A Potentiometric PVC Membrane Sensor for Zinc (II) Ions Based on a Newly Synthesized Schiff Base
DOI:
https://doi.org/10.32628/IJSRST25123155Keywords:
Zinc ion-selective electrode, Schiff base, PVC membrane, PotentiometryAbstract
A novel and highly selective polyvinyl chloride (PVC) membrane electrode for zinc (II) ions has been developed utilizing a newly synthesized Schiff base, [(E)-2,4-dichloro-6-(1-((4 chlorophenyl) imino) ethyl) phenol], as the ionophore. The sensor displays a near-Nernstian response toward Zn²⁺ ions across a broad concentration range of 1.0 × 10⁻¹ to 5.0 × 10⁻⁷ M, with a detection limit of 7.4 × 10⁻⁸ M. It exhibits a rapid response time of approximately 20 seconds and maintains consistent performance for at least three months without significant drift. The electrode demonstrates excellent selectivity for Zn²⁺ ions over numerous interfering cations and operates effectively within a pH range of 3.0 to 7.5. Furthermore, it has been successfully applied for the direct quantification of Zn²⁺ in aqueous samples and functioned reliably as an indicator electrode in potentiometric titration procedures involving zinc ions.
📊 Article Downloads
References
Abbaspour, A., Tavakol, F., Lead-selective electrode by using benzyl disulphide as ionophore, Analytica Chimica Acta Volume 378, Issues 1–3, 4 January 1999, Pages 145-149. DOI: https://doi.org/10.1016/S0003-2670(98)00520-0
F. Faridbod, M. R. Ganjali, R. Dinarvand, P. Norouzi, S. Riahi, Sensors, 8 (2008) 1645. DOI: https://doi.org/10.3390/s8031645
M. R. Ganjali, P. Norouzi, M. Rezapour, F. Faridbod, M. R. Pourjavid, Sensors, 6 (2006) 1018. DOI: https://doi.org/10.3390/s6081018
J.M. Berg, Y. Shi, Science 271 (1996) 1081–1085. DOI: https://doi.org/10.1126/science.271.5252.1081
P.D. Zalewski, X. Jian, L.L.L. Soon, W.G. Breed, R.F. Seamark, S.F. Lincolin, A.D.
Q. Li, X.H. Zhao, Q.Z. Lv, G.G. Liu, Sep. Purif. Technol. 55 (2007) 76–81. DOI: https://doi.org/10.1016/j.seppur.2006.11.001
M. Hosseini, Z. Vaezi, M.R. Ganjali, F. Faridbod, S. Dehghan Abkenar, K. Alizadeh, M. Salavati-Niasari, Spectrochim. Acta A 75 (2010) 978–982. DOI: https://doi.org/10.1016/j.saa.2009.12.016
P. Kaur, S. Kaur, A. Mahajan, K. Singh, Inorg. Chem. Commun. 11 (2008) 626–629. DOI: https://doi.org/10.1016/j.inoche.2008.02.025
P. Wilhartitz, S. Dreer, R. Krismer, O. Bobleter, Mikrochim. Acta 125 (1997) 45–52. DOI: https://doi.org/10.1007/BF01246161
N.R. Gupta, S. Mittal, S. Kumar, S.K.A. Kumar, Mater. Sci. Eng. C 28 (2008) 1025–1030. DOI: https://doi.org/10.1016/j.msec.2007.03.003
R. Kojuma, S. Kamata, Anal. Sci. 10 (1994) 409–412. DOI: https://doi.org/10.2116/analsci.10.409
M. Shamsipur, S. Rouhani, M.R. Ganjali, H. Sharghi, H. Eshghi, Sens. Actuators B 59 (1999) 30–34. DOI: https://doi.org/10.1016/S0925-4005(99)00160-4
A. Bhatola, B.K. Puri, Talanta 49 (1999) 485–493. DOI: https://doi.org/10.1016/S0039-9140(99)00013-2
P.C. Pandey, G. Dingh, Sens. Actuators B 85 (2002) 256–262. DOI: https://doi.org/10.1016/S0925-4005(02)00129-6
V.K. Gupta, A. Kumar, R. Mangla, Sens. Actuators B 76 (2001) 617–623. DOI: https://doi.org/10.1016/S0925-4005(01)00656-6
A.R. Fakhari, M. Shamsipur, Kh. Ghanbari, Anal. Chim. Acta 460 (2002) 177–183. DOI: https://doi.org/10.1016/S0003-2670(02)00200-3
M.B. Gholivand, Y. Mozaffari, Talanta 59 (2003) 399–407. DOI: https://doi.org/10.1016/S0039-9140(02)00528-3
V.K. Gupta, A.K. Jain, R. Mangla, P. Kumar, Electroanalysis 13 (12) (2001) 1036–1040. DOI: https://doi.org/10.1002/1521-4109(200108)13:12<1036::AID-ELAN1036>3.0.CO;2-7
V.K. Gupta, A.K. Jain, G. Maheswari, Chem. Anal. (Warsaw) 51 (2006) 889–897.
V.K. Gupta, S. Agarwal, A. Jakob, H. Lang, Sens. Actuators B 114 (2006) 812–818. DOI: https://doi.org/10.1016/j.snb.2005.07.039
M. Hosseini, S. Dehghan Abkenar, M.R. Ganjali, F. Faridbod, Mater. Sci. Eng. C31 (2011) 428–433. DOI: https://doi.org/10.1016/j.msec.2010.10.020
P. Singh, A.K. Singh, A.K. Jain, Electrochim. Acta 56 (2011) 5386–5395. DOI: https://doi.org/10.1016/j.electacta.2011.03.090
X. Lu, Z. Wang, Z. Geng, J. Kang, J. Gao, Talanta 52 (2000) 411–416. DOI: https://doi.org/10.1016/S0039-9140(00)00392-1
Rasmussen, P. E. ; Subramanian, K. S. ; Jessiman, B. J., Sci. Total Environ., 2001, 267(1-3), 125-140. DOI: https://doi.org/10.1016/S0048-9697(00)00775-0
Al-Momani, I. F., Soil & Sediment Contamination, 2007, 16, 485-496. DOI: https://doi.org/10.1080/15320380701490184
Jarup, L., Br. Med. Bull., 2003, 68, 167-182. DOI: https://doi.org/10.1093/bmb/ldg032
Tong, S. T. Y., Lamb, K. C., Sci. Total Environ., 2000, 256(2-3), 115-123. DOI: https://doi.org/10.1016/S0048-9697(00)00471-X
Maertens, R., Bailey, J., White, P., Mutation Research, 2004, 567, 401-425. DOI: https://doi.org/10.1016/j.mrrev.2004.08.004
Morawska, L.; He, C.; Hitchins, J.; Gilbert, D.; Parappukkaran, S., Atmospheric Environment, 2001, 35, 3463-3473. DOI: https://doi.org/10.1016/S1352-2310(01)00097-8
Butte, W.; Heinzow, B., Rev. Environ. Contam. Toxicol., 2002, 175, 1-46.
Al-Momani I. F., Jordan J. of Chemistry, 2009, 4(1), 77-87.
Massadeh A. M.; Tahat M.; Jaradat Q. M.; Al-Momani I. F., Soil & Sediment Contamination, 2004, 13, 347-359. DOI: https://doi.org/10.1080/10588330490466030
Zheng, J.; Chen, K.; Yan, X.; Chen, S.; Hu, G.; Peng, X.; Yuan, J.; Mai, B.; Yang, Z., Ecotox. Environ. Safe., 2013, 96(1), 205-2012. DOI: https://doi.org/10.1016/j.ecoenv.2013.06.017
Abdul Wahab, N.; Darus, F. M.; Isa, N.; Sumari, S. M.; Hanafi, N. F., Malaysian J. Anal. Sci., 2012, 16(1), 18-23.
Alnawaiseh, N. A.; Hashim, J. H.; Isa Z. M.; Salahat, S. J., Eur. J. Sci. Res., 2014, 120(4), 550-563.
Pueyo, M.; Sastre, J.; Hernandez, E.; Vidal, M.; Rauret, G., J. Environ. Qual. 2003, 32, 2054 - 2066. DOI: https://doi.org/10.2134/jeq2003.2054
Kashid, P.; Pansare, D.; Pawar, R.; Sonar,S.; Shelke, R.; Bembalkar, S., Letters in applied nanobioscience. 2024,13(2), 69(1-10).
Matysik, S., Matysik, F.M., Mattusch, J., Einicke, W.D, Electroanalysis, 1998. 10, 98. DOI: https://doi.org/10.1002/(SICI)1521-4109(199802)10:2<98::AID-ELAN98>3.0.CO;2-N
M. Shamsipur, K. Alizadeh, M. Hosseini, C. Caltagirone, V. Lippolis, Sens Actuators B 113 (2006) 892. DOI: https://doi.org/10.1016/j.snb.2005.03.117
Downloads
Published
Issue
Section
License
Copyright (c) 2025 International Journal of Scientific Research in Science and Technology
This work is licensed under a Creative Commons Attribution 4.0 International License.
https://creativecommons.org/licenses/by/4.0
