se3 thin films for use in solar cells. Solar Energy, 2020. 208: p. 451-456.
Xin-Li Liu, Y.-F.W., Ning Mao, Pei-Qing Zhang, Chang-Gui Lin, Xiang Shen, Shi-Xun Dai, and B.-A. Song, Effect of thickness of antimony selenide film on its photoelectric properties and microstructure. 2023. 32(2): p. 27802-027802.
Hobson, T.D.C., et al., Growth and Characterization of Sb<inf>2</Inf> Se<inf>3</Inf> Single Crystals for Fundamental Studies. 2018: p. 0818-0822.
Abdelkadir, A.A., et al., New Sb2Se3-Based Solar Cell for Achieving High Efficiency Theoretical Modeling. Optical and Quantum Electronics, 2023. 55(6).
Wang, X., et al., Upper efficiency limit of Sb2Se3 solar cells. Joule, 2024. 8(7): p. 2105-2122.
Huang, M., et al., Complicated and Unconventional Defect Properties of the Quasi-One-Dimensional Photovoltaic Semiconductor Sb(2)Se(3). ACS Appl Mater Interfaces, 2019. 11(17): p. 15564-15572.
Li, Y., et al., Characterization of Mg and Fe Doped Sb2Se3 Thin Films for Photovoltaic Application. Applied Physics Letters, 2016. 109(23).
Wang, Z., et al., One-Step Hydrothermal Synthesis of Sn-Doped Sb2Se3 for Solar Hydrogen Production. 2024.
Mamta, et al., Ideal HTLs May Open the Door for Further Development of Sb2Se3 Solar Cells—A Numerical Approach. Sustainability, 2023. 15(13): p. 10465.
Guo, L., et al., Tunable Quasi‐One‐Dimensional Ribbon Enhanced Light Absorption in Sb2Se3 Thin‐film Solar Cells Grown by Close‐Space Sublimation. Solar RRL, 2018. 2(10).
Mo, A., et al., Controlling Unintentional Defects Enables High‐Efficient Antimony Selenide Solar Cells. Advanced Functional Materials, 2024. 34(29).
Mo, A., et al., Reducing Parasitic Loss and Deep Defect Formation via Copper Doping Toward Highly Efficient Sb2Se3 Solar Cells. Advanced Functional Materials, 2025.
Liu, X., et al., Enhanced Sb2Se3solar Cell Performance Through Theory-Guided Defect Control. Progress in Photovoltaics Research and Applications, 2017. 25(10): p. 861-870.
Luo, Y., et al., Rapid Thermal‐Driven Crystal Growth and Defect Suppression in Antimony Selenide Thin Film for Efficient Solar Cells. Small, 2024. 21(1).
Chen, C., et al., Efficiency Improvement of Sb2Se3 Solar Cells via Grain Boundary Inversion. Acs Energy Letters, 2018. 3(10): p. 2335-2341.
Luo, Y., et al., An Effective Combination Reaction Involved With Sputtered and Selenized Sb Precursors for Efficient Sb2Se3 Thin Film Solar Cells. Chemical Engineering Journal, 2020. 393: p. 124599.
Spaggiari, G., et al., Exploring Cu-Doping for Performance Improvement in Sb2Se3 Photovoltaic Solar Cells. International Journal of Molecular Sciences, 2022. 23(24): p. 15529.
Guo, L., et al., Interface Engineering via Sputtered Oxygenated CdS:O Window Layer for Highly Efficient Sb2Se3 Thin‐Film Solar Cells With Efficiency Above 7%. Solar RRL, 2019. 3(10).
Hutter, O.S., et al., CSS Antimony Selenide Film Morphology and High Efficiency PV Devices. 2018: p. 0027-0031.
Guo, H., et al., Enhancement in the Efficiency of Sb2Se3 Thin‐Film Solar Cells by Increasing Carrier Concertation and Inducing Columnar Growth of the Grains (Solar RRL 3∕2019). Solar RRL, 2019. 3(3).
Cao, Z., et al., Oxygen Content Modulation Toward Highly Efficient Sb2Se3 Solar Cells. Acs Applied Materials & Interfaces, 2022. 14(50): p. 55691-55699.
Wen, X., et al., Vapor Transport Deposition of Antimony Selenide Thin Film Solar Cells With 7.6% Efficiency. Nature Communications, 2018. 9(1).
Guo, H., et al., Enhancement in the Efficiency of Sb2Se3 Thin‐Film Solar Cells by Increasing Carrier Concertation and Inducing Columnar Growth of the Grains. Solar RRL, 2018. 3(3).
Rahman, R.S., K. Asokan, and M. Zulfequar, Mitigation of Surface Oxidation in Sb2Se3 Thin Films via Te Doping: An Effective Strategy Towards Realization of Efficient Electronic Devices. The Journal of Physical Chemistry C, 2022. 126(13): p. 6065-6074.
Bilya, M.A., et al., Growth and Characterization of P-Type and N-Type Sb2Se3 for Use in Thin-Film Photovoltaic Solar Cell Devices. Energies, 2024. 17(2): p. 406.
Zeng, K., D.J. Xue, and J. Tang, Antimony selenide thin-film solar cells. Semiconductor Science and Technology, 2016. 31: p. 063001.
Tang, R., et al., Controlled Sputtering Pressure on High-Quality Sb2Se3 Thin Film for Substrate Configurated Solar Cells. Nanomaterials, 2020. 10(3): p. 574.
Liang, G., et al., Crystal Growth Promotion and Defects Healing Enable Minimum Open‐Circuit Voltage Deficit in Antimony Selenide Solar Cells. Advanced Science, 2022. 9(9).
Yao, S., et al., Improved Performance of Thermally Evaporated Sb2Se3 Thin-Film Solar Cells via Substrate-Cooling-Speed Control and Hydrogen-Sulfide Treatment. Acs Applied Materials & Interfaces, 2020. 12(21): p. 24112-24124.
Ngo, T.T., et al., Electrodeposition of Antimony Selenide Thin Films and Application in Semiconductor Sensitized Solar Cells. Acs Applied Materials & Interfaces, 2014. 6(4): p. 2836-2841.
Tang, R., et al., Effective Non-Radiative Interfacial Recombination Suppression Scenario Using Air Annealing for Antimony Triselenide Thin-Film Solar Cells. Materials, 2024. 17(13): p. 3222.
Liang, G.-X., et al., Sputtered and selenized Sb2Se3 thin-film solar cells with open-circuit voltage exceeding 500 mV. Nano Energy, 2020. 73: p. 104806.
Zhou, Y., et al., Thin-Film Sb2Se3 Photovoltaics With Oriented One-Dimensional Ribbons and Benign Grain Boundaries. Nature Photonics, 2015. 9(6): p. 409-415.
Kumar, V., et al., Analysis of Se Co-Evaporation and Post-Selenization for Sb2Se3-Based Solar Cells. Acs Applied Energy Materials, 2021. 4(11): p. 12479-12486.
Rijal, S., et al., Templated Growth and Passivation of Vertically Oriented Antimony Selenide Thin Films for High‐Efficiency Solar Cells in Substrate Configuration. Advanced Functional Materials, 2021. 32(10).
Xu, Y., et al., Enhanced Charge Carrier Mobility of Evaporated Sb2Se3 via Post‐Treatment for High‐Speed Photodetection. Laser & Photonics Review, 2023. 17(11).
Liu, X., et al., Thermal Evaporation and Characterization of Sb2Se3 Thin Film for Substrate Sb2Se3/CdS Solar Cells. Acs Applied Materials & Interfaces, 2014. 6(13): p. 10687-10695.
Liu, X., et al., Improving the Performance of Sb2Se3 Thin Film Solar Cells Over 4% by Controlled Addition of Oxygen During Film Deposition. Progress in Photovoltaics Research and Applications, 2015. 23(12): p. 1828-1836.
Vidal-Fuentes, P., et al., Efficient Se‐Rich Sb2Se3/CdS Planar Heterojunction Solar Cells by Sequential Processing: Control and Influence of Se Content. Solar RRL, 2020. 4(7).
Zhang, J. and S. Li, The Effect of Deposition Time Optimization on the Photovoltaic Performance of Sb2Se3 Thin-Film Solar Cells. Energies, 2024. 17(8): p. 1937.
Chen, S., et al., Improved Open‐Circuit Voltage of Sb2Se3 Thin‐Film Solar Cells via Interfacial Sulfur Diffusion‐Induced Gradient Bandgap Engineering. Solar RRL, 2021. 5(10).
Wang, W., et al., Remarkable Sb2Se3 Solar Cell With a Carbon Electrode by Tailoring Film Growth During the VTD Process. Acs Applied Energy Materials, 2021. 4(11): p. 13335-13346.
Spaggiari, G., S. Rampino, and D. Bersani, Sb2Se3: A Possible Future for Thin-Film Photovoltaics? Epj Web of Conferences, 2022. 268: p. 00006.
Brito, D., et al., Antimony Selenide Solar Cells Fabricated by Hybrid Reactive Magnetron Sputtering. Nanomaterials, 2023. 13(15): p. 2257.
Cai, H., et al., Interfacial Engineering Towards Enhanced Photovoltaic Performance of Sb2Se3 Solar Cell. Advanced Functional Materials, 2022. 32(46).
Cantas, A., Investigation of Thermally Induced Surface Composition and Morphology Variation of Magnetron Sputtered Sb2Se3 Absorber Layer for Thin Film Solar Cells. Physica Scripta, 2024. 99(10): p. 105993.
Ren, D., et al., Structure, Morphology, and Photoelectric Performances of Te-Sb2Se3 Thin Film Prepared via Magnetron Sputtering. Nanomaterials, 2020. 10(7): p. 1358.
Ding-Jiang, X., S. Hang-Jie, and J. Tang, Recent Progress in Material Study and Photovoltaic Device of Sb2Se3. Acta Physica Sinica, 2015. 64(3): p. 038406.
Juškėnas, R.g.j., et al., Seed Layer Optimisation for Ultra-Thin Sb2Se3 Solar Cells on TiO2 by Vapour Transport Deposition. Materials, 2022. 15(23): p. 8356.
Jakomin, R., et al., Advances on Sb2Se3 Solar Cells Fabricated by Physical Vapor Deposition Techniques. Solar, 2023. 3(4): p. 566-595.
Pasini, S., et al., Sb2Se3 Polycrystalline Thin Films Grown on Different Window Layers. Coatings, 2023. 13(2): p. 338.
Sun, S., et al., Substantially Improved Performance in Sb 2 Se 3 Solar Cells on CdS Buffered TiO 2 Electron Transport Layer. 2023.
Guo, H., et al., Highly Efficient and Thermally Stable Sb2Se3 Solar Cells Based on a Hexagonal CdS Buffer Layer by Environmentally Friendly Interface Optimization. Journal of Materials Chemistry C, 2020. 8(48): p. 17194-17201.
Li, K., et al., Effect of Energy‐driven Molecular Precursor Decomposition on the Crystal Orientation of Antimony Selenide Film and Solar Cell Efficiency. Small Methods, 2024. 8(12).
Tian, Y., et al., One-Dimensional Sb2Se3 Nanorods Synthesized through a Simple Polyol Process for High-Performance Lithium-Ion Batteries. 2018. 2018(1): p. 4273945.
Khac, D.L., et al., Influence/Effect of Deep-Level Defect of Absorber Layer and N/I Interface on the Performance of Antimony Triselenide Solar Cells by Numerical Simulation. Sustainability, 2022. 14(11): p. 6780.
Jakomin, R., et al., Cu-Doped Sb2Se3 Thin-Film Solar Cells Based on Hybrid Pulsed Electron Deposition/Radio Frequency Magnetron Sputtering Growth Techniques. Solar, 2024. 4(1): p. 83-98.
Dong, Y., et al., Zinc Chloride‐Treated Indium Sulfide as Buffer Layer for Cd‐Free Antimony Selenide Solar Cells. Solar RRL, 2023. 7(18).
Kumari, R., et al., 24% Efficient, Simple ZnSe/Sb2Se3 Heterojunction Solar Cell: An Analysis of PV Characteristics and Defects. Acs Omega, 2022. 8(1): p. 1632-1642.
Chen, C., K. Li, and J. Tang, Ten Years of Sb2Se3 Thin Film Solar Cells. Solar RRL, 2022. 6(7).
Verma, V.S., Advancement in Solar Technology: Evolution, Generation, Future Prospective, and Challenges - A Review. 2024.
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